Bis(μ-propan-2-olato-κ(2) O:O)bis­[chlor­ido(propan-2-ol-κO)bis­(pro­pan-1-ol­ato-κO)tin(IV)]

The binuclear centrosymmetric title compound, [Sn(2)(C(3)H(7)O)(6)Cl(2)(C(3)H(8)O)(2)], exhibits an edge-shared double octahedral exhibits an edge-shared octa­hedral structure, which is distorted owing to the presence of asymmetric intra­molecular hydrogen bonds between the axially coordinated isopr...

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Detalles Bibliográficos
Autores principales: Klishin, Nikolai, Brusylovets, Oleksii, Brusilovets, Anatoliy, Rusanov, Eduard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297279/
https://www.ncbi.nlm.nih.gov/pubmed/22412469
http://dx.doi.org/10.1107/S1600536812007799
Descripción
Sumario:The binuclear centrosymmetric title compound, [Sn(2)(C(3)H(7)O)(6)Cl(2)(C(3)H(8)O)(2)], exhibits an edge-shared double octahedral exhibits an edge-shared octa­hedral structure, which is distorted owing to the presence of asymmetric intra­molecular hydrogen bonds between the axially coordinated isopropanol and isopropoxide ligands. The H atom of the hy­droxy group is located nearer to an isoprop­oxy group with the longest Sn—O bond [2.1789 (17) Å].

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