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(2,2′-Bipyridine-κ(2) N,N′)bis­(4-chloro­benzoato-κO)zinc

In the title compound, [Zn(C(7)H(4)ClO(2))(2)(C(10)H(8)N(2))], the Zn(II) atom is coordinated by two O atoms from two 4-chloro­benzoate ligands and two N atoms from a chelating 2,2′-bipyridine (bpy) mol­ecule in a distorted N(2)O(2) tetra­hedral geometry. The Zn(II) atom is located on a twofold rota...

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Autores principales: Zhang, Bi-Song, Zhu, Hong-Line, Li, Jun, Dai, Dong-Dong, Peng, Yi-Bao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297269/
https://www.ncbi.nlm.nih.gov/pubmed/22412459
http://dx.doi.org/10.1107/S160053681200699X
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author Zhang, Bi-Song
Zhu, Hong-Line
Li, Jun
Dai, Dong-Dong
Peng, Yi-Bao
author_facet Zhang, Bi-Song
Zhu, Hong-Line
Li, Jun
Dai, Dong-Dong
Peng, Yi-Bao
author_sort Zhang, Bi-Song
collection PubMed
description In the title compound, [Zn(C(7)H(4)ClO(2))(2)(C(10)H(8)N(2))], the Zn(II) atom is coordinated by two O atoms from two 4-chloro­benzoate ligands and two N atoms from a chelating 2,2′-bipyridine (bpy) mol­ecule in a distorted N(2)O(2) tetra­hedral geometry. The Zn(II) atom is located on a twofold rotation axis, which also passes through the mid-point of the central C—C bond of the bpy ligand. In the crystal, weak C—H⋯O hydrogen bonds and π–π stacking inter­actions between the pyridine rings of the bpy ligands [centroid–centroid distance = 3.642 (3) Å] link the complex mol­ecules into a two-dimensional supra­molecular structure parallel to (100). An intra­molecular C—H⋯O hydrogen bond is also observed.
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spelling pubmed-32972692012-03-12 (2,2′-Bipyridine-κ(2) N,N′)bis­(4-chloro­benzoato-κO)zinc Zhang, Bi-Song Zhu, Hong-Line Li, Jun Dai, Dong-Dong Peng, Yi-Bao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(7)H(4)ClO(2))(2)(C(10)H(8)N(2))], the Zn(II) atom is coordinated by two O atoms from two 4-chloro­benzoate ligands and two N atoms from a chelating 2,2′-bipyridine (bpy) mol­ecule in a distorted N(2)O(2) tetra­hedral geometry. The Zn(II) atom is located on a twofold rotation axis, which also passes through the mid-point of the central C—C bond of the bpy ligand. In the crystal, weak C—H⋯O hydrogen bonds and π–π stacking inter­actions between the pyridine rings of the bpy ligands [centroid–centroid distance = 3.642 (3) Å] link the complex mol­ecules into a two-dimensional supra­molecular structure parallel to (100). An intra­molecular C—H⋯O hydrogen bond is also observed. International Union of Crystallography 2012-02-24 /pmc/articles/PMC3297269/ /pubmed/22412459 http://dx.doi.org/10.1107/S160053681200699X Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Bi-Song
Zhu, Hong-Line
Li, Jun
Dai, Dong-Dong
Peng, Yi-Bao
(2,2′-Bipyridine-κ(2) N,N′)bis­(4-chloro­benzoato-κO)zinc
title (2,2′-Bipyridine-κ(2) N,N′)bis­(4-chloro­benzoato-κO)zinc
title_full (2,2′-Bipyridine-κ(2) N,N′)bis­(4-chloro­benzoato-κO)zinc
title_fullStr (2,2′-Bipyridine-κ(2) N,N′)bis­(4-chloro­benzoato-κO)zinc
title_full_unstemmed (2,2′-Bipyridine-κ(2) N,N′)bis­(4-chloro­benzoato-κO)zinc
title_short (2,2′-Bipyridine-κ(2) N,N′)bis­(4-chloro­benzoato-κO)zinc
title_sort (2,2′-bipyridine-κ(2) n,n′)bis­(4-chloro­benzoato-κo)zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297269/
https://www.ncbi.nlm.nih.gov/pubmed/22412459
http://dx.doi.org/10.1107/S160053681200699X
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