7′-(2,5-Dimeth­oxy­phen­yl)-1′,3′,5′,6′,7′,7a’-hexa­hydro­dispiro­[indan-2,5′-pyrrolo­[1,2-c][1,3]thia­zole-6′,2′′-indan]-1,3,1′′-trione

In the title compound, C(30)H(25)NO(5)S, all the five-membered rings are in envelope conformations with the spiro and methylene C atoms as the flap atoms. Intra­molecular C—H⋯O inter­actions stabilize the mol­ecular structure and form S(6) and S(7) ring motifs. The mean plane through the hexa­hydro­...

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Autores principales: Wei, Ang Chee, Ali, Mohamed Ashraf, Choon, Tan Soo, Razak, Ibrahim Abdul, Arshad, Suhana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297291/
https://www.ncbi.nlm.nih.gov/pubmed/22412481
http://dx.doi.org/10.1107/S1600536812003169
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author Wei, Ang Chee
Ali, Mohamed Ashraf
Choon, Tan Soo
Razak, Ibrahim Abdul
Arshad, Suhana
author_facet Wei, Ang Chee
Ali, Mohamed Ashraf
Choon, Tan Soo
Razak, Ibrahim Abdul
Arshad, Suhana
author_sort Wei, Ang Chee
collection PubMed
description In the title compound, C(30)H(25)NO(5)S, all the five-membered rings are in envelope conformations with the spiro and methylene C atoms as the flap atoms. Intra­molecular C—H⋯O inter­actions stabilize the mol­ecular structure and form S(6) and S(7) ring motifs. The mean plane through the hexa­hydro­pyrrolo­[1,2-c]thia­zole ring [r.m.s deviation of 0.0393 (1) Å] makes dihedral angles of 60.92 (5), 88.33 (4) and 84.12 (4)° with the terminal benzene ring and the mean planes of the mono and di-oxo substituted indan rings, respectively. Mol­ecules are linked by inter­molecular C—H⋯O inter­actions into a three-dimensional network. In addition, C—H⋯π and π–π inter­actions [centroid-to-centroid distance = 3.4084 (8) Å] further stabilize the crystal structure.
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spelling pubmed-32972912012-03-12 7′-(2,5-Dimeth­oxy­phen­yl)-1′,3′,5′,6′,7′,7a’-hexa­hydro­dispiro­[indan-2,5′-pyrrolo­[1,2-c][1,3]thia­zole-6′,2′′-indan]-1,3,1′′-trione Wei, Ang Chee Ali, Mohamed Ashraf Choon, Tan Soo Razak, Ibrahim Abdul Arshad, Suhana Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(30)H(25)NO(5)S, all the five-membered rings are in envelope conformations with the spiro and methylene C atoms as the flap atoms. Intra­molecular C—H⋯O inter­actions stabilize the mol­ecular structure and form S(6) and S(7) ring motifs. The mean plane through the hexa­hydro­pyrrolo­[1,2-c]thia­zole ring [r.m.s deviation of 0.0393 (1) Å] makes dihedral angles of 60.92 (5), 88.33 (4) and 84.12 (4)° with the terminal benzene ring and the mean planes of the mono and di-oxo substituted indan rings, respectively. Mol­ecules are linked by inter­molecular C—H⋯O inter­actions into a three-dimensional network. In addition, C—H⋯π and π–π inter­actions [centroid-to-centroid distance = 3.4084 (8) Å] further stabilize the crystal structure. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297291/ /pubmed/22412481 http://dx.doi.org/10.1107/S1600536812003169 Text en © Wei et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wei, Ang Chee
Ali, Mohamed Ashraf
Choon, Tan Soo
Razak, Ibrahim Abdul
Arshad, Suhana
7′-(2,5-Dimeth­oxy­phen­yl)-1′,3′,5′,6′,7′,7a’-hexa­hydro­dispiro­[indan-2,5′-pyrrolo­[1,2-c][1,3]thia­zole-6′,2′′-indan]-1,3,1′′-trione
title 7′-(2,5-Dimeth­oxy­phen­yl)-1′,3′,5′,6′,7′,7a’-hexa­hydro­dispiro­[indan-2,5′-pyrrolo­[1,2-c][1,3]thia­zole-6′,2′′-indan]-1,3,1′′-trione
title_full 7′-(2,5-Dimeth­oxy­phen­yl)-1′,3′,5′,6′,7′,7a’-hexa­hydro­dispiro­[indan-2,5′-pyrrolo­[1,2-c][1,3]thia­zole-6′,2′′-indan]-1,3,1′′-trione
title_fullStr 7′-(2,5-Dimeth­oxy­phen­yl)-1′,3′,5′,6′,7′,7a’-hexa­hydro­dispiro­[indan-2,5′-pyrrolo­[1,2-c][1,3]thia­zole-6′,2′′-indan]-1,3,1′′-trione
title_full_unstemmed 7′-(2,5-Dimeth­oxy­phen­yl)-1′,3′,5′,6′,7′,7a’-hexa­hydro­dispiro­[indan-2,5′-pyrrolo­[1,2-c][1,3]thia­zole-6′,2′′-indan]-1,3,1′′-trione
title_short 7′-(2,5-Dimeth­oxy­phen­yl)-1′,3′,5′,6′,7′,7a’-hexa­hydro­dispiro­[indan-2,5′-pyrrolo­[1,2-c][1,3]thia­zole-6′,2′′-indan]-1,3,1′′-trione
title_sort 7′-(2,5-dimeth­oxy­phen­yl)-1′,3′,5′,6′,7′,7a’-hexa­hydro­dispiro­[indan-2,5′-pyrrolo­[1,2-c][1,3]thia­zole-6′,2′′-indan]-1,3,1′′-trione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297291/
https://www.ncbi.nlm.nih.gov/pubmed/22412481
http://dx.doi.org/10.1107/S1600536812003169
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