Cargando…
{S-Benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) monohydrate
The structure of the title compound, [Ni(C(15)H(14)N(3)S(2))(2)]·H(2)O, has one molecule in the asymmetric unit, along with a solvent water molecule. The two different Schiff base moieties coordinate to the central Ni(II) ion as tridentate N,N′,S-chelating ligands, creating a six-coordinate distor...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297266/ https://www.ncbi.nlm.nih.gov/pubmed/22412456 http://dx.doi.org/10.1107/S1600536812006952 |
_version_ | 1782225852551921664 |
---|---|
author | Omar, Siti Aminah Ravoof, Thahira B. S. A. Mohamed Tahir, Mohamed Ibrahim Crouse, Karen A. |
author_facet | Omar, Siti Aminah Ravoof, Thahira B. S. A. Mohamed Tahir, Mohamed Ibrahim Crouse, Karen A. |
author_sort | Omar, Siti Aminah |
collection | PubMed |
description | The structure of the title compound, [Ni(C(15)H(14)N(3)S(2))(2)]·H(2)O, has one molecule in the asymmetric unit, along with a solvent water molecule. The two different Schiff base moieties coordinate to the central Ni(II) ion as tridentate N,N′,S-chelating ligands, creating a six-coordinate distorted octahedral environment [the smallest angle being 77.43 (7)° and the widest angle being 169.99 (7)°]. The mean planes of the two ligands are nearly orthogonal to each other with an angle of 89.53 (6)°. The packing of the complex is supported by O—H⋯N and O—H⋯S hydrogen bonding between the solvent water molecule and the uncoordinated N and S atoms of neighbouring ligands. |
format | Online Article Text |
id | pubmed-3297266 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32972662012-03-12 {S-Benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) monohydrate Omar, Siti Aminah Ravoof, Thahira B. S. A. Mohamed Tahir, Mohamed Ibrahim Crouse, Karen A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Ni(C(15)H(14)N(3)S(2))(2)]·H(2)O, has one molecule in the asymmetric unit, along with a solvent water molecule. The two different Schiff base moieties coordinate to the central Ni(II) ion as tridentate N,N′,S-chelating ligands, creating a six-coordinate distorted octahedral environment [the smallest angle being 77.43 (7)° and the widest angle being 169.99 (7)°]. The mean planes of the two ligands are nearly orthogonal to each other with an angle of 89.53 (6)°. The packing of the complex is supported by O—H⋯N and O—H⋯S hydrogen bonding between the solvent water molecule and the uncoordinated N and S atoms of neighbouring ligands. International Union of Crystallography 2012-02-24 /pmc/articles/PMC3297266/ /pubmed/22412456 http://dx.doi.org/10.1107/S1600536812006952 Text en © Omar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Omar, Siti Aminah Ravoof, Thahira B. S. A. Mohamed Tahir, Mohamed Ibrahim Crouse, Karen A. {S-Benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) monohydrate |
title | {S-Benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) monohydrate |
title_full | {S-Benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) monohydrate |
title_fullStr | {S-Benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) monohydrate |
title_full_unstemmed | {S-Benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) monohydrate |
title_short | {S-Benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) monohydrate |
title_sort | {s-benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(ii) monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297266/ https://www.ncbi.nlm.nih.gov/pubmed/22412456 http://dx.doi.org/10.1107/S1600536812006952 |
work_keys_str_mv | AT omarsitiaminah sbenzyl36methylpyridin2ylmethylidenedithiocarbazatonickeliimonohydrate AT ravoofthahirabsa sbenzyl36methylpyridin2ylmethylidenedithiocarbazatonickeliimonohydrate AT mohamedtahirmohamedibrahim sbenzyl36methylpyridin2ylmethylidenedithiocarbazatonickeliimonohydrate AT crousekarena sbenzyl36methylpyridin2ylmethylidenedithiocarbazatonickeliimonohydrate |