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Aqua(benzamidato-κN)bis[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC (1)]iridium(III) methanol monosolvate
In the title compound, [Ir(C(11)H(6)F(2)N)(2)(C(7)H(6)NO)(H(2)O)]·CH(3)OH, the Ir(III) ion adopts an octahedral geometry, and is coordinated by two 3,5-difluoro-2-(pyridin-2-yl)phenyl ligands, one molecule of water and one benzamidate anion. The two 2-(4,6-difluorophenyl)pyridyl ligands are arra...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297261/ https://www.ncbi.nlm.nih.gov/pubmed/22412451 http://dx.doi.org/10.1107/S1600536812005922 |
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author | Zhang, Songlin Wu, Feng Ding, Yuqiang |
author_facet | Zhang, Songlin Wu, Feng Ding, Yuqiang |
author_sort | Zhang, Songlin |
collection | PubMed |
description | In the title compound, [Ir(C(11)H(6)F(2)N)(2)(C(7)H(6)NO)(H(2)O)]·CH(3)OH, the Ir(III) ion adopts an octahedral geometry, and is coordinated by two 3,5-difluoro-2-(pyridin-2-yl)phenyl ligands, one molecule of water and one benzamidate anion. The two 2-(4,6-difluorophenyl)pyridyl ligands are arranged in a cis-C,C′ and trans-N,N′ fashion. Additionally, there is a bystanding methanol molecule outside the coordination sphere of the Ir(III) ion. In the crystal, molecules of the title compound are linked by O—H⋯O and O—H⋯N hydrogen bonds. One F atom of each ligand is equally disordered over two sites. The C atom of the solvent molecule is likewise disordered over two sites in a 0.589 (11):0.411 (11) ratio. |
format | Online Article Text |
id | pubmed-3297261 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32972612012-03-12 Aqua(benzamidato-κN)bis[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC (1)]iridium(III) methanol monosolvate Zhang, Songlin Wu, Feng Ding, Yuqiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ir(C(11)H(6)F(2)N)(2)(C(7)H(6)NO)(H(2)O)]·CH(3)OH, the Ir(III) ion adopts an octahedral geometry, and is coordinated by two 3,5-difluoro-2-(pyridin-2-yl)phenyl ligands, one molecule of water and one benzamidate anion. The two 2-(4,6-difluorophenyl)pyridyl ligands are arranged in a cis-C,C′ and trans-N,N′ fashion. Additionally, there is a bystanding methanol molecule outside the coordination sphere of the Ir(III) ion. In the crystal, molecules of the title compound are linked by O—H⋯O and O—H⋯N hydrogen bonds. One F atom of each ligand is equally disordered over two sites. The C atom of the solvent molecule is likewise disordered over two sites in a 0.589 (11):0.411 (11) ratio. International Union of Crystallography 2012-02-17 /pmc/articles/PMC3297261/ /pubmed/22412451 http://dx.doi.org/10.1107/S1600536812005922 Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Songlin Wu, Feng Ding, Yuqiang Aqua(benzamidato-κN)bis[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC (1)]iridium(III) methanol monosolvate |
title | Aqua(benzamidato-κN)bis[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC
(1)]iridium(III) methanol monosolvate |
title_full | Aqua(benzamidato-κN)bis[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC
(1)]iridium(III) methanol monosolvate |
title_fullStr | Aqua(benzamidato-κN)bis[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC
(1)]iridium(III) methanol monosolvate |
title_full_unstemmed | Aqua(benzamidato-κN)bis[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC
(1)]iridium(III) methanol monosolvate |
title_short | Aqua(benzamidato-κN)bis[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC
(1)]iridium(III) methanol monosolvate |
title_sort | aqua(benzamidato-κn)bis[3,5-difluoro-2-(pyridin-2-yl)phenyl-κc
(1)]iridium(iii) methanol monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297261/ https://www.ncbi.nlm.nih.gov/pubmed/22412451 http://dx.doi.org/10.1107/S1600536812005922 |
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