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Bis[[aqua­(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2) N (6),N (7))cadmium]bis­(μ-pyridine-2,3-dicarboxyl­ato)-κ(3) N,O (2):O (3);κ(3) O (3):N,O (2)]

In the title compound, [Cd(2)(C(7)H(3)NO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(2)], the Cd(II) ion is six-coordinated by two N atoms from a 1H-imidazo[4,5-f][1,10]phenanthroline (IP) ligand, one N atom and one O atom from a pyridine-2,3-dicarboxyl­ate (pdc) ligand, one O atom from another pdc ligand and o...

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Autores principales: Chen, Li-Juan, Yang, Ming-Xing, Huang, Hua, Chen, Xiao-Hua, Lin, Shen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297253/
https://www.ncbi.nlm.nih.gov/pubmed/22412443
http://dx.doi.org/10.1107/S160053681200579X
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author Chen, Li-Juan
Yang, Ming-Xing
Huang, Hua
Chen, Xiao-Hua
Lin, Shen
author_facet Chen, Li-Juan
Yang, Ming-Xing
Huang, Hua
Chen, Xiao-Hua
Lin, Shen
author_sort Chen, Li-Juan
collection PubMed
description In the title compound, [Cd(2)(C(7)H(3)NO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(2)], the Cd(II) ion is six-coordinated by two N atoms from a 1H-imidazo[4,5-f][1,10]phenanthroline (IP) ligand, one N atom and one O atom from a pyridine-2,3-dicarboxyl­ate (pdc) ligand, one O atom from another pdc ligand and one water mol­ecule in a distorted octa­hedral geometry. Two Cd(II) ions are bridged by a pair of pdc ligands, forming a centrosymmetric dinuclear structure. Neighboring dinuclear units are linked by the coordinated water mol­ecules through O—H⋯N and O—H⋯O hydrogen bonds, forming a layer parallel to (011). The layers are further linked into a three-dimensional network through N—H⋯O hydrogen bonds. π–π inter­actions between the IP ligands further stabilize the supra­molecular structure [centroid–centroid distances = 3.579 (3), 3.686 (3), 3.710 (3), 3.766 (3) and 3.841 (3) Å].
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spelling pubmed-32972532012-03-12 Bis[[aqua­(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2) N (6),N (7))cadmium]bis­(μ-pyridine-2,3-dicarboxyl­ato)-κ(3) N,O (2):O (3);κ(3) O (3):N,O (2)] Chen, Li-Juan Yang, Ming-Xing Huang, Hua Chen, Xiao-Hua Lin, Shen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(2)(C(7)H(3)NO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(2)], the Cd(II) ion is six-coordinated by two N atoms from a 1H-imidazo[4,5-f][1,10]phenanthroline (IP) ligand, one N atom and one O atom from a pyridine-2,3-dicarboxyl­ate (pdc) ligand, one O atom from another pdc ligand and one water mol­ecule in a distorted octa­hedral geometry. Two Cd(II) ions are bridged by a pair of pdc ligands, forming a centrosymmetric dinuclear structure. Neighboring dinuclear units are linked by the coordinated water mol­ecules through O—H⋯N and O—H⋯O hydrogen bonds, forming a layer parallel to (011). The layers are further linked into a three-dimensional network through N—H⋯O hydrogen bonds. π–π inter­actions between the IP ligands further stabilize the supra­molecular structure [centroid–centroid distances = 3.579 (3), 3.686 (3), 3.710 (3), 3.766 (3) and 3.841 (3) Å]. International Union of Crystallography 2012-02-17 /pmc/articles/PMC3297253/ /pubmed/22412443 http://dx.doi.org/10.1107/S160053681200579X Text en © Chen et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Li-Juan
Yang, Ming-Xing
Huang, Hua
Chen, Xiao-Hua
Lin, Shen
Bis[[aqua­(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2) N (6),N (7))cadmium]bis­(μ-pyridine-2,3-dicarboxyl­ato)-κ(3) N,O (2):O (3);κ(3) O (3):N,O (2)]
title Bis[[aqua­(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2) N (6),N (7))cadmium]bis­(μ-pyridine-2,3-dicarboxyl­ato)-κ(3) N,O (2):O (3);κ(3) O (3):N,O (2)]
title_full Bis[[aqua­(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2) N (6),N (7))cadmium]bis­(μ-pyridine-2,3-dicarboxyl­ato)-κ(3) N,O (2):O (3);κ(3) O (3):N,O (2)]
title_fullStr Bis[[aqua­(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2) N (6),N (7))cadmium]bis­(μ-pyridine-2,3-dicarboxyl­ato)-κ(3) N,O (2):O (3);κ(3) O (3):N,O (2)]
title_full_unstemmed Bis[[aqua­(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2) N (6),N (7))cadmium]bis­(μ-pyridine-2,3-dicarboxyl­ato)-κ(3) N,O (2):O (3);κ(3) O (3):N,O (2)]
title_short Bis[[aqua­(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2) N (6),N (7))cadmium]bis­(μ-pyridine-2,3-dicarboxyl­ato)-κ(3) N,O (2):O (3);κ(3) O (3):N,O (2)]
title_sort bis[[aqua­(1h-imidazo[4,5-f][1,10]phenanthroline-κ(2) n (6),n (7))cadmium]bis­(μ-pyridine-2,3-dicarboxyl­ato)-κ(3) n,o (2):o (3);κ(3) o (3):n,o (2)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297253/
https://www.ncbi.nlm.nih.gov/pubmed/22412443
http://dx.doi.org/10.1107/S160053681200579X
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