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Triaquachlorido(18-crown-6)barium chloride
In the title compound, [BaCl(C(12)H(24)O(6))(H(2)O)(3)]Cl, the Ba(II) atom, the coordinating and free Cl(−) anions, one coordinating water molecule and two O atoms of an 18-crown-6 molecule lie on a mirror plane. The environment of the ten-coordinate Ba(2+) ion is defined by one Cl atom, three wat...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297242/ https://www.ncbi.nlm.nih.gov/pubmed/22412432 http://dx.doi.org/10.1107/S1600536812004990 |
| Sumario: | In the title compound, [BaCl(C(12)H(24)O(6))(H(2)O)(3)]Cl, the Ba(II) atom, the coordinating and free Cl(−) anions, one coordinating water molecule and two O atoms of an 18-crown-6 molecule lie on a mirror plane. The environment of the ten-coordinate Ba(2+) ion is defined by one Cl atom, three water molecules and six O atoms from the macrocyclic ether. The macrocycle adopts a conformation with an approximate D (3d) symmetry. In the crystal, O—H⋯Cl hydrogen bonds link the complex cations and Cl(−) anions into a two-dimensional network parallel to (010). An intramolecular O—H⋯Cl hydrogen bond is also present. |
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