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(2,2′-Bipyridine-6,6′-dicarboxylato-κ(3) N,N′,O (6))(6′-carboxy-2,2′-bipyridine-6-carboxylato-κ(3) N,N′,O (6))rhodium(III)
The Rh(III) ion in the title compound, [Rh(C(12)H(6)N(2)O(4))(C(12)H(7)N(2)O(4))], is coordinated by four N atoms and two O atoms from two chelating ligands L and HL (H(2)L = 2,2′-bipyridine-6,6′-dicarboxylic acid) to form a distorted octahedral geometry. Face-to-face π-stacking interactions are...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297246/ https://www.ncbi.nlm.nih.gov/pubmed/22412436 http://dx.doi.org/10.1107/S1600536812004850 |
Sumario: | The Rh(III) ion in the title compound, [Rh(C(12)H(6)N(2)O(4))(C(12)H(7)N(2)O(4))], is coordinated by four N atoms and two O atoms from two chelating ligands L and HL (H(2)L = 2,2′-bipyridine-6,6′-dicarboxylic acid) to form a distorted octahedral geometry. Face-to-face π-stacking interactions are observed between inversion-related pyridine rings, with a centroid-to-centroid distance of 3.581 (1) Å [the perpendicular distance between the rings is 3.3980 (7) Å]. Intermolecular O—H⋯O hydrogen bonds link adjacent molecules into one-dimensional supramolecular chains along the c axis, while several intermolecular C—H⋯O interactions are also observed. |
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