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2-((E)-{3-[(E)-2-Hy­droxy-3,5-diiodo­benzyl­idene­amino]-2,2-dimethyl­prop­yl}imino­meth­yl)-4,6-diiodo­phenol

The asymmetric unit of the title compound, C(19)H(18)I(4)N(2)O(2), comprises a potentially tetra­dentate Schiff base ligand. The disordered H atoms on the N and O atoms were refined with site occupancies of 0.54 (8)/0.46 (8) and 0.59 (7)/0.41 (7), respectively. The dihedral angle between the benzene...

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Autores principales: Kargar, Hadi, Kia, Reza, Shakarami, Tayebeh, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297293/
https://www.ncbi.nlm.nih.gov/pubmed/22412483
http://dx.doi.org/10.1107/S1600536812003704
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author Kargar, Hadi
Kia, Reza
Shakarami, Tayebeh
Tahir, Muhammad Nawaz
author_facet Kargar, Hadi
Kia, Reza
Shakarami, Tayebeh
Tahir, Muhammad Nawaz
author_sort Kargar, Hadi
collection PubMed
description The asymmetric unit of the title compound, C(19)H(18)I(4)N(2)O(2), comprises a potentially tetra­dentate Schiff base ligand. The disordered H atoms on the N and O atoms were refined with site occupancies of 0.54 (8)/0.46 (8) and 0.59 (7)/0.41 (7), respectively. The dihedral angle between the benzene rings is 73.3 (3)°. Intra­molecular O—H⋯N and N—H⋯O hydrogen bonds make S(6) ring motifs. Short I⋯I [3.8919 (7) Å] and I⋯Cg [Cg is a ring centroid; 3.911 (2) Å] contacts are present in the crystal structure. The crystal structure is further stabilized by inter­molecular π–π inter­actions [centroid-to-centroid distance = 3.827 (3) Å].
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spelling pubmed-32972932012-03-12 2-((E)-{3-[(E)-2-Hy­droxy-3,5-diiodo­benzyl­idene­amino]-2,2-dimethyl­prop­yl}imino­meth­yl)-4,6-diiodo­phenol Kargar, Hadi Kia, Reza Shakarami, Tayebeh Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(19)H(18)I(4)N(2)O(2), comprises a potentially tetra­dentate Schiff base ligand. The disordered H atoms on the N and O atoms were refined with site occupancies of 0.54 (8)/0.46 (8) and 0.59 (7)/0.41 (7), respectively. The dihedral angle between the benzene rings is 73.3 (3)°. Intra­molecular O—H⋯N and N—H⋯O hydrogen bonds make S(6) ring motifs. Short I⋯I [3.8919 (7) Å] and I⋯Cg [Cg is a ring centroid; 3.911 (2) Å] contacts are present in the crystal structure. The crystal structure is further stabilized by inter­molecular π–π inter­actions [centroid-to-centroid distance = 3.827 (3) Å]. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297293/ /pubmed/22412483 http://dx.doi.org/10.1107/S1600536812003704 Text en © Kargar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kargar, Hadi
Kia, Reza
Shakarami, Tayebeh
Tahir, Muhammad Nawaz
2-((E)-{3-[(E)-2-Hy­droxy-3,5-diiodo­benzyl­idene­amino]-2,2-dimethyl­prop­yl}imino­meth­yl)-4,6-diiodo­phenol
title 2-((E)-{3-[(E)-2-Hy­droxy-3,5-diiodo­benzyl­idene­amino]-2,2-dimethyl­prop­yl}imino­meth­yl)-4,6-diiodo­phenol
title_full 2-((E)-{3-[(E)-2-Hy­droxy-3,5-diiodo­benzyl­idene­amino]-2,2-dimethyl­prop­yl}imino­meth­yl)-4,6-diiodo­phenol
title_fullStr 2-((E)-{3-[(E)-2-Hy­droxy-3,5-diiodo­benzyl­idene­amino]-2,2-dimethyl­prop­yl}imino­meth­yl)-4,6-diiodo­phenol
title_full_unstemmed 2-((E)-{3-[(E)-2-Hy­droxy-3,5-diiodo­benzyl­idene­amino]-2,2-dimethyl­prop­yl}imino­meth­yl)-4,6-diiodo­phenol
title_short 2-((E)-{3-[(E)-2-Hy­droxy-3,5-diiodo­benzyl­idene­amino]-2,2-dimethyl­prop­yl}imino­meth­yl)-4,6-diiodo­phenol
title_sort 2-((e)-{3-[(e)-2-hy­droxy-3,5-diiodo­benzyl­idene­amino]-2,2-dimethyl­prop­yl}imino­meth­yl)-4,6-diiodo­phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297293/
https://www.ncbi.nlm.nih.gov/pubmed/22412483
http://dx.doi.org/10.1107/S1600536812003704
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