Dichlorido(4′-phenyl-2,2′:6′,2′′-ter­pyridyl)zinc

The title compound, [ZnCl(2)(C(21)H(15)N(3))], was obtained from the reaction of ZnCl(2)·4H(2)O with 4′-phenyl­terpyridine (L) and disodium 2,6-dipicolinate. The Zn(2+) cation is ligated by the N atoms of the tridentate L ligand and two chloride anions, forming a ZnN(3)Cl(2) polyhedron with a distor...

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Detalles Bibliográficos
Autores principales: Ma, Zhen, Liang, Baohuan, Yang, Mei, Lu, Lingjun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297251/
https://www.ncbi.nlm.nih.gov/pubmed/22412441
http://dx.doi.org/10.1107/S1600536812004862
Descripción
Sumario:The title compound, [ZnCl(2)(C(21)H(15)N(3))], was obtained from the reaction of ZnCl(2)·4H(2)O with 4′-phenyl­terpyridine (L) and disodium 2,6-dipicolinate. The Zn(2+) cation is ligated by the N atoms of the tridentate L ligand and two chloride anions, forming a ZnN(3)Cl(2) polyhedron with a distorted trigonal–bipyramidal coordination geometry. In the crystal, nonclassical C—H⋯Cl hydrogen bonds are observed.

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