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Bis[[aqua(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2) N (6),N (7))cadmium]bis(μ-pyridine-2,3-dicarboxylato)-κ(3) N,O (2):O (3);κ(3) O (3):N,O (2)]
In the title compound, [Cd(2)(C(7)H(3)NO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(2)], the Cd(II) ion is six-coordinated by two N atoms from a 1H-imidazo[4,5-f][1,10]phenanthroline (IP) ligand, one N atom and one O atom from a pyridine-2,3-dicarboxylate (pdc) ligand, one O atom from another pdc ligand and o...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297253/ https://www.ncbi.nlm.nih.gov/pubmed/22412443 http://dx.doi.org/10.1107/S160053681200579X |
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author | Chen, Li-Juan Yang, Ming-Xing Huang, Hua Chen, Xiao-Hua Lin, Shen |
author_facet | Chen, Li-Juan Yang, Ming-Xing Huang, Hua Chen, Xiao-Hua Lin, Shen |
author_sort | Chen, Li-Juan |
collection | PubMed |
description | In the title compound, [Cd(2)(C(7)H(3)NO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(2)], the Cd(II) ion is six-coordinated by two N atoms from a 1H-imidazo[4,5-f][1,10]phenanthroline (IP) ligand, one N atom and one O atom from a pyridine-2,3-dicarboxylate (pdc) ligand, one O atom from another pdc ligand and one water molecule in a distorted octahedral geometry. Two Cd(II) ions are bridged by a pair of pdc ligands, forming a centrosymmetric dinuclear structure. Neighboring dinuclear units are linked by the coordinated water molecules through O—H⋯N and O—H⋯O hydrogen bonds, forming a layer parallel to (011). The layers are further linked into a three-dimensional network through N—H⋯O hydrogen bonds. π–π interactions between the IP ligands further stabilize the supramolecular structure [centroid–centroid distances = 3.579 (3), 3.686 (3), 3.710 (3), 3.766 (3) and 3.841 (3) Å]. |
format | Online Article Text |
id | pubmed-3297253 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32972532012-03-12 Bis[[aqua(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2) N (6),N (7))cadmium]bis(μ-pyridine-2,3-dicarboxylato)-κ(3) N,O (2):O (3);κ(3) O (3):N,O (2)] Chen, Li-Juan Yang, Ming-Xing Huang, Hua Chen, Xiao-Hua Lin, Shen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(2)(C(7)H(3)NO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(2)], the Cd(II) ion is six-coordinated by two N atoms from a 1H-imidazo[4,5-f][1,10]phenanthroline (IP) ligand, one N atom and one O atom from a pyridine-2,3-dicarboxylate (pdc) ligand, one O atom from another pdc ligand and one water molecule in a distorted octahedral geometry. Two Cd(II) ions are bridged by a pair of pdc ligands, forming a centrosymmetric dinuclear structure. Neighboring dinuclear units are linked by the coordinated water molecules through O—H⋯N and O—H⋯O hydrogen bonds, forming a layer parallel to (011). The layers are further linked into a three-dimensional network through N—H⋯O hydrogen bonds. π–π interactions between the IP ligands further stabilize the supramolecular structure [centroid–centroid distances = 3.579 (3), 3.686 (3), 3.710 (3), 3.766 (3) and 3.841 (3) Å]. International Union of Crystallography 2012-02-17 /pmc/articles/PMC3297253/ /pubmed/22412443 http://dx.doi.org/10.1107/S160053681200579X Text en © Chen et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Chen, Li-Juan Yang, Ming-Xing Huang, Hua Chen, Xiao-Hua Lin, Shen Bis[[aqua(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2) N (6),N (7))cadmium]bis(μ-pyridine-2,3-dicarboxylato)-κ(3) N,O (2):O (3);κ(3) O (3):N,O (2)] |
title | Bis[[aqua(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2)
N
(6),N
(7))cadmium]bis(μ-pyridine-2,3-dicarboxylato)-κ(3)
N,O
(2):O
(3);κ(3)
O
(3):N,O
(2)] |
title_full | Bis[[aqua(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2)
N
(6),N
(7))cadmium]bis(μ-pyridine-2,3-dicarboxylato)-κ(3)
N,O
(2):O
(3);κ(3)
O
(3):N,O
(2)] |
title_fullStr | Bis[[aqua(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2)
N
(6),N
(7))cadmium]bis(μ-pyridine-2,3-dicarboxylato)-κ(3)
N,O
(2):O
(3);κ(3)
O
(3):N,O
(2)] |
title_full_unstemmed | Bis[[aqua(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2)
N
(6),N
(7))cadmium]bis(μ-pyridine-2,3-dicarboxylato)-κ(3)
N,O
(2):O
(3);κ(3)
O
(3):N,O
(2)] |
title_short | Bis[[aqua(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2)
N
(6),N
(7))cadmium]bis(μ-pyridine-2,3-dicarboxylato)-κ(3)
N,O
(2):O
(3);κ(3)
O
(3):N,O
(2)] |
title_sort | bis[[aqua(1h-imidazo[4,5-f][1,10]phenanthroline-κ(2)
n
(6),n
(7))cadmium]bis(μ-pyridine-2,3-dicarboxylato)-κ(3)
n,o
(2):o
(3);κ(3)
o
(3):n,o
(2)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297253/ https://www.ncbi.nlm.nih.gov/pubmed/22412443 http://dx.doi.org/10.1107/S160053681200579X |
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