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catena-Poly[1-butyl-3-methylimidazolium [[dichlorido(methanol-κO)(propan-2-ol-κO)lanthanate(III)]-di-μ-chlorido]]
The title compound, (C(8)H(15)N(2))[LaCl(4)(CH(3)OH)(C(3)H(7)OH)], consists of one 1-butyl-3-methylimidazolium (BMI(+)) cation and one hexahedral tetrachlorido(methanol)(propan-2-ol)lanthanate anion. The La(III) ion is eight-coordinate, with the La(III) ion bridged by a pair of Cl atoms, so formi...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297247/ https://www.ncbi.nlm.nih.gov/pubmed/22412437 http://dx.doi.org/10.1107/S160053681200517X |
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author | Han, Yulun Dai, Fengrong Sykes, Andrew G. May, P. Stanley Berry, Mary T. Meng, Qingguo Lin, Cuikun |
author_facet | Han, Yulun Dai, Fengrong Sykes, Andrew G. May, P. Stanley Berry, Mary T. Meng, Qingguo Lin, Cuikun |
author_sort | Han, Yulun |
collection | PubMed |
description | The title compound, (C(8)H(15)N(2))[LaCl(4)(CH(3)OH)(C(3)H(7)OH)], consists of one 1-butyl-3-methylimidazolium (BMI(+)) cation and one hexahedral tetrachlorido(methanol)(propan-2-ol)lanthanate anion. The La(III) ion is eight-coordinate, with the La(III) ion bridged by a pair of Cl atoms, so forming chains propagating along the a-axis direction. Each La(III) ion is further coordinated by two isolated Cl atoms, one methanol and one propan-2-ol molecule. The coordinated methanol and propan-2-ol molecules of the anion form O—H⋯Cl hydrogen bonds with the Cl atoms of inversion-related anions. The BMI(+) cation froms C—H⋯Cl hydrogen bonds with the Cl atoms of the anion. The anions are located in the C faces of the triclinic unit cell, with an inversion center in the middle of the La(2)Cl(2) ring of the polymeric chain. |
format | Online Article Text |
id | pubmed-3297247 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32972472012-03-12 catena-Poly[1-butyl-3-methylimidazolium [[dichlorido(methanol-κO)(propan-2-ol-κO)lanthanate(III)]-di-μ-chlorido]] Han, Yulun Dai, Fengrong Sykes, Andrew G. May, P. Stanley Berry, Mary T. Meng, Qingguo Lin, Cuikun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(8)H(15)N(2))[LaCl(4)(CH(3)OH)(C(3)H(7)OH)], consists of one 1-butyl-3-methylimidazolium (BMI(+)) cation and one hexahedral tetrachlorido(methanol)(propan-2-ol)lanthanate anion. The La(III) ion is eight-coordinate, with the La(III) ion bridged by a pair of Cl atoms, so forming chains propagating along the a-axis direction. Each La(III) ion is further coordinated by two isolated Cl atoms, one methanol and one propan-2-ol molecule. The coordinated methanol and propan-2-ol molecules of the anion form O—H⋯Cl hydrogen bonds with the Cl atoms of inversion-related anions. The BMI(+) cation froms C—H⋯Cl hydrogen bonds with the Cl atoms of the anion. The anions are located in the C faces of the triclinic unit cell, with an inversion center in the middle of the La(2)Cl(2) ring of the polymeric chain. International Union of Crystallography 2012-02-17 /pmc/articles/PMC3297247/ /pubmed/22412437 http://dx.doi.org/10.1107/S160053681200517X Text en © Han et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Han, Yulun Dai, Fengrong Sykes, Andrew G. May, P. Stanley Berry, Mary T. Meng, Qingguo Lin, Cuikun catena-Poly[1-butyl-3-methylimidazolium [[dichlorido(methanol-κO)(propan-2-ol-κO)lanthanate(III)]-di-μ-chlorido]] |
title |
catena-Poly[1-butyl-3-methylimidazolium [[dichlorido(methanol-κO)(propan-2-ol-κO)lanthanate(III)]-di-μ-chlorido]] |
title_full |
catena-Poly[1-butyl-3-methylimidazolium [[dichlorido(methanol-κO)(propan-2-ol-κO)lanthanate(III)]-di-μ-chlorido]] |
title_fullStr |
catena-Poly[1-butyl-3-methylimidazolium [[dichlorido(methanol-κO)(propan-2-ol-κO)lanthanate(III)]-di-μ-chlorido]] |
title_full_unstemmed |
catena-Poly[1-butyl-3-methylimidazolium [[dichlorido(methanol-κO)(propan-2-ol-κO)lanthanate(III)]-di-μ-chlorido]] |
title_short |
catena-Poly[1-butyl-3-methylimidazolium [[dichlorido(methanol-κO)(propan-2-ol-κO)lanthanate(III)]-di-μ-chlorido]] |
title_sort | catena-poly[1-butyl-3-methylimidazolium [[dichlorido(methanol-κo)(propan-2-ol-κo)lanthanate(iii)]-di-μ-chlorido]] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297247/ https://www.ncbi.nlm.nih.gov/pubmed/22412437 http://dx.doi.org/10.1107/S160053681200517X |
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