Dichlorido{2-[(2,6-dimethyl­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}zinc

In the asymmetric unit of the title compound, [ZnCl(2)(C(14)H(14)N(2))], the central Zn(II) ion is four-coordinated in a distorted tetra­hedral environment by two N atoms of the ligand 2-[(2,6-dimethyl­phen­yl)imino­meth­yl]pyridine and two chloride anions. In the crystal, adjacent mol­ecules are co...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Xue-hong, Zhao, Li-min, Liu, Feng-shou
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297262/
https://www.ncbi.nlm.nih.gov/pubmed/22412452
http://dx.doi.org/10.1107/S1600536812006204
Descripción
Sumario:In the asymmetric unit of the title compound, [ZnCl(2)(C(14)H(14)N(2))], the central Zn(II) ion is four-coordinated in a distorted tetra­hedral environment by two N atoms of the ligand 2-[(2,6-dimethyl­phen­yl)imino­meth­yl]pyridine and two chloride anions. In the crystal, adjacent mol­ecules are connected through C—H⋯Cl hydrogen bonds between a C—H group of the ligand and a Cl(−) anion, leading to a chain-like structure along the b direction.

Ejemplares similares