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(Acetylacetonato-κ(2) O,O′)bis[2-(5-methyl-3-phenylpyrazin-2-yl-κN (1))phenyl-κC (1)]iridium(III)
In the title complex, [Ir(C(17)H(13)N(2))(2)(C(5)H(7)O(2))], the Ir(III) atom is hexacoordinated in a distorted octahedral geometry by two C,N-bidentate 2-(5-methyl-3-phenylpyrazin-2-yl)phenyl (mdpp) ligands and one O,O-bidentate acetylacetonate ligand. The dihedral angles between the phenyl rin...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297258/ https://www.ncbi.nlm.nih.gov/pubmed/22412448 http://dx.doi.org/10.1107/S1600536812006022 |
| _version_ | 1782225850733690880 |
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| author | Ge, Guo-Ping Li, Chun-Yan Gu, Cheng-Hao Li, Mao-He Xu, Xiao-Nan |
| author_facet | Ge, Guo-Ping Li, Chun-Yan Gu, Cheng-Hao Li, Mao-He Xu, Xiao-Nan |
| author_sort | Ge, Guo-Ping |
| collection | PubMed |
| description | In the title complex, [Ir(C(17)H(13)N(2))(2)(C(5)H(7)O(2))], the Ir(III) atom is hexacoordinated in a distorted octahedral geometry by two C,N-bidentate 2-(5-methyl-3-phenylpyrazin-2-yl)phenyl (mdpp) ligands and one O,O-bidentate acetylacetonate ligand. The dihedral angles between the phenyl rings and the pyrazine ring are 9.56 (14) and 58.99 (14)° for one mdpp ligand and 9.34 (14) and 79.94 (15)° for the other. |
| format | Online Article Text |
| id | pubmed-3297258 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32972582012-03-12 (Acetylacetonato-κ(2) O,O′)bis[2-(5-methyl-3-phenylpyrazin-2-yl-κN (1))phenyl-κC (1)]iridium(III) Ge, Guo-Ping Li, Chun-Yan Gu, Cheng-Hao Li, Mao-He Xu, Xiao-Nan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ir(C(17)H(13)N(2))(2)(C(5)H(7)O(2))], the Ir(III) atom is hexacoordinated in a distorted octahedral geometry by two C,N-bidentate 2-(5-methyl-3-phenylpyrazin-2-yl)phenyl (mdpp) ligands and one O,O-bidentate acetylacetonate ligand. The dihedral angles between the phenyl rings and the pyrazine ring are 9.56 (14) and 58.99 (14)° for one mdpp ligand and 9.34 (14) and 79.94 (15)° for the other. International Union of Crystallography 2012-02-17 /pmc/articles/PMC3297258/ /pubmed/22412448 http://dx.doi.org/10.1107/S1600536812006022 Text en © Ge et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ge, Guo-Ping Li, Chun-Yan Gu, Cheng-Hao Li, Mao-He Xu, Xiao-Nan (Acetylacetonato-κ(2) O,O′)bis[2-(5-methyl-3-phenylpyrazin-2-yl-κN (1))phenyl-κC (1)]iridium(III) |
| title | (Acetylacetonato-κ(2)
O,O′)bis[2-(5-methyl-3-phenylpyrazin-2-yl-κN
(1))phenyl-κC
(1)]iridium(III) |
| title_full | (Acetylacetonato-κ(2)
O,O′)bis[2-(5-methyl-3-phenylpyrazin-2-yl-κN
(1))phenyl-κC
(1)]iridium(III) |
| title_fullStr | (Acetylacetonato-κ(2)
O,O′)bis[2-(5-methyl-3-phenylpyrazin-2-yl-κN
(1))phenyl-κC
(1)]iridium(III) |
| title_full_unstemmed | (Acetylacetonato-κ(2)
O,O′)bis[2-(5-methyl-3-phenylpyrazin-2-yl-κN
(1))phenyl-κC
(1)]iridium(III) |
| title_short | (Acetylacetonato-κ(2)
O,O′)bis[2-(5-methyl-3-phenylpyrazin-2-yl-κN
(1))phenyl-κC
(1)]iridium(III) |
| title_sort | (acetylacetonato-κ(2)
o,o′)bis[2-(5-methyl-3-phenylpyrazin-2-yl-κn
(1))phenyl-κc
(1)]iridium(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297258/ https://www.ncbi.nlm.nih.gov/pubmed/22412448 http://dx.doi.org/10.1107/S1600536812006022 |
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