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(Acetato-κO)diaqua­[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ(2) N,N′)manganese(II) dihydrate

In the hydrated title complex, [Mn(C(8)H(6)N(3)O(2))(CH(3)CO(2))(C(12)H(8)N(2))(H(2)O)(2)]·2H(2)O, the Mn(II) atom is coordinated by two N atoms from a 1,10-phenanthroline ligand, two water O atoms, a monodentate acetate anion and an O-monodentate 2-(1H-benzotriazol-1-yl)acetate ligand, resulting in...

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Autor principal: Zeng, Ling
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297274/
https://www.ncbi.nlm.nih.gov/pubmed/22412464
http://dx.doi.org/10.1107/S1600536812007404
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author Zeng, Ling
author_facet Zeng, Ling
author_sort Zeng, Ling
collection PubMed
description In the hydrated title complex, [Mn(C(8)H(6)N(3)O(2))(CH(3)CO(2))(C(12)H(8)N(2))(H(2)O)(2)]·2H(2)O, the Mn(II) atom is coordinated by two N atoms from a 1,10-phenanthroline ligand, two water O atoms, a monodentate acetate anion and an O-monodentate 2-(1H-benzotriazol-1-yl)acetate ligand, resulting in a distorted cis-MnN(2)O(4) octa­hedral coordination geometry. The water O atoms are in a trans arrangement and one of them forms an intra­molecular O—H⋯O hydrogen bond to the uncoordinated O atom of the acetate ion. In the crystal, the complex mol­ecules and water mol­ecules are connected by O—H⋯O and O—H⋯N hydrogen bonds to generate a three-dimensional network.
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spelling pubmed-32972742012-03-12 (Acetato-κO)diaqua­[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ(2) N,N′)manganese(II) dihydrate Zeng, Ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the hydrated title complex, [Mn(C(8)H(6)N(3)O(2))(CH(3)CO(2))(C(12)H(8)N(2))(H(2)O)(2)]·2H(2)O, the Mn(II) atom is coordinated by two N atoms from a 1,10-phenanthroline ligand, two water O atoms, a monodentate acetate anion and an O-monodentate 2-(1H-benzotriazol-1-yl)acetate ligand, resulting in a distorted cis-MnN(2)O(4) octa­hedral coordination geometry. The water O atoms are in a trans arrangement and one of them forms an intra­molecular O—H⋯O hydrogen bond to the uncoordinated O atom of the acetate ion. In the crystal, the complex mol­ecules and water mol­ecules are connected by O—H⋯O and O—H⋯N hydrogen bonds to generate a three-dimensional network. International Union of Crystallography 2012-02-24 /pmc/articles/PMC3297274/ /pubmed/22412464 http://dx.doi.org/10.1107/S1600536812007404 Text en © Ling Zeng 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zeng, Ling
(Acetato-κO)diaqua­[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ(2) N,N′)manganese(II) dihydrate
title (Acetato-κO)diaqua­[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ(2) N,N′)manganese(II) dihydrate
title_full (Acetato-κO)diaqua­[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ(2) N,N′)manganese(II) dihydrate
title_fullStr (Acetato-κO)diaqua­[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ(2) N,N′)manganese(II) dihydrate
title_full_unstemmed (Acetato-κO)diaqua­[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ(2) N,N′)manganese(II) dihydrate
title_short (Acetato-κO)diaqua­[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ(2) N,N′)manganese(II) dihydrate
title_sort (acetato-κo)diaqua­[2-(1h-benzotriazol-1-yl)acetato-κo](1,10-phenanthroline-κ(2) n,n′)manganese(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297274/
https://www.ncbi.nlm.nih.gov/pubmed/22412464
http://dx.doi.org/10.1107/S1600536812007404
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