catena-Poly[ammonium (cadmium-tri-μ-thio­cyanato-κ(4) S:N;κ(2) N:S)–1,4,10,13,16-hexa­oxa­cyclo­octa­decane (1/1)]

In the title compound, {(NH(4))[Cd(NCS)(3)]·C(12)H(24)O(6)}(n), the Cd(2+) ion, the ammonium cation, one of the SCN(−) ligands and the macrocycle are located on mirror planes. The thiocyanate anions act as bridging ligands between the Cd(II) ions, leading to a polymeric chain arrangement extending a...

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Detalles Bibliográficos
Autores principales: Ramesh, V., Rajarajan, K., Kumar, K. Sendil, Subashini, A., NizamMohideen, M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297278/
https://www.ncbi.nlm.nih.gov/pubmed/22412468
http://dx.doi.org/10.1107/S1600536812004898
Descripción
Sumario:In the title compound, {(NH(4))[Cd(NCS)(3)]·C(12)H(24)O(6)}(n), the Cd(2+) ion, the ammonium cation, one of the SCN(−) ligands and the macrocycle are located on mirror planes. The thiocyanate anions act as bridging ligands between the Cd(II) ions, leading to a polymeric chain arrangement extending along [001] around a twofold screw axis. The ammonium ions are contained within the bowl of the macrocycle via extensive N—H⋯O hydrogen bonding.

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