Dichloridobis(4-pyridylmethyl 1H-pyrrole-2-carboxyl­ate-κN)zinc

In the title mol­ecule, [ZnCl(2)(C(11)H(10)N(2)O(2))(2)], the Zn(II) ion, situated on a twofold axis, is in a distorted tetra­hedral coordination environment formed by two chloride anions and two pyridine N atoms of the two organic ligands. In the pyrrole-2-carboxyl­ate unit, the pyrrole N—H group a...

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Detalles Bibliográficos
Autores principales: Li, Can, Zhang, Guilong, Yin, Zhenming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297270/
https://www.ncbi.nlm.nih.gov/pubmed/22412460
http://dx.doi.org/10.1107/S1600536812001353
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author Li, Can
Zhang, Guilong
Yin, Zhenming
author_facet Li, Can
Zhang, Guilong
Yin, Zhenming
author_sort Li, Can
collection PubMed
description In the title mol­ecule, [ZnCl(2)(C(11)H(10)N(2)O(2))(2)], the Zn(II) ion, situated on a twofold axis, is in a distorted tetra­hedral coordination environment formed by two chloride anions and two pyridine N atoms of the two organic ligands. In the pyrrole-2-carboxyl­ate unit, the pyrrole N—H group and the carbonyl group point approximately in the same direction. The dihedral angle between the two pyridine rings is 54.8 (3)°. The complex mol­ecules are connected into chains extending along [101] by N—H⋯Cl hydrogen bonds. The chains are further assembled into (-101) layers by C—H⋯O and C—H⋯Cl inter­actions.
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spelling pubmed-32972702012-03-12 Dichloridobis(4-pyridylmethyl 1H-pyrrole-2-carboxyl­ate-κN)zinc Li, Can Zhang, Guilong Yin, Zhenming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mol­ecule, [ZnCl(2)(C(11)H(10)N(2)O(2))(2)], the Zn(II) ion, situated on a twofold axis, is in a distorted tetra­hedral coordination environment formed by two chloride anions and two pyridine N atoms of the two organic ligands. In the pyrrole-2-carboxyl­ate unit, the pyrrole N—H group and the carbonyl group point approximately in the same direction. The dihedral angle between the two pyridine rings is 54.8 (3)°. The complex mol­ecules are connected into chains extending along [101] by N—H⋯Cl hydrogen bonds. The chains are further assembled into (-101) layers by C—H⋯O and C—H⋯Cl inter­actions. International Union of Crystallography 2012-02-24 /pmc/articles/PMC3297270/ /pubmed/22412460 http://dx.doi.org/10.1107/S1600536812001353 Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Can
Zhang, Guilong
Yin, Zhenming
Dichloridobis(4-pyridylmethyl 1H-pyrrole-2-carboxyl­ate-κN)zinc
title Dichloridobis(4-pyridylmethyl 1H-pyrrole-2-carboxyl­ate-κN)zinc
title_full Dichloridobis(4-pyridylmethyl 1H-pyrrole-2-carboxyl­ate-κN)zinc
title_fullStr Dichloridobis(4-pyridylmethyl 1H-pyrrole-2-carboxyl­ate-κN)zinc
title_full_unstemmed Dichloridobis(4-pyridylmethyl 1H-pyrrole-2-carboxyl­ate-κN)zinc
title_short Dichloridobis(4-pyridylmethyl 1H-pyrrole-2-carboxyl­ate-κN)zinc
title_sort dichloridobis(4-pyridylmethyl 1h-pyrrole-2-carboxyl­ate-κn)zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297270/
https://www.ncbi.nlm.nih.gov/pubmed/22412460
http://dx.doi.org/10.1107/S1600536812001353
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