Bis(μ-propan-2-olato-κ(2) O:O)bis­[chlor­ido(propan-2-ol-κO)bis­(pro­pan-1-ol­ato-κO)tin(IV)]

The binuclear centrosymmetric title compound, [Sn(2)(C(3)H(7)O)(6)Cl(2)(C(3)H(8)O)(2)], exhibits an edge-shared double octahedral exhibits an edge-shared octa­hedral structure, which is distorted owing to the presence of asymmetric intra­molecular hydrogen bonds between the axially coordinated isopr...

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Autores principales: Klishin, Nikolai, Brusylovets, Oleksii, Brusilovets, Anatoliy, Rusanov, Eduard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297279/
https://www.ncbi.nlm.nih.gov/pubmed/22412469
http://dx.doi.org/10.1107/S1600536812007799
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author Klishin, Nikolai
Brusylovets, Oleksii
Brusilovets, Anatoliy
Rusanov, Eduard
author_facet Klishin, Nikolai
Brusylovets, Oleksii
Brusilovets, Anatoliy
Rusanov, Eduard
author_sort Klishin, Nikolai
collection PubMed
description The binuclear centrosymmetric title compound, [Sn(2)(C(3)H(7)O)(6)Cl(2)(C(3)H(8)O)(2)], exhibits an edge-shared double octahedral exhibits an edge-shared octa­hedral structure, which is distorted owing to the presence of asymmetric intra­molecular hydrogen bonds between the axially coordinated isopropanol and isopropoxide ligands. The H atom of the hy­droxy group is located nearer to an isoprop­oxy group with the longest Sn—O bond [2.1789 (17) Å].
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spelling pubmed-32972792012-03-12 Bis(μ-propan-2-olato-κ(2) O:O)bis­[chlor­ido(propan-2-ol-κO)bis­(pro­pan-1-ol­ato-κO)tin(IV)] Klishin, Nikolai Brusylovets, Oleksii Brusilovets, Anatoliy Rusanov, Eduard Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The binuclear centrosymmetric title compound, [Sn(2)(C(3)H(7)O)(6)Cl(2)(C(3)H(8)O)(2)], exhibits an edge-shared double octahedral exhibits an edge-shared octa­hedral structure, which is distorted owing to the presence of asymmetric intra­molecular hydrogen bonds between the axially coordinated isopropanol and isopropoxide ligands. The H atom of the hy­droxy group is located nearer to an isoprop­oxy group with the longest Sn—O bond [2.1789 (17) Å]. International Union of Crystallography 2012-02-24 /pmc/articles/PMC3297279/ /pubmed/22412469 http://dx.doi.org/10.1107/S1600536812007799 Text en © Klishin et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Klishin, Nikolai
Brusylovets, Oleksii
Brusilovets, Anatoliy
Rusanov, Eduard
Bis(μ-propan-2-olato-κ(2) O:O)bis­[chlor­ido(propan-2-ol-κO)bis­(pro­pan-1-ol­ato-κO)tin(IV)]
title Bis(μ-propan-2-olato-κ(2) O:O)bis­[chlor­ido(propan-2-ol-κO)bis­(pro­pan-1-ol­ato-κO)tin(IV)]
title_full Bis(μ-propan-2-olato-κ(2) O:O)bis­[chlor­ido(propan-2-ol-κO)bis­(pro­pan-1-ol­ato-κO)tin(IV)]
title_fullStr Bis(μ-propan-2-olato-κ(2) O:O)bis­[chlor­ido(propan-2-ol-κO)bis­(pro­pan-1-ol­ato-κO)tin(IV)]
title_full_unstemmed Bis(μ-propan-2-olato-κ(2) O:O)bis­[chlor­ido(propan-2-ol-κO)bis­(pro­pan-1-ol­ato-κO)tin(IV)]
title_short Bis(μ-propan-2-olato-κ(2) O:O)bis­[chlor­ido(propan-2-ol-κO)bis­(pro­pan-1-ol­ato-κO)tin(IV)]
title_sort bis(μ-propan-2-olato-κ(2) o:o)bis­[chlor­ido(propan-2-ol-κo)bis­(pro­pan-1-ol­ato-κo)tin(iv)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297279/
https://www.ncbi.nlm.nih.gov/pubmed/22412469
http://dx.doi.org/10.1107/S1600536812007799
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