Cargando…
Chlorido[2-({[2-(diphenylphosphanyl)benzylidene]amino}methyl)thiophene-κ(2) N,P]methylpalladium(II)
In the title compound, [Pd(CH(3))Cl(C(24)H(20)NPS)], the Pd(II) ion is coordinated in a distorted square-planar environment which includes the P and N atoms of the bis-chelating ligand. The thiophene ring is rotationally ordered, unlike in the majority of crystal structures containing this group.
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297280/ https://www.ncbi.nlm.nih.gov/pubmed/22412470 http://dx.doi.org/10.1107/S1600536812007295 |
| _version_ | 1782225855790972928 |
|---|---|
| author | Motswainyana, William M. Onani, Martin O. Lalancette, Roger A. |
| author_facet | Motswainyana, William M. Onani, Martin O. Lalancette, Roger A. |
| author_sort | Motswainyana, William M. |
| collection | PubMed |
| description | In the title compound, [Pd(CH(3))Cl(C(24)H(20)NPS)], the Pd(II) ion is coordinated in a distorted square-planar environment which includes the P and N atoms of the bis-chelating ligand. The thiophene ring is rotationally ordered, unlike in the majority of crystal structures containing this group. |
| format | Online Article Text |
| id | pubmed-3297280 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32972802012-03-12 Chlorido[2-({[2-(diphenylphosphanyl)benzylidene]amino}methyl)thiophene-κ(2) N,P]methylpalladium(II) Motswainyana, William M. Onani, Martin O. Lalancette, Roger A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pd(CH(3))Cl(C(24)H(20)NPS)], the Pd(II) ion is coordinated in a distorted square-planar environment which includes the P and N atoms of the bis-chelating ligand. The thiophene ring is rotationally ordered, unlike in the majority of crystal structures containing this group. International Union of Crystallography 2012-02-29 /pmc/articles/PMC3297280/ /pubmed/22412470 http://dx.doi.org/10.1107/S1600536812007295 Text en © Motswainyana et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Motswainyana, William M. Onani, Martin O. Lalancette, Roger A. Chlorido[2-({[2-(diphenylphosphanyl)benzylidene]amino}methyl)thiophene-κ(2) N,P]methylpalladium(II) |
| title | Chlorido[2-({[2-(diphenylphosphanyl)benzylidene]amino}methyl)thiophene-κ(2)
N,P]methylpalladium(II) |
| title_full | Chlorido[2-({[2-(diphenylphosphanyl)benzylidene]amino}methyl)thiophene-κ(2)
N,P]methylpalladium(II) |
| title_fullStr | Chlorido[2-({[2-(diphenylphosphanyl)benzylidene]amino}methyl)thiophene-κ(2)
N,P]methylpalladium(II) |
| title_full_unstemmed | Chlorido[2-({[2-(diphenylphosphanyl)benzylidene]amino}methyl)thiophene-κ(2)
N,P]methylpalladium(II) |
| title_short | Chlorido[2-({[2-(diphenylphosphanyl)benzylidene]amino}methyl)thiophene-κ(2)
N,P]methylpalladium(II) |
| title_sort | chlorido[2-({[2-(diphenylphosphanyl)benzylidene]amino}methyl)thiophene-κ(2)
n,p]methylpalladium(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297280/ https://www.ncbi.nlm.nih.gov/pubmed/22412470 http://dx.doi.org/10.1107/S1600536812007295 |
| work_keys_str_mv | AT motswainyanawilliamm chlorido22diphenylphosphanylbenzylideneaminomethylthiophenek2npmethylpalladiumii AT onanimartino chlorido22diphenylphosphanylbenzylideneaminomethylthiophenek2npmethylpalladiumii AT lalancetterogera chlorido22diphenylphosphanylbenzylideneaminomethylthiophenek2npmethylpalladiumii |