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{S-Benzyl 3-[(6-methyl­pyridin-2-yl)­methyl­idene]dithio­carbazato}nickel(II) monohydrate

The structure of the title compound, [Ni(C(15)H(14)N(3)S(2))(2)]·H(2)O, has one mol­ecule in the asymmetric unit, along with a solvent water mol­ecule. The two different Schiff base moieties coordinate to the central Ni(II) ion as tridentate N,N′,S-chelating ligands, creating a six-coordinate distor...

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Detalles Bibliográficos
Autores principales: Omar, Siti Aminah, Ravoof, Thahira B. S. A., Mohamed Tahir, Mohamed Ibrahim, Crouse, Karen A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297266/
https://www.ncbi.nlm.nih.gov/pubmed/22412456
http://dx.doi.org/10.1107/S1600536812006952
Descripción
Sumario:The structure of the title compound, [Ni(C(15)H(14)N(3)S(2))(2)]·H(2)O, has one mol­ecule in the asymmetric unit, along with a solvent water mol­ecule. The two different Schiff base moieties coordinate to the central Ni(II) ion as tridentate N,N′,S-chelating ligands, creating a six-coordinate distorted octa­hedral environment [the smallest angle being 77.43 (7)° and the widest angle being 169.99 (7)°]. The mean planes of the two ligands are nearly orthogonal to each other with an angle of 89.53 (6)°. The packing of the complex is supported by O—H⋯N and O—H⋯S hydrogen bonding between the solvent water mol­ecule and the uncoordinated N and S atoms of neighbouring ligands.