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Aqua­(benzamidato-κN)bis­[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC (1)]iridium(III) methanol monosolvate

In the title compound, [Ir(C(11)H(6)F(2)N)(2)(C(7)H(6)NO)(H(2)O)]·CH(3)OH, the Ir(III) ion adopts an octa­hedral geometry, and is coordinated by two 3,5-difluoro-2-(pyridin-2-yl)phenyl ligands, one mol­ecule of water and one benzamidate anion. The two 2-(4,6-difluoro­phen­yl)pyridyl ligands are arra...

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Detalles Bibliográficos
Autores principales: Zhang, Songlin, Wu, Feng, Ding, Yuqiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297261/
https://www.ncbi.nlm.nih.gov/pubmed/22412451
http://dx.doi.org/10.1107/S1600536812005922
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author Zhang, Songlin
Wu, Feng
Ding, Yuqiang
author_facet Zhang, Songlin
Wu, Feng
Ding, Yuqiang
author_sort Zhang, Songlin
collection PubMed
description In the title compound, [Ir(C(11)H(6)F(2)N)(2)(C(7)H(6)NO)(H(2)O)]·CH(3)OH, the Ir(III) ion adopts an octa­hedral geometry, and is coordinated by two 3,5-difluoro-2-(pyridin-2-yl)phenyl ligands, one mol­ecule of water and one benzamidate anion. The two 2-(4,6-difluoro­phen­yl)pyridyl ligands are arranged in a cis-C,C′ and trans-N,N′ fashion. Additionally, there is a bystanding methanol mol­ecule outside the coordination sphere of the Ir(III) ion. In the crystal, mol­ecules of the title compound are linked by O—H⋯O and O—H⋯N hydrogen bonds. One F atom of each ligand is equally disordered over two sites. The C atom of the solvent molecule is likewise disordered over two sites in a 0.589 (11):0.411 (11) ratio.
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spelling pubmed-32972612012-03-12 Aqua­(benzamidato-κN)bis­[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC (1)]iridium(III) methanol monosolvate Zhang, Songlin Wu, Feng Ding, Yuqiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ir(C(11)H(6)F(2)N)(2)(C(7)H(6)NO)(H(2)O)]·CH(3)OH, the Ir(III) ion adopts an octa­hedral geometry, and is coordinated by two 3,5-difluoro-2-(pyridin-2-yl)phenyl ligands, one mol­ecule of water and one benzamidate anion. The two 2-(4,6-difluoro­phen­yl)pyridyl ligands are arranged in a cis-C,C′ and trans-N,N′ fashion. Additionally, there is a bystanding methanol mol­ecule outside the coordination sphere of the Ir(III) ion. In the crystal, mol­ecules of the title compound are linked by O—H⋯O and O—H⋯N hydrogen bonds. One F atom of each ligand is equally disordered over two sites. The C atom of the solvent molecule is likewise disordered over two sites in a 0.589 (11):0.411 (11) ratio. International Union of Crystallography 2012-02-17 /pmc/articles/PMC3297261/ /pubmed/22412451 http://dx.doi.org/10.1107/S1600536812005922 Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Songlin
Wu, Feng
Ding, Yuqiang
Aqua­(benzamidato-κN)bis­[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC (1)]iridium(III) methanol monosolvate
title Aqua­(benzamidato-κN)bis­[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC (1)]iridium(III) methanol monosolvate
title_full Aqua­(benzamidato-κN)bis­[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC (1)]iridium(III) methanol monosolvate
title_fullStr Aqua­(benzamidato-κN)bis­[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC (1)]iridium(III) methanol monosolvate
title_full_unstemmed Aqua­(benzamidato-κN)bis­[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC (1)]iridium(III) methanol monosolvate
title_short Aqua­(benzamidato-κN)bis­[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC (1)]iridium(III) methanol monosolvate
title_sort aqua­(benzamidato-κn)bis­[3,5-difluoro-2-(pyridin-2-yl)phenyl-κc (1)]iridium(iii) methanol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297261/
https://www.ncbi.nlm.nih.gov/pubmed/22412451
http://dx.doi.org/10.1107/S1600536812005922
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