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Triaquachlorido(18-crown-6)barium chloride
In the title compound, [BaCl(C(12)H(24)O(6))(H(2)O)(3)]Cl, the Ba(II) atom, the coordinating and free Cl(−) anions, one coordinating water molecule and two O atoms of an 18-crown-6 molecule lie on a mirror plane. The environment of the ten-coordinate Ba(2+) ion is defined by one Cl atom, three wat...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2012
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297242/ https://www.ncbi.nlm.nih.gov/pubmed/22412432 http://dx.doi.org/10.1107/S1600536812004990 |
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| author | Zhao, Min-Min |
| author_facet | Zhao, Min-Min |
| author_sort | Zhao, Min-Min |
| collection | PubMed |
| description | In the title compound, [BaCl(C(12)H(24)O(6))(H(2)O)(3)]Cl, the Ba(II) atom, the coordinating and free Cl(−) anions, one coordinating water molecule and two O atoms of an 18-crown-6 molecule lie on a mirror plane. The environment of the ten-coordinate Ba(2+) ion is defined by one Cl atom, three water molecules and six O atoms from the macrocyclic ether. The macrocycle adopts a conformation with an approximate D (3d) symmetry. In the crystal, O—H⋯Cl hydrogen bonds link the complex cations and Cl(−) anions into a two-dimensional network parallel to (010). An intramolecular O—H⋯Cl hydrogen bond is also present. |
| format | Online Article Text |
| id | pubmed-3297242 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32972422012-03-12 Triaquachlorido(18-crown-6)barium chloride Zhao, Min-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [BaCl(C(12)H(24)O(6))(H(2)O)(3)]Cl, the Ba(II) atom, the coordinating and free Cl(−) anions, one coordinating water molecule and two O atoms of an 18-crown-6 molecule lie on a mirror plane. The environment of the ten-coordinate Ba(2+) ion is defined by one Cl atom, three water molecules and six O atoms from the macrocyclic ether. The macrocycle adopts a conformation with an approximate D (3d) symmetry. In the crystal, O—H⋯Cl hydrogen bonds link the complex cations and Cl(−) anions into a two-dimensional network parallel to (010). An intramolecular O—H⋯Cl hydrogen bond is also present. International Union of Crystallography 2012-02-10 /pmc/articles/PMC3297242/ /pubmed/22412432 http://dx.doi.org/10.1107/S1600536812004990 Text en © Min-Min Zhao 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhao, Min-Min Triaquachlorido(18-crown-6)barium chloride |
| title | Triaquachlorido(18-crown-6)barium chloride |
| title_full | Triaquachlorido(18-crown-6)barium chloride |
| title_fullStr | Triaquachlorido(18-crown-6)barium chloride |
| title_full_unstemmed | Triaquachlorido(18-crown-6)barium chloride |
| title_short | Triaquachlorido(18-crown-6)barium chloride |
| title_sort | triaquachlorido(18-crown-6)barium chloride |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297242/ https://www.ncbi.nlm.nih.gov/pubmed/22412432 http://dx.doi.org/10.1107/S1600536812004990 |
| work_keys_str_mv | AT zhaominmin triaquachlorido18crown6bariumchloride |