Bis[N-(2-hy­droxy­eth­yl)-N-methyl­dithio­carbamato-κS][2,4,6-tris­(pyridin-2-yl)-1,3,5-triazine-κ(3) N (1),N (2),N (6)]zinc dioxane sesquisolvate

The asymmetric unit of the title compound, [Zn(C(4)H(8)NOS(2))(2)(C(18)H(12)N(6))]·1.5C(4)H(8)O(2), comprises a Zn-containing mol­ecule and one and a half dioxane mol­ecules as one of the solvent mol­ecules is located about a crystallographic inversion centre. The approximately square-pyramidal N(3)...

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Autores principales: Arman, Hadi D., Poplaukhin, Pavel, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297268/
https://www.ncbi.nlm.nih.gov/pubmed/22412458
http://dx.doi.org/10.1107/S160053681200671X
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author Arman, Hadi D.
Poplaukhin, Pavel
Tiekink, Edward R. T.
author_facet Arman, Hadi D.
Poplaukhin, Pavel
Tiekink, Edward R. T.
author_sort Arman, Hadi D.
collection PubMed
description The asymmetric unit of the title compound, [Zn(C(4)H(8)NOS(2))(2)(C(18)H(12)N(6))]·1.5C(4)H(8)O(2), comprises a Zn-containing mol­ecule and one and a half dioxane mol­ecules as one of the solvent mol­ecules is located about a crystallographic inversion centre. The approximately square-pyramidal N(3)S(2) donor set is defined by two monodentate dithio­carbamate ligands and two pyridine and one triazine N atom from the tridentate triazine ligand. Mol­ecules are connected into a supra­molecular array via O—H⋯S and O—H⋯N hydrogen bonds. These stack along the b axis and the solvent mol­ecules reside in the channels thus formed.
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spelling pubmed-32972682012-03-12 Bis[N-(2-hy­droxy­eth­yl)-N-methyl­dithio­carbamato-κS][2,4,6-tris­(pyridin-2-yl)-1,3,5-triazine-κ(3) N (1),N (2),N (6)]zinc dioxane sesquisolvate Arman, Hadi D. Poplaukhin, Pavel Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Zn(C(4)H(8)NOS(2))(2)(C(18)H(12)N(6))]·1.5C(4)H(8)O(2), comprises a Zn-containing mol­ecule and one and a half dioxane mol­ecules as one of the solvent mol­ecules is located about a crystallographic inversion centre. The approximately square-pyramidal N(3)S(2) donor set is defined by two monodentate dithio­carbamate ligands and two pyridine and one triazine N atom from the tridentate triazine ligand. Mol­ecules are connected into a supra­molecular array via O—H⋯S and O—H⋯N hydrogen bonds. These stack along the b axis and the solvent mol­ecules reside in the channels thus formed. International Union of Crystallography 2012-02-24 /pmc/articles/PMC3297268/ /pubmed/22412458 http://dx.doi.org/10.1107/S160053681200671X Text en © Arman et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Arman, Hadi D.
Poplaukhin, Pavel
Tiekink, Edward R. T.
Bis[N-(2-hy­droxy­eth­yl)-N-methyl­dithio­carbamato-κS][2,4,6-tris­(pyridin-2-yl)-1,3,5-triazine-κ(3) N (1),N (2),N (6)]zinc dioxane sesquisolvate
title Bis[N-(2-hy­droxy­eth­yl)-N-methyl­dithio­carbamato-κS][2,4,6-tris­(pyridin-2-yl)-1,3,5-triazine-κ(3) N (1),N (2),N (6)]zinc dioxane sesquisolvate
title_full Bis[N-(2-hy­droxy­eth­yl)-N-methyl­dithio­carbamato-κS][2,4,6-tris­(pyridin-2-yl)-1,3,5-triazine-κ(3) N (1),N (2),N (6)]zinc dioxane sesquisolvate
title_fullStr Bis[N-(2-hy­droxy­eth­yl)-N-methyl­dithio­carbamato-κS][2,4,6-tris­(pyridin-2-yl)-1,3,5-triazine-κ(3) N (1),N (2),N (6)]zinc dioxane sesquisolvate
title_full_unstemmed Bis[N-(2-hy­droxy­eth­yl)-N-methyl­dithio­carbamato-κS][2,4,6-tris­(pyridin-2-yl)-1,3,5-triazine-κ(3) N (1),N (2),N (6)]zinc dioxane sesquisolvate
title_short Bis[N-(2-hy­droxy­eth­yl)-N-methyl­dithio­carbamato-κS][2,4,6-tris­(pyridin-2-yl)-1,3,5-triazine-κ(3) N (1),N (2),N (6)]zinc dioxane sesquisolvate
title_sort bis[n-(2-hy­droxy­eth­yl)-n-methyl­dithio­carbamato-κs][2,4,6-tris­(pyridin-2-yl)-1,3,5-triazine-κ(3) n (1),n (2),n (6)]zinc dioxane sesquisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297268/
https://www.ncbi.nlm.nih.gov/pubmed/22412458
http://dx.doi.org/10.1107/S160053681200671X
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AT tiekinkedwardrt bisn2hydroxyethylnmethyldithiocarbamatoks246trispyridin2yl135triazinek3n1n2n6zincdioxanesesquisolvate

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