Cargando…
Dichlorido{2-[(2,6-dimethylphenyl)iminomethyl]pyridine-κ(2) N,N′}zinc
In the asymmetric unit of the title compound, [ZnCl(2)(C(14)H(14)N(2))], the central Zn(II) ion is four-coordinated in a distorted tetrahedral environment by two N atoms of the ligand 2-[(2,6-dimethylphenyl)iminomethyl]pyridine and two chloride anions. In the crystal, adjacent molecules are co...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297262/ https://www.ncbi.nlm.nih.gov/pubmed/22412452 http://dx.doi.org/10.1107/S1600536812006204 |
_version_ | 1782225851639660544 |
---|---|
author | Liu, Xue-hong Zhao, Li-min Liu, Feng-shou |
author_facet | Liu, Xue-hong Zhao, Li-min Liu, Feng-shou |
author_sort | Liu, Xue-hong |
collection | PubMed |
description | In the asymmetric unit of the title compound, [ZnCl(2)(C(14)H(14)N(2))], the central Zn(II) ion is four-coordinated in a distorted tetrahedral environment by two N atoms of the ligand 2-[(2,6-dimethylphenyl)iminomethyl]pyridine and two chloride anions. In the crystal, adjacent molecules are connected through C—H⋯Cl hydrogen bonds between a C—H group of the ligand and a Cl(−) anion, leading to a chain-like structure along the b direction. |
format | Online Article Text |
id | pubmed-3297262 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32972622012-03-12 Dichlorido{2-[(2,6-dimethylphenyl)iminomethyl]pyridine-κ(2) N,N′}zinc Liu, Xue-hong Zhao, Li-min Liu, Feng-shou Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the asymmetric unit of the title compound, [ZnCl(2)(C(14)H(14)N(2))], the central Zn(II) ion is four-coordinated in a distorted tetrahedral environment by two N atoms of the ligand 2-[(2,6-dimethylphenyl)iminomethyl]pyridine and two chloride anions. In the crystal, adjacent molecules are connected through C—H⋯Cl hydrogen bonds between a C—H group of the ligand and a Cl(−) anion, leading to a chain-like structure along the b direction. International Union of Crystallography 2012-02-24 /pmc/articles/PMC3297262/ /pubmed/22412452 http://dx.doi.org/10.1107/S1600536812006204 Text en © Liu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Xue-hong Zhao, Li-min Liu, Feng-shou Dichlorido{2-[(2,6-dimethylphenyl)iminomethyl]pyridine-κ(2) N,N′}zinc |
title | Dichlorido{2-[(2,6-dimethylphenyl)iminomethyl]pyridine-κ(2)
N,N′}zinc |
title_full | Dichlorido{2-[(2,6-dimethylphenyl)iminomethyl]pyridine-κ(2)
N,N′}zinc |
title_fullStr | Dichlorido{2-[(2,6-dimethylphenyl)iminomethyl]pyridine-κ(2)
N,N′}zinc |
title_full_unstemmed | Dichlorido{2-[(2,6-dimethylphenyl)iminomethyl]pyridine-κ(2)
N,N′}zinc |
title_short | Dichlorido{2-[(2,6-dimethylphenyl)iminomethyl]pyridine-κ(2)
N,N′}zinc |
title_sort | dichlorido{2-[(2,6-dimethylphenyl)iminomethyl]pyridine-κ(2)
n,n′}zinc |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297262/ https://www.ncbi.nlm.nih.gov/pubmed/22412452 http://dx.doi.org/10.1107/S1600536812006204 |
work_keys_str_mv | AT liuxuehong dichlorido226dimethylphenyliminomethylpyridinek2nnzinc AT zhaolimin dichlorido226dimethylphenyliminomethylpyridinek2nnzinc AT liufengshou dichlorido226dimethylphenyliminomethylpyridinek2nnzinc |