[μ-Bis(diphenyl­phosphan­yl)methane]­tricarbon­yl(μ-p-toluene­sulfonyl­meth­yl isocyanato)(triphenyl­phosphane)ironplatinum(Fe—Pt)

The title compound, [FePt(C(9)H(9)NO(2)S)(C(18)H(15)P)(C(25)H(22)P(2))(CO)(3)], represents a rare example of an isonitrile-bridged heterobimetallic complex (here Pt and Fe) and is an inter­esting precursor for the preparation of heterodinuclear μ-amino­carbyne complexes, since the basic imine-type N...

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Detalles Bibliográficos
Autores principales: Jourdain, Isabelle, Knorr, Michael, Koller, Stephan G., Strohmann, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297276/
https://www.ncbi.nlm.nih.gov/pubmed/22412466
http://dx.doi.org/10.1107/S1600536812004023
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author Jourdain, Isabelle
Knorr, Michael
Koller, Stephan G.
Strohmann, Carsten
author_facet Jourdain, Isabelle
Knorr, Michael
Koller, Stephan G.
Strohmann, Carsten
author_sort Jourdain, Isabelle
collection PubMed
description The title compound, [FePt(C(9)H(9)NO(2)S)(C(18)H(15)P)(C(25)H(22)P(2))(CO)(3)], represents a rare example of an isonitrile-bridged heterobimetallic complex (here Pt and Fe) and is an inter­esting precursor for the preparation of heterodinuclear μ-amino­carbyne complexes, since the basic imine-type N atom of the μ(2)-C=N–R ligand readily undergoes addition with various electrophiles to afford iminium-like salts. In the crystal, the almost symmetrically bridging μ(2)-C=N-R ligand (neglecting the different atomic radii of Fe and Pt) is strongly bent towards the Fe(CO)(3) fragment, with a C=N-R angle of only 121.1 (4)°.
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spelling pubmed-32972762012-03-12 [μ-Bis(diphenyl­phosphan­yl)methane]­tricarbon­yl(μ-p-toluene­sulfonyl­meth­yl isocyanato)(triphenyl­phosphane)ironplatinum(Fe—Pt) Jourdain, Isabelle Knorr, Michael Koller, Stephan G. Strohmann, Carsten Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [FePt(C(9)H(9)NO(2)S)(C(18)H(15)P)(C(25)H(22)P(2))(CO)(3)], represents a rare example of an isonitrile-bridged heterobimetallic complex (here Pt and Fe) and is an inter­esting precursor for the preparation of heterodinuclear μ-amino­carbyne complexes, since the basic imine-type N atom of the μ(2)-C=N–R ligand readily undergoes addition with various electrophiles to afford iminium-like salts. In the crystal, the almost symmetrically bridging μ(2)-C=N-R ligand (neglecting the different atomic radii of Fe and Pt) is strongly bent towards the Fe(CO)(3) fragment, with a C=N-R angle of only 121.1 (4)°. International Union of Crystallography 2012-02-24 /pmc/articles/PMC3297276/ /pubmed/22412466 http://dx.doi.org/10.1107/S1600536812004023 Text en © Jourdain et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jourdain, Isabelle
Knorr, Michael
Koller, Stephan G.
Strohmann, Carsten
[μ-Bis(diphenyl­phosphan­yl)methane]­tricarbon­yl(μ-p-toluene­sulfonyl­meth­yl isocyanato)(triphenyl­phosphane)ironplatinum(Fe—Pt)
title [μ-Bis(diphenyl­phosphan­yl)methane]­tricarbon­yl(μ-p-toluene­sulfonyl­meth­yl isocyanato)(triphenyl­phosphane)ironplatinum(Fe—Pt)
title_full [μ-Bis(diphenyl­phosphan­yl)methane]­tricarbon­yl(μ-p-toluene­sulfonyl­meth­yl isocyanato)(triphenyl­phosphane)ironplatinum(Fe—Pt)
title_fullStr [μ-Bis(diphenyl­phosphan­yl)methane]­tricarbon­yl(μ-p-toluene­sulfonyl­meth­yl isocyanato)(triphenyl­phosphane)ironplatinum(Fe—Pt)
title_full_unstemmed [μ-Bis(diphenyl­phosphan­yl)methane]­tricarbon­yl(μ-p-toluene­sulfonyl­meth­yl isocyanato)(triphenyl­phosphane)ironplatinum(Fe—Pt)
title_short [μ-Bis(diphenyl­phosphan­yl)methane]­tricarbon­yl(μ-p-toluene­sulfonyl­meth­yl isocyanato)(triphenyl­phosphane)ironplatinum(Fe—Pt)
title_sort [μ-bis(diphenyl­phosphan­yl)methane]­tricarbon­yl(μ-p-toluene­sulfonyl­meth­yl isocyanato)(triphenyl­phosphane)ironplatinum(fe—pt)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297276/
https://www.ncbi.nlm.nih.gov/pubmed/22412466
http://dx.doi.org/10.1107/S1600536812004023
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