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(N,N,N′,N′-Tetramethylethylenediamine-κN)bis(2,4,6-trimethylphenolato-κO)germanium(II)
In the title compound, [Ge(C(9)H(11)O)(2)(C(6)H(16)N(2))], the Ge(II) atom is coordinated in a distorted trigonal–pyramidal geometry by two O atoms belonging to two 2,4,6-trimethylphenolate ligands and one N atom of a tetramethylethylenediamine ligand. Comparing the structure with published data...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297249/ https://www.ncbi.nlm.nih.gov/pubmed/22412439 http://dx.doi.org/10.1107/S160053681200503X |
| _version_ | 1782225848707842048 |
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| author | Brusylovets, Oleksii Yrushnikov, Oleg Naumova, Dina Klishin, Nikolai Rusanov, Eduard |
| author_facet | Brusylovets, Oleksii Yrushnikov, Oleg Naumova, Dina Klishin, Nikolai Rusanov, Eduard |
| author_sort | Brusylovets, Oleksii |
| collection | PubMed |
| description | In the title compound, [Ge(C(9)H(11)O)(2)(C(6)H(16)N(2))], the Ge(II) atom is coordinated in a distorted trigonal–pyramidal geometry by two O atoms belonging to two 2,4,6-trimethylphenolate ligands and one N atom of a tetramethylethylenediamine ligand. Comparing the structure with published data of similar compounds shows that the Ge—O bonds are covalent and the Ge—N bond is coordinated. |
| format | Online Article Text |
| id | pubmed-3297249 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32972492012-03-12 (N,N,N′,N′-Tetramethylethylenediamine-κN)bis(2,4,6-trimethylphenolato-κO)germanium(II) Brusylovets, Oleksii Yrushnikov, Oleg Naumova, Dina Klishin, Nikolai Rusanov, Eduard Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ge(C(9)H(11)O)(2)(C(6)H(16)N(2))], the Ge(II) atom is coordinated in a distorted trigonal–pyramidal geometry by two O atoms belonging to two 2,4,6-trimethylphenolate ligands and one N atom of a tetramethylethylenediamine ligand. Comparing the structure with published data of similar compounds shows that the Ge—O bonds are covalent and the Ge—N bond is coordinated. International Union of Crystallography 2012-02-17 /pmc/articles/PMC3297249/ /pubmed/22412439 http://dx.doi.org/10.1107/S160053681200503X Text en © Brusylovets et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Brusylovets, Oleksii Yrushnikov, Oleg Naumova, Dina Klishin, Nikolai Rusanov, Eduard (N,N,N′,N′-Tetramethylethylenediamine-κN)bis(2,4,6-trimethylphenolato-κO)germanium(II) |
| title | (N,N,N′,N′-Tetramethylethylenediamine-κN)bis(2,4,6-trimethylphenolato-κO)germanium(II) |
| title_full | (N,N,N′,N′-Tetramethylethylenediamine-κN)bis(2,4,6-trimethylphenolato-κO)germanium(II) |
| title_fullStr | (N,N,N′,N′-Tetramethylethylenediamine-κN)bis(2,4,6-trimethylphenolato-κO)germanium(II) |
| title_full_unstemmed | (N,N,N′,N′-Tetramethylethylenediamine-κN)bis(2,4,6-trimethylphenolato-κO)germanium(II) |
| title_short | (N,N,N′,N′-Tetramethylethylenediamine-κN)bis(2,4,6-trimethylphenolato-κO)germanium(II) |
| title_sort | (n,n,n′,n′-tetramethylethylenediamine-κn)bis(2,4,6-trimethylphenolato-κo)germanium(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297249/ https://www.ncbi.nlm.nih.gov/pubmed/22412439 http://dx.doi.org/10.1107/S160053681200503X |
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