Trichloridotris{N-[phen­yl(pyridin-2-yl)­methyl­idene]hydroxyl­amine-κ(2) N,N′}samarium(III)

The Sm(III) ion in the title compound, [SmCl(3)(C(12)H(10)N(2)O)(3)], shows a coordination number of nine with a slightly distorted tricapped trigonal prismatic geometry based on a Cl(3)N(6) donor set. The mol­ecular structure is stabilized by three intra­molecular O—H⋯Cl hydrogen bonds.

Detalles Bibliográficos
Autores principales: Lei, Tao, Chen, Wenqian, Chen, Yanmei, Hu, Bin, Li, Yahong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297284/
https://www.ncbi.nlm.nih.gov/pubmed/22412474
http://dx.doi.org/10.1107/S1600536812008100
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author Lei, Tao
Chen, Wenqian
Chen, Yanmei
Hu, Bin
Li, Yahong
author_facet Lei, Tao
Chen, Wenqian
Chen, Yanmei
Hu, Bin
Li, Yahong
author_sort Lei, Tao
collection PubMed
description The Sm(III) ion in the title compound, [SmCl(3)(C(12)H(10)N(2)O)(3)], shows a coordination number of nine with a slightly distorted tricapped trigonal prismatic geometry based on a Cl(3)N(6) donor set. The mol­ecular structure is stabilized by three intra­molecular O—H⋯Cl hydrogen bonds.
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spelling pubmed-32972842012-03-12 Trichloridotris{N-[phen­yl(pyridin-2-yl)­methyl­idene]hydroxyl­amine-κ(2) N,N′}samarium(III) Lei, Tao Chen, Wenqian Chen, Yanmei Hu, Bin Li, Yahong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sm(III) ion in the title compound, [SmCl(3)(C(12)H(10)N(2)O)(3)], shows a coordination number of nine with a slightly distorted tricapped trigonal prismatic geometry based on a Cl(3)N(6) donor set. The mol­ecular structure is stabilized by three intra­molecular O—H⋯Cl hydrogen bonds. International Union of Crystallography 2012-02-29 /pmc/articles/PMC3297284/ /pubmed/22412474 http://dx.doi.org/10.1107/S1600536812008100 Text en © Lei et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lei, Tao
Chen, Wenqian
Chen, Yanmei
Hu, Bin
Li, Yahong
Trichloridotris{N-[phen­yl(pyridin-2-yl)­methyl­idene]hydroxyl­amine-κ(2) N,N′}samarium(III)
title Trichloridotris{N-[phen­yl(pyridin-2-yl)­methyl­idene]hydroxyl­amine-κ(2) N,N′}samarium(III)
title_full Trichloridotris{N-[phen­yl(pyridin-2-yl)­methyl­idene]hydroxyl­amine-κ(2) N,N′}samarium(III)
title_fullStr Trichloridotris{N-[phen­yl(pyridin-2-yl)­methyl­idene]hydroxyl­amine-κ(2) N,N′}samarium(III)
title_full_unstemmed Trichloridotris{N-[phen­yl(pyridin-2-yl)­methyl­idene]hydroxyl­amine-κ(2) N,N′}samarium(III)
title_short Trichloridotris{N-[phen­yl(pyridin-2-yl)­methyl­idene]hydroxyl­amine-κ(2) N,N′}samarium(III)
title_sort trichloridotris{n-[phen­yl(pyridin-2-yl)­methyl­idene]hydroxyl­amine-κ(2) n,n′}samarium(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297284/
https://www.ncbi.nlm.nih.gov/pubmed/22412474
http://dx.doi.org/10.1107/S1600536812008100
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