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(2,2′-Bipyridine-κ(2) N,N′)bis­(4-chloro­benzoato-κO)zinc

In the title compound, [Zn(C(7)H(4)ClO(2))(2)(C(10)H(8)N(2))], the Zn(II) atom is coordinated by two O atoms from two 4-chloro­benzoate ligands and two N atoms from a chelating 2,2′-bipyridine (bpy) mol­ecule in a distorted N(2)O(2) tetra­hedral geometry. The Zn(II) atom is located on a twofold rota...

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Detalles Bibliográficos
Autores principales: Zhang, Bi-Song, Zhu, Hong-Line, Li, Jun, Dai, Dong-Dong, Peng, Yi-Bao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297269/
https://www.ncbi.nlm.nih.gov/pubmed/22412459
http://dx.doi.org/10.1107/S160053681200699X
Descripción
Sumario:In the title compound, [Zn(C(7)H(4)ClO(2))(2)(C(10)H(8)N(2))], the Zn(II) atom is coordinated by two O atoms from two 4-chloro­benzoate ligands and two N atoms from a chelating 2,2′-bipyridine (bpy) mol­ecule in a distorted N(2)O(2) tetra­hedral geometry. The Zn(II) atom is located on a twofold rotation axis, which also passes through the mid-point of the central C—C bond of the bpy ligand. In the crystal, weak C—H⋯O hydrogen bonds and π–π stacking inter­actions between the pyridine rings of the bpy ligands [centroid–centroid distance = 3.642 (3) Å] link the complex mol­ecules into a two-dimensional supra­molecular structure parallel to (100). An intra­molecular C—H⋯O hydrogen bond is also observed.