Dichlorido(4′-phenyl-2,2′:6′,2′′-ter­pyridyl)zinc

The title compound, [ZnCl(2)(C(21)H(15)N(3))], was obtained from the reaction of ZnCl(2)·4H(2)O with 4′-phenyl­terpyridine (L) and disodium 2,6-dipicolinate. The Zn(2+) cation is ligated by the N atoms of the tridentate L ligand and two chloride anions, forming a ZnN(3)Cl(2) polyhedron with a distor...

Descripción completa

Detalles Bibliográficos
Autores principales: Ma, Zhen, Liang, Baohuan, Yang, Mei, Lu, Lingjun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297251/
https://www.ncbi.nlm.nih.gov/pubmed/22412441
http://dx.doi.org/10.1107/S1600536812004862
_version_ 1782225849151389696
author Ma, Zhen
Liang, Baohuan
Yang, Mei
Lu, Lingjun
author_facet Ma, Zhen
Liang, Baohuan
Yang, Mei
Lu, Lingjun
author_sort Ma, Zhen
collection PubMed
description The title compound, [ZnCl(2)(C(21)H(15)N(3))], was obtained from the reaction of ZnCl(2)·4H(2)O with 4′-phenyl­terpyridine (L) and disodium 2,6-dipicolinate. The Zn(2+) cation is ligated by the N atoms of the tridentate L ligand and two chloride anions, forming a ZnN(3)Cl(2) polyhedron with a distorted trigonal–bipyramidal coordination geometry. In the crystal, nonclassical C—H⋯Cl hydrogen bonds are observed.
format Online
Article
Text
id pubmed-3297251
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32972512012-03-12 Dichlorido(4′-phenyl-2,2′:6′,2′′-ter­pyridyl)zinc Ma, Zhen Liang, Baohuan Yang, Mei Lu, Lingjun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [ZnCl(2)(C(21)H(15)N(3))], was obtained from the reaction of ZnCl(2)·4H(2)O with 4′-phenyl­terpyridine (L) and disodium 2,6-dipicolinate. The Zn(2+) cation is ligated by the N atoms of the tridentate L ligand and two chloride anions, forming a ZnN(3)Cl(2) polyhedron with a distorted trigonal–bipyramidal coordination geometry. In the crystal, nonclassical C—H⋯Cl hydrogen bonds are observed. International Union of Crystallography 2012-02-17 /pmc/articles/PMC3297251/ /pubmed/22412441 http://dx.doi.org/10.1107/S1600536812004862 Text en © Ma et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ma, Zhen
Liang, Baohuan
Yang, Mei
Lu, Lingjun
Dichlorido(4′-phenyl-2,2′:6′,2′′-ter­pyridyl)zinc
title Dichlorido(4′-phenyl-2,2′:6′,2′′-ter­pyridyl)zinc
title_full Dichlorido(4′-phenyl-2,2′:6′,2′′-ter­pyridyl)zinc
title_fullStr Dichlorido(4′-phenyl-2,2′:6′,2′′-ter­pyridyl)zinc
title_full_unstemmed Dichlorido(4′-phenyl-2,2′:6′,2′′-ter­pyridyl)zinc
title_short Dichlorido(4′-phenyl-2,2′:6′,2′′-ter­pyridyl)zinc
title_sort dichlorido(4′-phenyl-2,2′:6′,2′′-ter­pyridyl)zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297251/
https://www.ncbi.nlm.nih.gov/pubmed/22412441
http://dx.doi.org/10.1107/S1600536812004862
work_keys_str_mv AT mazhen dichlorido4phenyl2262terpyridylzinc
AT liangbaohuan dichlorido4phenyl2262terpyridylzinc
AT yangmei dichlorido4phenyl2262terpyridylzinc
AT lulingjun dichlorido4phenyl2262terpyridylzinc

Ejemplares similares