2-Hy­droxy-N′-(5-hy­droxy-2-nitro­benzyl­idene)-3-methyl­benzohydrazide

The title compound, C(15)H(13)N(3)O(5), was prepared by condensing 5-hy­droxy-2-nitro­benzaldehyde and 2-hy­droxy-3-methyl­benzohydrazide in methanol. The two benzene rings make a dihedral angle of 3.9 (3)°. An intra­molecular O—H⋯O hydrogen bond is observed. The crystal structure is stabilized by i...

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Detalles Bibliográficos
Autores principales: Zhu, Zhao-Fu, Shao, Li-Juen, Shen, Xi-Hai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297290/
https://www.ncbi.nlm.nih.gov/pubmed/22412480
http://dx.doi.org/10.1107/S1600536812002437
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author Zhu, Zhao-Fu
Shao, Li-Juen
Shen, Xi-Hai
author_facet Zhu, Zhao-Fu
Shao, Li-Juen
Shen, Xi-Hai
author_sort Zhu, Zhao-Fu
collection PubMed
description The title compound, C(15)H(13)N(3)O(5), was prepared by condensing 5-hy­droxy-2-nitro­benzaldehyde and 2-hy­droxy-3-methyl­benzohydrazide in methanol. The two benzene rings make a dihedral angle of 3.9 (3)°. An intra­molecular O—H⋯O hydrogen bond is observed. The crystal structure is stabilized by inter­molecular O—H⋯O and N—H⋯O hydrogen bonds, and C—H⋯O and π–π inter­actions [centroid–centroid distances = 3.5658 (17)–3.9287 (19) Å].
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spelling pubmed-32972902012-03-12 2-Hy­droxy-N′-(5-hy­droxy-2-nitro­benzyl­idene)-3-methyl­benzohydrazide Zhu, Zhao-Fu Shao, Li-Juen Shen, Xi-Hai Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(13)N(3)O(5), was prepared by condensing 5-hy­droxy-2-nitro­benzaldehyde and 2-hy­droxy-3-methyl­benzohydrazide in methanol. The two benzene rings make a dihedral angle of 3.9 (3)°. An intra­molecular O—H⋯O hydrogen bond is observed. The crystal structure is stabilized by inter­molecular O—H⋯O and N—H⋯O hydrogen bonds, and C—H⋯O and π–π inter­actions [centroid–centroid distances = 3.5658 (17)–3.9287 (19) Å]. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297290/ /pubmed/22412480 http://dx.doi.org/10.1107/S1600536812002437 Text en © Zhu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhu, Zhao-Fu
Shao, Li-Juen
Shen, Xi-Hai
2-Hy­droxy-N′-(5-hy­droxy-2-nitro­benzyl­idene)-3-methyl­benzohydrazide
title 2-Hy­droxy-N′-(5-hy­droxy-2-nitro­benzyl­idene)-3-methyl­benzohydrazide
title_full 2-Hy­droxy-N′-(5-hy­droxy-2-nitro­benzyl­idene)-3-methyl­benzohydrazide
title_fullStr 2-Hy­droxy-N′-(5-hy­droxy-2-nitro­benzyl­idene)-3-methyl­benzohydrazide
title_full_unstemmed 2-Hy­droxy-N′-(5-hy­droxy-2-nitro­benzyl­idene)-3-methyl­benzohydrazide
title_short 2-Hy­droxy-N′-(5-hy­droxy-2-nitro­benzyl­idene)-3-methyl­benzohydrazide
title_sort 2-hy­droxy-n′-(5-hy­droxy-2-nitro­benzyl­idene)-3-methyl­benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297290/
https://www.ncbi.nlm.nih.gov/pubmed/22412480
http://dx.doi.org/10.1107/S1600536812002437
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AT shaolijuen 2hydroxyn5hydroxy2nitrobenzylidene3methylbenzohydrazide
AT shenxihai 2hydroxyn5hydroxy2nitrobenzylidene3methylbenzohydrazide

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