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(Acetato-κO)diaqua[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ(2) N,N′)manganese(II) dihydrate
In the hydrated title complex, [Mn(C(8)H(6)N(3)O(2))(CH(3)CO(2))(C(12)H(8)N(2))(H(2)O)(2)]·2H(2)O, the Mn(II) atom is coordinated by two N atoms from a 1,10-phenanthroline ligand, two water O atoms, a monodentate acetate anion and an O-monodentate 2-(1H-benzotriazol-1-yl)acetate ligand, resulting in...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297274/ https://www.ncbi.nlm.nih.gov/pubmed/22412464 http://dx.doi.org/10.1107/S1600536812007404 |
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author | Zeng, Ling |
author_facet | Zeng, Ling |
author_sort | Zeng, Ling |
collection | PubMed |
description | In the hydrated title complex, [Mn(C(8)H(6)N(3)O(2))(CH(3)CO(2))(C(12)H(8)N(2))(H(2)O)(2)]·2H(2)O, the Mn(II) atom is coordinated by two N atoms from a 1,10-phenanthroline ligand, two water O atoms, a monodentate acetate anion and an O-monodentate 2-(1H-benzotriazol-1-yl)acetate ligand, resulting in a distorted cis-MnN(2)O(4) octahedral coordination geometry. The water O atoms are in a trans arrangement and one of them forms an intramolecular O—H⋯O hydrogen bond to the uncoordinated O atom of the acetate ion. In the crystal, the complex molecules and water molecules are connected by O—H⋯O and O—H⋯N hydrogen bonds to generate a three-dimensional network. |
format | Online Article Text |
id | pubmed-3297274 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32972742012-03-12 (Acetato-κO)diaqua[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ(2) N,N′)manganese(II) dihydrate Zeng, Ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the hydrated title complex, [Mn(C(8)H(6)N(3)O(2))(CH(3)CO(2))(C(12)H(8)N(2))(H(2)O)(2)]·2H(2)O, the Mn(II) atom is coordinated by two N atoms from a 1,10-phenanthroline ligand, two water O atoms, a monodentate acetate anion and an O-monodentate 2-(1H-benzotriazol-1-yl)acetate ligand, resulting in a distorted cis-MnN(2)O(4) octahedral coordination geometry. The water O atoms are in a trans arrangement and one of them forms an intramolecular O—H⋯O hydrogen bond to the uncoordinated O atom of the acetate ion. In the crystal, the complex molecules and water molecules are connected by O—H⋯O and O—H⋯N hydrogen bonds to generate a three-dimensional network. International Union of Crystallography 2012-02-24 /pmc/articles/PMC3297274/ /pubmed/22412464 http://dx.doi.org/10.1107/S1600536812007404 Text en © Ling Zeng 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zeng, Ling (Acetato-κO)diaqua[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ(2) N,N′)manganese(II) dihydrate |
title | (Acetato-κO)diaqua[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ(2)
N,N′)manganese(II) dihydrate |
title_full | (Acetato-κO)diaqua[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ(2)
N,N′)manganese(II) dihydrate |
title_fullStr | (Acetato-κO)diaqua[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ(2)
N,N′)manganese(II) dihydrate |
title_full_unstemmed | (Acetato-κO)diaqua[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ(2)
N,N′)manganese(II) dihydrate |
title_short | (Acetato-κO)diaqua[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ(2)
N,N′)manganese(II) dihydrate |
title_sort | (acetato-κo)diaqua[2-(1h-benzotriazol-1-yl)acetato-κo](1,10-phenanthroline-κ(2)
n,n′)manganese(ii) dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297274/ https://www.ncbi.nlm.nih.gov/pubmed/22412464 http://dx.doi.org/10.1107/S1600536812007404 |
work_keys_str_mv | AT zengling acetatokodiaqua21hbenzotriazol1ylacetatoko110phenanthrolinek2nnmanganeseiidihydrate |