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Tetraaquatetrakis(4,4′-bipyridine dioxide-κO)terbium(III) octacyanidotungstate(V)
In the title compound, [Tb(C(10)H(8)N(2)O(2))(4)(H(2)O)(4)][W(CN)(8)], both metal atoms are eight-coordinated. The Tb(III) ion displays a dodecahedral geometry, while the W(v) ion exhibits a distorted square-antiprismatic geometry. The Tb atoms are located on a special position of site symmetry -4...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297244/ https://www.ncbi.nlm.nih.gov/pubmed/22412434 http://dx.doi.org/10.1107/S1600536812005004 |
| _version_ | 1782225847542874112 |
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| author | Shi, Yu-Sheng Ran, Mao-Qian Chen, Ying-Ying Yuan, Ai-Hua |
| author_facet | Shi, Yu-Sheng Ran, Mao-Qian Chen, Ying-Ying Yuan, Ai-Hua |
| author_sort | Shi, Yu-Sheng |
| collection | PubMed |
| description | In the title compound, [Tb(C(10)H(8)N(2)O(2))(4)(H(2)O)(4)][W(CN)(8)], both metal atoms are eight-coordinated. The Tb(III) ion displays a dodecahedral geometry, while the W(v) ion exhibits a distorted square-antiprismatic geometry. The Tb atoms are located on a special position of site symmetry -4, whereas the W atoms are located on a twofold rotation axis. The cations are linked by O—H⋯O hydrogen bonds. The title compound is isotypic with the corresponding and previously described Mo compound [Qian & Yuan (2011 ▶). Acta Cryst. E67, m845]. |
| format | Online Article Text |
| id | pubmed-3297244 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32972442012-03-12 Tetraaquatetrakis(4,4′-bipyridine dioxide-κO)terbium(III) octacyanidotungstate(V) Shi, Yu-Sheng Ran, Mao-Qian Chen, Ying-Ying Yuan, Ai-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Tb(C(10)H(8)N(2)O(2))(4)(H(2)O)(4)][W(CN)(8)], both metal atoms are eight-coordinated. The Tb(III) ion displays a dodecahedral geometry, while the W(v) ion exhibits a distorted square-antiprismatic geometry. The Tb atoms are located on a special position of site symmetry -4, whereas the W atoms are located on a twofold rotation axis. The cations are linked by O—H⋯O hydrogen bonds. The title compound is isotypic with the corresponding and previously described Mo compound [Qian & Yuan (2011 ▶). Acta Cryst. E67, m845]. International Union of Crystallography 2012-02-10 /pmc/articles/PMC3297244/ /pubmed/22412434 http://dx.doi.org/10.1107/S1600536812005004 Text en © Shi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Shi, Yu-Sheng Ran, Mao-Qian Chen, Ying-Ying Yuan, Ai-Hua Tetraaquatetrakis(4,4′-bipyridine dioxide-κO)terbium(III) octacyanidotungstate(V) |
| title | Tetraaquatetrakis(4,4′-bipyridine dioxide-κO)terbium(III) octacyanidotungstate(V) |
| title_full | Tetraaquatetrakis(4,4′-bipyridine dioxide-κO)terbium(III) octacyanidotungstate(V) |
| title_fullStr | Tetraaquatetrakis(4,4′-bipyridine dioxide-κO)terbium(III) octacyanidotungstate(V) |
| title_full_unstemmed | Tetraaquatetrakis(4,4′-bipyridine dioxide-κO)terbium(III) octacyanidotungstate(V) |
| title_short | Tetraaquatetrakis(4,4′-bipyridine dioxide-κO)terbium(III) octacyanidotungstate(V) |
| title_sort | tetraaquatetrakis(4,4′-bipyridine dioxide-κo)terbium(iii) octacyanidotungstate(v) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297244/ https://www.ncbi.nlm.nih.gov/pubmed/22412434 http://dx.doi.org/10.1107/S1600536812005004 |
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