Trichloridotris{N-[phen­yl(pyridin-2-yl)­methyl­idene]hydroxyl­amine-κ(2) N,N′}samarium(III)

The Sm(III) ion in the title compound, [SmCl(3)(C(12)H(10)N(2)O)(3)], shows a coordination number of nine with a slightly distorted tricapped trigonal prismatic geometry based on a Cl(3)N(6) donor set. The mol­ecular structure is stabilized by three intra­molecular O—H⋯Cl hydrogen bonds.

Detalles Bibliográficos
Autores principales: Lei, Tao, Chen, Wenqian, Chen, Yanmei, Hu, Bin, Li, Yahong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297284/
https://www.ncbi.nlm.nih.gov/pubmed/22412474
http://dx.doi.org/10.1107/S1600536812008100
Descripción
Sumario:The Sm(III) ion in the title compound, [SmCl(3)(C(12)H(10)N(2)O)(3)], shows a coordination number of nine with a slightly distorted tricapped trigonal prismatic geometry based on a Cl(3)N(6) donor set. The mol­ecular structure is stabilized by three intra­molecular O—H⋯Cl hydrogen bonds.

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