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catena-Poly[1-butyl-3-methyl­imidazolium [[dichlorido(methanol-κO)(propan-2-ol-κO)lanthanate(III)]-di-μ-chlorido]]

The title compound, (C(8)H(15)N(2))[LaCl(4)(CH(3)OH)(C(3)H(7)OH)], consists of one 1-butyl-3-methyl­imidazolium (BMI(+)) cation and one hexa­hedral tetra­chlorido(methanol)(propan-2-ol)lanthanate anion. The La(III) ion is eight-coordinate, with the La(III) ion bridged by a pair of Cl atoms, so formi...

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Autores principales: Han, Yulun, Dai, Fengrong, Sykes, Andrew G., May, P. Stanley, Berry, Mary T., Meng, Qingguo, Lin, Cuikun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297247/
https://www.ncbi.nlm.nih.gov/pubmed/22412437
http://dx.doi.org/10.1107/S160053681200517X
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author Han, Yulun
Dai, Fengrong
Sykes, Andrew G.
May, P. Stanley
Berry, Mary T.
Meng, Qingguo
Lin, Cuikun
author_facet Han, Yulun
Dai, Fengrong
Sykes, Andrew G.
May, P. Stanley
Berry, Mary T.
Meng, Qingguo
Lin, Cuikun
author_sort Han, Yulun
collection PubMed
description The title compound, (C(8)H(15)N(2))[LaCl(4)(CH(3)OH)(C(3)H(7)OH)], consists of one 1-butyl-3-methyl­imidazolium (BMI(+)) cation and one hexa­hedral tetra­chlorido(methanol)(propan-2-ol)lanthanate anion. The La(III) ion is eight-coordinate, with the La(III) ion bridged by a pair of Cl atoms, so forming chains propagating along the a-axis direction. Each La(III) ion is further coordinated by two isolated Cl atoms, one methanol and one propan-2-ol mol­ecule. The coordinated methanol and propan-2-ol mol­ecules of the anion form O—H⋯Cl hydrogen bonds with the Cl atoms of inversion-related anions. The BMI(+) cation froms C—H⋯Cl hydrogen bonds with the Cl atoms of the anion. The anions are located in the C faces of the triclinic unit cell, with an inversion center in the middle of the La(2)Cl(2) ring of the polymeric chain.
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spelling pubmed-32972472012-03-12 catena-Poly[1-butyl-3-methyl­imidazolium [[dichlorido(methanol-κO)(propan-2-ol-κO)lanthanate(III)]-di-μ-chlorido]] Han, Yulun Dai, Fengrong Sykes, Andrew G. May, P. Stanley Berry, Mary T. Meng, Qingguo Lin, Cuikun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(8)H(15)N(2))[LaCl(4)(CH(3)OH)(C(3)H(7)OH)], consists of one 1-butyl-3-methyl­imidazolium (BMI(+)) cation and one hexa­hedral tetra­chlorido(methanol)(propan-2-ol)lanthanate anion. The La(III) ion is eight-coordinate, with the La(III) ion bridged by a pair of Cl atoms, so forming chains propagating along the a-axis direction. Each La(III) ion is further coordinated by two isolated Cl atoms, one methanol and one propan-2-ol mol­ecule. The coordinated methanol and propan-2-ol mol­ecules of the anion form O—H⋯Cl hydrogen bonds with the Cl atoms of inversion-related anions. The BMI(+) cation froms C—H⋯Cl hydrogen bonds with the Cl atoms of the anion. The anions are located in the C faces of the triclinic unit cell, with an inversion center in the middle of the La(2)Cl(2) ring of the polymeric chain. International Union of Crystallography 2012-02-17 /pmc/articles/PMC3297247/ /pubmed/22412437 http://dx.doi.org/10.1107/S160053681200517X Text en © Han et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Han, Yulun
Dai, Fengrong
Sykes, Andrew G.
May, P. Stanley
Berry, Mary T.
Meng, Qingguo
Lin, Cuikun
catena-Poly[1-butyl-3-methyl­imidazolium [[dichlorido(methanol-κO)(propan-2-ol-κO)lanthanate(III)]-di-μ-chlorido]]
title catena-Poly[1-butyl-3-methyl­imidazolium [[dichlorido(methanol-κO)(propan-2-ol-κO)lanthanate(III)]-di-μ-chlorido]]
title_full catena-Poly[1-butyl-3-methyl­imidazolium [[dichlorido(methanol-κO)(propan-2-ol-κO)lanthanate(III)]-di-μ-chlorido]]
title_fullStr catena-Poly[1-butyl-3-methyl­imidazolium [[dichlorido(methanol-κO)(propan-2-ol-κO)lanthanate(III)]-di-μ-chlorido]]
title_full_unstemmed catena-Poly[1-butyl-3-methyl­imidazolium [[dichlorido(methanol-κO)(propan-2-ol-κO)lanthanate(III)]-di-μ-chlorido]]
title_short catena-Poly[1-butyl-3-methyl­imidazolium [[dichlorido(methanol-κO)(propan-2-ol-κO)lanthanate(III)]-di-μ-chlorido]]
title_sort catena-poly[1-butyl-3-methyl­imidazolium [[dichlorido(methanol-κo)(propan-2-ol-κo)lanthanate(iii)]-di-μ-chlorido]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297247/
https://www.ncbi.nlm.nih.gov/pubmed/22412437
http://dx.doi.org/10.1107/S160053681200517X
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