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Bis(1H-benzimidazole-κN (3))bis[2-(naphthalen-1-yl)acetato-κ(2) O,O′]manganese(II) monohydrate
In the title compound, [Mn(C(12)H(9)O(2))(2)(C(7)H(6)N(2))(2)]·H(2)O, the Mn(II) ion is located on a twofold rotation axis and six-coordinated, displaying a distorted MnN(2)O(4) octahedral geometry. The crystal packing is stabilized by N—H⋯O hydrogen bonds, which give rise to a one-dimensional stru...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297273/ https://www.ncbi.nlm.nih.gov/pubmed/22412463 http://dx.doi.org/10.1107/S1600536812007441 |
| _version_ | 1782225854162534400 |
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| author | Zhang, Zhen-Ming Yin, Fu-Jun Li, Shu-An Wang, Li-Ping |
| author_facet | Zhang, Zhen-Ming Yin, Fu-Jun Li, Shu-An Wang, Li-Ping |
| author_sort | Zhang, Zhen-Ming |
| collection | PubMed |
| description | In the title compound, [Mn(C(12)H(9)O(2))(2)(C(7)H(6)N(2))(2)]·H(2)O, the Mn(II) ion is located on a twofold rotation axis and six-coordinated, displaying a distorted MnN(2)O(4) octahedral geometry. The crystal packing is stabilized by N—H⋯O hydrogen bonds, which give rise to a one-dimensional structure along [001], and π–π interactions between the imidazole rings and between the benzene rings of the 2-(naphthalen-1-yl)acetate ligands [centroid–centroid distances = 3.761 (3) and 3.728 (4) Å]. The contribution of the electron density associated with the disordered water molecules was not considerd in the final structure model. |
| format | Online Article Text |
| id | pubmed-3297273 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32972732012-03-12 Bis(1H-benzimidazole-κN (3))bis[2-(naphthalen-1-yl)acetato-κ(2) O,O′]manganese(II) monohydrate Zhang, Zhen-Ming Yin, Fu-Jun Li, Shu-An Wang, Li-Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(12)H(9)O(2))(2)(C(7)H(6)N(2))(2)]·H(2)O, the Mn(II) ion is located on a twofold rotation axis and six-coordinated, displaying a distorted MnN(2)O(4) octahedral geometry. The crystal packing is stabilized by N—H⋯O hydrogen bonds, which give rise to a one-dimensional structure along [001], and π–π interactions between the imidazole rings and between the benzene rings of the 2-(naphthalen-1-yl)acetate ligands [centroid–centroid distances = 3.761 (3) and 3.728 (4) Å]. The contribution of the electron density associated with the disordered water molecules was not considerd in the final structure model. International Union of Crystallography 2012-02-24 /pmc/articles/PMC3297273/ /pubmed/22412463 http://dx.doi.org/10.1107/S1600536812007441 Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhang, Zhen-Ming Yin, Fu-Jun Li, Shu-An Wang, Li-Ping Bis(1H-benzimidazole-κN (3))bis[2-(naphthalen-1-yl)acetato-κ(2) O,O′]manganese(II) monohydrate |
| title | Bis(1H-benzimidazole-κN
(3))bis[2-(naphthalen-1-yl)acetato-κ(2)
O,O′]manganese(II) monohydrate |
| title_full | Bis(1H-benzimidazole-κN
(3))bis[2-(naphthalen-1-yl)acetato-κ(2)
O,O′]manganese(II) monohydrate |
| title_fullStr | Bis(1H-benzimidazole-κN
(3))bis[2-(naphthalen-1-yl)acetato-κ(2)
O,O′]manganese(II) monohydrate |
| title_full_unstemmed | Bis(1H-benzimidazole-κN
(3))bis[2-(naphthalen-1-yl)acetato-κ(2)
O,O′]manganese(II) monohydrate |
| title_short | Bis(1H-benzimidazole-κN
(3))bis[2-(naphthalen-1-yl)acetato-κ(2)
O,O′]manganese(II) monohydrate |
| title_sort | bis(1h-benzimidazole-κn
(3))bis[2-(naphthalen-1-yl)acetato-κ(2)
o,o′]manganese(ii) monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297273/ https://www.ncbi.nlm.nih.gov/pubmed/22412463 http://dx.doi.org/10.1107/S1600536812007441 |
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