Cargando…

Aqua­(benzamidato-κN)bis­[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC (1)]iridium(III) methanol monosolvate

In the title compound, [Ir(C(11)H(6)F(2)N)(2)(C(7)H(6)NO)(H(2)O)]·CH(3)OH, the Ir(III) ion adopts an octa­hedral geometry, and is coordinated by two 3,5-difluoro-2-(pyridin-2-yl)phenyl ligands, one mol­ecule of water and one benzamidate anion. The two 2-(4,6-difluoro­phen­yl)pyridyl ligands are arra...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Songlin, Wu, Feng, Ding, Yuqiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297261/
https://www.ncbi.nlm.nih.gov/pubmed/22412451
http://dx.doi.org/10.1107/S1600536812005922
Descripción
Sumario:In the title compound, [Ir(C(11)H(6)F(2)N)(2)(C(7)H(6)NO)(H(2)O)]·CH(3)OH, the Ir(III) ion adopts an octa­hedral geometry, and is coordinated by two 3,5-difluoro-2-(pyridin-2-yl)phenyl ligands, one mol­ecule of water and one benzamidate anion. The two 2-(4,6-difluoro­phen­yl)pyridyl ligands are arranged in a cis-C,C′ and trans-N,N′ fashion. Additionally, there is a bystanding methanol mol­ecule outside the coordination sphere of the Ir(III) ion. In the crystal, mol­ecules of the title compound are linked by O—H⋯O and O—H⋯N hydrogen bonds. One F atom of each ligand is equally disordered over two sites. The C atom of the solvent molecule is likewise disordered over two sites in a 0.589 (11):0.411 (11) ratio.