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2-((E)-{3-[(E)-2-Hydroxy-3,5-diiodobenzylideneamino]-2,2-dimethylpropyl}iminomethyl)-4,6-diiodophenol
The asymmetric unit of the title compound, C(19)H(18)I(4)N(2)O(2), comprises a potentially tetradentate Schiff base ligand. The disordered H atoms on the N and O atoms were refined with site occupancies of 0.54 (8)/0.46 (8) and 0.59 (7)/0.41 (7), respectively. The dihedral angle between the benzene...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297293/ https://www.ncbi.nlm.nih.gov/pubmed/22412483 http://dx.doi.org/10.1107/S1600536812003704 |
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author | Kargar, Hadi Kia, Reza Shakarami, Tayebeh Tahir, Muhammad Nawaz |
author_facet | Kargar, Hadi Kia, Reza Shakarami, Tayebeh Tahir, Muhammad Nawaz |
author_sort | Kargar, Hadi |
collection | PubMed |
description | The asymmetric unit of the title compound, C(19)H(18)I(4)N(2)O(2), comprises a potentially tetradentate Schiff base ligand. The disordered H atoms on the N and O atoms were refined with site occupancies of 0.54 (8)/0.46 (8) and 0.59 (7)/0.41 (7), respectively. The dihedral angle between the benzene rings is 73.3 (3)°. Intramolecular O—H⋯N and N—H⋯O hydrogen bonds make S(6) ring motifs. Short I⋯I [3.8919 (7) Å] and I⋯Cg [Cg is a ring centroid; 3.911 (2) Å] contacts are present in the crystal structure. The crystal structure is further stabilized by intermolecular π–π interactions [centroid-to-centroid distance = 3.827 (3) Å]. |
format | Online Article Text |
id | pubmed-3297293 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32972932012-03-12 2-((E)-{3-[(E)-2-Hydroxy-3,5-diiodobenzylideneamino]-2,2-dimethylpropyl}iminomethyl)-4,6-diiodophenol Kargar, Hadi Kia, Reza Shakarami, Tayebeh Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(19)H(18)I(4)N(2)O(2), comprises a potentially tetradentate Schiff base ligand. The disordered H atoms on the N and O atoms were refined with site occupancies of 0.54 (8)/0.46 (8) and 0.59 (7)/0.41 (7), respectively. The dihedral angle between the benzene rings is 73.3 (3)°. Intramolecular O—H⋯N and N—H⋯O hydrogen bonds make S(6) ring motifs. Short I⋯I [3.8919 (7) Å] and I⋯Cg [Cg is a ring centroid; 3.911 (2) Å] contacts are present in the crystal structure. The crystal structure is further stabilized by intermolecular π–π interactions [centroid-to-centroid distance = 3.827 (3) Å]. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297293/ /pubmed/22412483 http://dx.doi.org/10.1107/S1600536812003704 Text en © Kargar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kargar, Hadi Kia, Reza Shakarami, Tayebeh Tahir, Muhammad Nawaz 2-((E)-{3-[(E)-2-Hydroxy-3,5-diiodobenzylideneamino]-2,2-dimethylpropyl}iminomethyl)-4,6-diiodophenol |
title | 2-((E)-{3-[(E)-2-Hydroxy-3,5-diiodobenzylideneamino]-2,2-dimethylpropyl}iminomethyl)-4,6-diiodophenol |
title_full | 2-((E)-{3-[(E)-2-Hydroxy-3,5-diiodobenzylideneamino]-2,2-dimethylpropyl}iminomethyl)-4,6-diiodophenol |
title_fullStr | 2-((E)-{3-[(E)-2-Hydroxy-3,5-diiodobenzylideneamino]-2,2-dimethylpropyl}iminomethyl)-4,6-diiodophenol |
title_full_unstemmed | 2-((E)-{3-[(E)-2-Hydroxy-3,5-diiodobenzylideneamino]-2,2-dimethylpropyl}iminomethyl)-4,6-diiodophenol |
title_short | 2-((E)-{3-[(E)-2-Hydroxy-3,5-diiodobenzylideneamino]-2,2-dimethylpropyl}iminomethyl)-4,6-diiodophenol |
title_sort | 2-((e)-{3-[(e)-2-hydroxy-3,5-diiodobenzylideneamino]-2,2-dimethylpropyl}iminomethyl)-4,6-diiodophenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297293/ https://www.ncbi.nlm.nih.gov/pubmed/22412483 http://dx.doi.org/10.1107/S1600536812003704 |
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