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{S-Benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) monohydrate
The structure of the title compound, [Ni(C(15)H(14)N(3)S(2))(2)]·H(2)O, has one molecule in the asymmetric unit, along with a solvent water molecule. The two different Schiff base moieties coordinate to the central Ni(II) ion as tridentate N,N′,S-chelating ligands, creating a six-coordinate distor...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297266/ https://www.ncbi.nlm.nih.gov/pubmed/22412456 http://dx.doi.org/10.1107/S1600536812006952 |
Sumario: | The structure of the title compound, [Ni(C(15)H(14)N(3)S(2))(2)]·H(2)O, has one molecule in the asymmetric unit, along with a solvent water molecule. The two different Schiff base moieties coordinate to the central Ni(II) ion as tridentate N,N′,S-chelating ligands, creating a six-coordinate distorted octahedral environment [the smallest angle being 77.43 (7)° and the widest angle being 169.99 (7)°]. The mean planes of the two ligands are nearly orthogonal to each other with an angle of 89.53 (6)°. The packing of the complex is supported by O—H⋯N and O—H⋯S hydrogen bonding between the solvent water molecule and the uncoordinated N and S atoms of neighbouring ligands. |
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