Cargando…
(E)-4-Methoxy-N′-(3,4,5-trimethoxybenzylidene)benzohydrazide
In the asymmetric unit of the title compound, C(18)H(20)N(2)O(5), there are two crystallographic independent molecules. Both molecules are twisted; the dihedral angle between the two benzene rings is 7.2 (5)° in one molecule, whereas it is 85.9 (4)° in the other. Of the three methoxy groups in t...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297292/ https://www.ncbi.nlm.nih.gov/pubmed/22412482 http://dx.doi.org/10.1107/S1600536812003534 |
_version_ | 1782225858575990784 |
---|---|
author | Fun, Hoong-Kun Promdet, Premrudee Horkaew, Jirapa Chantrapromma, Suchada |
author_facet | Fun, Hoong-Kun Promdet, Premrudee Horkaew, Jirapa Chantrapromma, Suchada |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | In the asymmetric unit of the title compound, C(18)H(20)N(2)O(5), there are two crystallographic independent molecules. Both molecules are twisted; the dihedral angle between the two benzene rings is 7.2 (5)° in one molecule, whereas it is 85.9 (4)° in the other. Of the three methoxy groups in the 3,4,5-trimethoxyphenyl unit, two methoxy groups at meta positions are approximately coplanar with the benzene plane [C—O—C—C torsion angles of −2.3 (13)–4.8 (11)°], but the other methoxy, at the para position, is out of the plane [C—O—C—C of 72.8 (9)° in one molecule and −77.5 (9)° in the other]. In the crystal, molecules are linked by N—H⋯O hydrogen bonds and weak C—H⋯O interactions into tapes along the b axis. C—H⋯π interactions are also present. |
format | Online Article Text |
id | pubmed-3297292 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32972922012-03-12 (E)-4-Methoxy-N′-(3,4,5-trimethoxybenzylidene)benzohydrazide Fun, Hoong-Kun Promdet, Premrudee Horkaew, Jirapa Chantrapromma, Suchada Acta Crystallogr Sect E Struct Rep Online Organic Papers In the asymmetric unit of the title compound, C(18)H(20)N(2)O(5), there are two crystallographic independent molecules. Both molecules are twisted; the dihedral angle between the two benzene rings is 7.2 (5)° in one molecule, whereas it is 85.9 (4)° in the other. Of the three methoxy groups in the 3,4,5-trimethoxyphenyl unit, two methoxy groups at meta positions are approximately coplanar with the benzene plane [C—O—C—C torsion angles of −2.3 (13)–4.8 (11)°], but the other methoxy, at the para position, is out of the plane [C—O—C—C of 72.8 (9)° in one molecule and −77.5 (9)° in the other]. In the crystal, molecules are linked by N—H⋯O hydrogen bonds and weak C—H⋯O interactions into tapes along the b axis. C—H⋯π interactions are also present. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297292/ /pubmed/22412482 http://dx.doi.org/10.1107/S1600536812003534 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Promdet, Premrudee Horkaew, Jirapa Chantrapromma, Suchada (E)-4-Methoxy-N′-(3,4,5-trimethoxybenzylidene)benzohydrazide |
title | (E)-4-Methoxy-N′-(3,4,5-trimethoxybenzylidene)benzohydrazide |
title_full | (E)-4-Methoxy-N′-(3,4,5-trimethoxybenzylidene)benzohydrazide |
title_fullStr | (E)-4-Methoxy-N′-(3,4,5-trimethoxybenzylidene)benzohydrazide |
title_full_unstemmed | (E)-4-Methoxy-N′-(3,4,5-trimethoxybenzylidene)benzohydrazide |
title_short | (E)-4-Methoxy-N′-(3,4,5-trimethoxybenzylidene)benzohydrazide |
title_sort | (e)-4-methoxy-n′-(3,4,5-trimethoxybenzylidene)benzohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297292/ https://www.ncbi.nlm.nih.gov/pubmed/22412482 http://dx.doi.org/10.1107/S1600536812003534 |
work_keys_str_mv | AT funhoongkun e4methoxyn345trimethoxybenzylidenebenzohydrazide AT promdetpremrudee e4methoxyn345trimethoxybenzylidenebenzohydrazide AT horkaewjirapa e4methoxyn345trimethoxybenzylidenebenzohydrazide AT chantraprommasuchada e4methoxyn345trimethoxybenzylidenebenzohydrazide |