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{S-Benzyl 3-[(6-methyl­pyridin-2-yl)­methyl­idene]dithio­carbazato}nickel(II) monohydrate

The structure of the title compound, [Ni(C(15)H(14)N(3)S(2))(2)]·H(2)O, has one mol­ecule in the asymmetric unit, along with a solvent water mol­ecule. The two different Schiff base moieties coordinate to the central Ni(II) ion as tridentate N,N′,S-chelating ligands, creating a six-coordinate distor...

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Autores principales: Omar, Siti Aminah, Ravoof, Thahira B. S. A., Mohamed Tahir, Mohamed Ibrahim, Crouse, Karen A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297266/
https://www.ncbi.nlm.nih.gov/pubmed/22412456
http://dx.doi.org/10.1107/S1600536812006952
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author Omar, Siti Aminah
Ravoof, Thahira B. S. A.
Mohamed Tahir, Mohamed Ibrahim
Crouse, Karen A.
author_facet Omar, Siti Aminah
Ravoof, Thahira B. S. A.
Mohamed Tahir, Mohamed Ibrahim
Crouse, Karen A.
author_sort Omar, Siti Aminah
collection PubMed
description The structure of the title compound, [Ni(C(15)H(14)N(3)S(2))(2)]·H(2)O, has one mol­ecule in the asymmetric unit, along with a solvent water mol­ecule. The two different Schiff base moieties coordinate to the central Ni(II) ion as tridentate N,N′,S-chelating ligands, creating a six-coordinate distorted octa­hedral environment [the smallest angle being 77.43 (7)° and the widest angle being 169.99 (7)°]. The mean planes of the two ligands are nearly orthogonal to each other with an angle of 89.53 (6)°. The packing of the complex is supported by O—H⋯N and O—H⋯S hydrogen bonding between the solvent water mol­ecule and the uncoordinated N and S atoms of neighbouring ligands.
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spelling pubmed-32972662012-03-12 {S-Benzyl 3-[(6-methyl­pyridin-2-yl)­methyl­idene]dithio­carbazato}nickel(II) monohydrate Omar, Siti Aminah Ravoof, Thahira B. S. A. Mohamed Tahir, Mohamed Ibrahim Crouse, Karen A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Ni(C(15)H(14)N(3)S(2))(2)]·H(2)O, has one mol­ecule in the asymmetric unit, along with a solvent water mol­ecule. The two different Schiff base moieties coordinate to the central Ni(II) ion as tridentate N,N′,S-chelating ligands, creating a six-coordinate distorted octa­hedral environment [the smallest angle being 77.43 (7)° and the widest angle being 169.99 (7)°]. The mean planes of the two ligands are nearly orthogonal to each other with an angle of 89.53 (6)°. The packing of the complex is supported by O—H⋯N and O—H⋯S hydrogen bonding between the solvent water mol­ecule and the uncoordinated N and S atoms of neighbouring ligands. International Union of Crystallography 2012-02-24 /pmc/articles/PMC3297266/ /pubmed/22412456 http://dx.doi.org/10.1107/S1600536812006952 Text en © Omar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Omar, Siti Aminah
Ravoof, Thahira B. S. A.
Mohamed Tahir, Mohamed Ibrahim
Crouse, Karen A.
{S-Benzyl 3-[(6-methyl­pyridin-2-yl)­methyl­idene]dithio­carbazato}nickel(II) monohydrate
title {S-Benzyl 3-[(6-methyl­pyridin-2-yl)­methyl­idene]dithio­carbazato}nickel(II) monohydrate
title_full {S-Benzyl 3-[(6-methyl­pyridin-2-yl)­methyl­idene]dithio­carbazato}nickel(II) monohydrate
title_fullStr {S-Benzyl 3-[(6-methyl­pyridin-2-yl)­methyl­idene]dithio­carbazato}nickel(II) monohydrate
title_full_unstemmed {S-Benzyl 3-[(6-methyl­pyridin-2-yl)­methyl­idene]dithio­carbazato}nickel(II) monohydrate
title_short {S-Benzyl 3-[(6-methyl­pyridin-2-yl)­methyl­idene]dithio­carbazato}nickel(II) monohydrate
title_sort {s-benzyl 3-[(6-methyl­pyridin-2-yl)­methyl­idene]dithio­carbazato}nickel(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297266/
https://www.ncbi.nlm.nih.gov/pubmed/22412456
http://dx.doi.org/10.1107/S1600536812006952
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