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(E)-4-Meth­oxy-N′-(3,4,5-trimeth­oxy­benzyl­idene)benzohydrazide

In the asymmetric unit of the title compound, C(18)H(20)N(2)O(5), there are two crystallographic independent mol­ecules. Both mol­ecules are twisted; the dihedral angle between the two benzene rings is 7.2 (5)° in one mol­ecule, whereas it is 85.9 (4)° in the other. Of the three meth­oxy groups in t...

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Autores principales: Fun, Hoong-Kun, Promdet, Premrudee, Horkaew, Jirapa, Chantrapromma, Suchada
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297292/
https://www.ncbi.nlm.nih.gov/pubmed/22412482
http://dx.doi.org/10.1107/S1600536812003534
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author Fun, Hoong-Kun
Promdet, Premrudee
Horkaew, Jirapa
Chantrapromma, Suchada
author_facet Fun, Hoong-Kun
Promdet, Premrudee
Horkaew, Jirapa
Chantrapromma, Suchada
author_sort Fun, Hoong-Kun
collection PubMed
description In the asymmetric unit of the title compound, C(18)H(20)N(2)O(5), there are two crystallographic independent mol­ecules. Both mol­ecules are twisted; the dihedral angle between the two benzene rings is 7.2 (5)° in one mol­ecule, whereas it is 85.9 (4)° in the other. Of the three meth­oxy groups in the 3,4,5-trimeth­oxy­phenyl unit, two meth­oxy groups at meta positions are approximately coplanar with the benzene plane [C—O—C—C torsion angles of −2.3 (13)–4.8 (11)°], but the other meth­oxy, at the para position, is out of the plane [C—O—C—C of 72.8 (9)° in one mol­ecule and −77.5 (9)° in the other]. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds and weak C—H⋯O inter­actions into tapes along the b axis. C—H⋯π inter­actions are also present.
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spelling pubmed-32972922012-03-12 (E)-4-Meth­oxy-N′-(3,4,5-trimeth­oxy­benzyl­idene)benzohydrazide Fun, Hoong-Kun Promdet, Premrudee Horkaew, Jirapa Chantrapromma, Suchada Acta Crystallogr Sect E Struct Rep Online Organic Papers In the asymmetric unit of the title compound, C(18)H(20)N(2)O(5), there are two crystallographic independent mol­ecules. Both mol­ecules are twisted; the dihedral angle between the two benzene rings is 7.2 (5)° in one mol­ecule, whereas it is 85.9 (4)° in the other. Of the three meth­oxy groups in the 3,4,5-trimeth­oxy­phenyl unit, two meth­oxy groups at meta positions are approximately coplanar with the benzene plane [C—O—C—C torsion angles of −2.3 (13)–4.8 (11)°], but the other meth­oxy, at the para position, is out of the plane [C—O—C—C of 72.8 (9)° in one mol­ecule and −77.5 (9)° in the other]. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds and weak C—H⋯O inter­actions into tapes along the b axis. C—H⋯π inter­actions are also present. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297292/ /pubmed/22412482 http://dx.doi.org/10.1107/S1600536812003534 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Promdet, Premrudee
Horkaew, Jirapa
Chantrapromma, Suchada
(E)-4-Meth­oxy-N′-(3,4,5-trimeth­oxy­benzyl­idene)benzohydrazide
title (E)-4-Meth­oxy-N′-(3,4,5-trimeth­oxy­benzyl­idene)benzohydrazide
title_full (E)-4-Meth­oxy-N′-(3,4,5-trimeth­oxy­benzyl­idene)benzohydrazide
title_fullStr (E)-4-Meth­oxy-N′-(3,4,5-trimeth­oxy­benzyl­idene)benzohydrazide
title_full_unstemmed (E)-4-Meth­oxy-N′-(3,4,5-trimeth­oxy­benzyl­idene)benzohydrazide
title_short (E)-4-Meth­oxy-N′-(3,4,5-trimeth­oxy­benzyl­idene)benzohydrazide
title_sort (e)-4-meth­oxy-n′-(3,4,5-trimeth­oxy­benzyl­idene)benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297292/
https://www.ncbi.nlm.nih.gov/pubmed/22412482
http://dx.doi.org/10.1107/S1600536812003534
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