(2,2′-Bipyridine-6,6′-dicarboxyl­ato-κ(3) N,N′,O (6))(6′-carb­oxy-2,2′-bipyridine-6-carboxyl­ato-κ(3) N,N′,O (6))rhodium(III)

The Rh(III) ion in the title compound, [Rh(C(12)H(6)N(2)O(4))(C(12)H(7)N(2)O(4))], is coordinated by four N atoms and two O atoms from two chelating ligands L and HL (H(2)L = 2,2′-bipyridine-6,6′-dicarb­oxy­lic acid) to form a distorted octa­hedral geometry. Face-to-face π-stacking inter­actions are...

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Detalles Bibliográficos
Autores principales: Wang, Huimin, Gu, Xiaojun, Zhang, Bingbing, Su, Haiquan, Hu, Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297246/
https://www.ncbi.nlm.nih.gov/pubmed/22412436
http://dx.doi.org/10.1107/S1600536812004850
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author Wang, Huimin
Gu, Xiaojun
Zhang, Bingbing
Su, Haiquan
Hu, Ming
author_facet Wang, Huimin
Gu, Xiaojun
Zhang, Bingbing
Su, Haiquan
Hu, Ming
author_sort Wang, Huimin
collection PubMed
description The Rh(III) ion in the title compound, [Rh(C(12)H(6)N(2)O(4))(C(12)H(7)N(2)O(4))], is coordinated by four N atoms and two O atoms from two chelating ligands L and HL (H(2)L = 2,2′-bipyridine-6,6′-dicarb­oxy­lic acid) to form a distorted octa­hedral geometry. Face-to-face π-stacking inter­actions are observed between inversion-related pyridine rings, with a centroid-to-centroid distance of 3.581 (1) Å [the perpendicular distance between the rings is 3.3980 (7) Å]. Inter­molecular O—H⋯O hydrogen bonds link adjacent mol­ecules into one-dimensional supra­molecular chains along the c axis, while several inter­molecular C—H⋯O inter­actions are also observed.
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spelling pubmed-32972462012-03-12 (2,2′-Bipyridine-6,6′-dicarboxyl­ato-κ(3) N,N′,O (6))(6′-carb­oxy-2,2′-bipyridine-6-carboxyl­ato-κ(3) N,N′,O (6))rhodium(III) Wang, Huimin Gu, Xiaojun Zhang, Bingbing Su, Haiquan Hu, Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Rh(III) ion in the title compound, [Rh(C(12)H(6)N(2)O(4))(C(12)H(7)N(2)O(4))], is coordinated by four N atoms and two O atoms from two chelating ligands L and HL (H(2)L = 2,2′-bipyridine-6,6′-dicarb­oxy­lic acid) to form a distorted octa­hedral geometry. Face-to-face π-stacking inter­actions are observed between inversion-related pyridine rings, with a centroid-to-centroid distance of 3.581 (1) Å [the perpendicular distance between the rings is 3.3980 (7) Å]. Inter­molecular O—H⋯O hydrogen bonds link adjacent mol­ecules into one-dimensional supra­molecular chains along the c axis, while several inter­molecular C—H⋯O inter­actions are also observed. International Union of Crystallography 2012-02-17 /pmc/articles/PMC3297246/ /pubmed/22412436 http://dx.doi.org/10.1107/S1600536812004850 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Huimin
Gu, Xiaojun
Zhang, Bingbing
Su, Haiquan
Hu, Ming
(2,2′-Bipyridine-6,6′-dicarboxyl­ato-κ(3) N,N′,O (6))(6′-carb­oxy-2,2′-bipyridine-6-carboxyl­ato-κ(3) N,N′,O (6))rhodium(III)
title (2,2′-Bipyridine-6,6′-dicarboxyl­ato-κ(3) N,N′,O (6))(6′-carb­oxy-2,2′-bipyridine-6-carboxyl­ato-κ(3) N,N′,O (6))rhodium(III)
title_full (2,2′-Bipyridine-6,6′-dicarboxyl­ato-κ(3) N,N′,O (6))(6′-carb­oxy-2,2′-bipyridine-6-carboxyl­ato-κ(3) N,N′,O (6))rhodium(III)
title_fullStr (2,2′-Bipyridine-6,6′-dicarboxyl­ato-κ(3) N,N′,O (6))(6′-carb­oxy-2,2′-bipyridine-6-carboxyl­ato-κ(3) N,N′,O (6))rhodium(III)
title_full_unstemmed (2,2′-Bipyridine-6,6′-dicarboxyl­ato-κ(3) N,N′,O (6))(6′-carb­oxy-2,2′-bipyridine-6-carboxyl­ato-κ(3) N,N′,O (6))rhodium(III)
title_short (2,2′-Bipyridine-6,6′-dicarboxyl­ato-κ(3) N,N′,O (6))(6′-carb­oxy-2,2′-bipyridine-6-carboxyl­ato-κ(3) N,N′,O (6))rhodium(III)
title_sort (2,2′-bipyridine-6,6′-dicarboxyl­ato-κ(3) n,n′,o (6))(6′-carb­oxy-2,2′-bipyridine-6-carboxyl­ato-κ(3) n,n′,o (6))rhodium(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297246/
https://www.ncbi.nlm.nih.gov/pubmed/22412436
http://dx.doi.org/10.1107/S1600536812004850
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