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(2,2′-Bipyridine-κ(2) N,N′)bis(4-chlorobenzoato-κO)zinc
In the title compound, [Zn(C(7)H(4)ClO(2))(2)(C(10)H(8)N(2))], the Zn(II) atom is coordinated by two O atoms from two 4-chlorobenzoate ligands and two N atoms from a chelating 2,2′-bipyridine (bpy) molecule in a distorted N(2)O(2) tetrahedral geometry. The Zn(II) atom is located on a twofold rota...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297269/ https://www.ncbi.nlm.nih.gov/pubmed/22412459 http://dx.doi.org/10.1107/S160053681200699X |
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author | Zhang, Bi-Song Zhu, Hong-Line Li, Jun Dai, Dong-Dong Peng, Yi-Bao |
author_facet | Zhang, Bi-Song Zhu, Hong-Line Li, Jun Dai, Dong-Dong Peng, Yi-Bao |
author_sort | Zhang, Bi-Song |
collection | PubMed |
description | In the title compound, [Zn(C(7)H(4)ClO(2))(2)(C(10)H(8)N(2))], the Zn(II) atom is coordinated by two O atoms from two 4-chlorobenzoate ligands and two N atoms from a chelating 2,2′-bipyridine (bpy) molecule in a distorted N(2)O(2) tetrahedral geometry. The Zn(II) atom is located on a twofold rotation axis, which also passes through the mid-point of the central C—C bond of the bpy ligand. In the crystal, weak C—H⋯O hydrogen bonds and π–π stacking interactions between the pyridine rings of the bpy ligands [centroid–centroid distance = 3.642 (3) Å] link the complex molecules into a two-dimensional supramolecular structure parallel to (100). An intramolecular C—H⋯O hydrogen bond is also observed. |
format | Online Article Text |
id | pubmed-3297269 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32972692012-03-12 (2,2′-Bipyridine-κ(2) N,N′)bis(4-chlorobenzoato-κO)zinc Zhang, Bi-Song Zhu, Hong-Line Li, Jun Dai, Dong-Dong Peng, Yi-Bao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(7)H(4)ClO(2))(2)(C(10)H(8)N(2))], the Zn(II) atom is coordinated by two O atoms from two 4-chlorobenzoate ligands and two N atoms from a chelating 2,2′-bipyridine (bpy) molecule in a distorted N(2)O(2) tetrahedral geometry. The Zn(II) atom is located on a twofold rotation axis, which also passes through the mid-point of the central C—C bond of the bpy ligand. In the crystal, weak C—H⋯O hydrogen bonds and π–π stacking interactions between the pyridine rings of the bpy ligands [centroid–centroid distance = 3.642 (3) Å] link the complex molecules into a two-dimensional supramolecular structure parallel to (100). An intramolecular C—H⋯O hydrogen bond is also observed. International Union of Crystallography 2012-02-24 /pmc/articles/PMC3297269/ /pubmed/22412459 http://dx.doi.org/10.1107/S160053681200699X Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Bi-Song Zhu, Hong-Line Li, Jun Dai, Dong-Dong Peng, Yi-Bao (2,2′-Bipyridine-κ(2) N,N′)bis(4-chlorobenzoato-κO)zinc |
title | (2,2′-Bipyridine-κ(2)
N,N′)bis(4-chlorobenzoato-κO)zinc |
title_full | (2,2′-Bipyridine-κ(2)
N,N′)bis(4-chlorobenzoato-κO)zinc |
title_fullStr | (2,2′-Bipyridine-κ(2)
N,N′)bis(4-chlorobenzoato-κO)zinc |
title_full_unstemmed | (2,2′-Bipyridine-κ(2)
N,N′)bis(4-chlorobenzoato-κO)zinc |
title_short | (2,2′-Bipyridine-κ(2)
N,N′)bis(4-chlorobenzoato-κO)zinc |
title_sort | (2,2′-bipyridine-κ(2)
n,n′)bis(4-chlorobenzoato-κo)zinc |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297269/ https://www.ncbi.nlm.nih.gov/pubmed/22412459 http://dx.doi.org/10.1107/S160053681200699X |
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