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4-{4-[(E)-(2-Hydroxyphenyl)iminomethyl]phenoxy}benzene-1,2-dicarbonitrile
The asymmetric unit of the title compound, C(21)H(13)N(3)O(2), contains two independent molecules with a similar structure. In one molecule, the central benzene ring is oriented with respect to the terminal benzene rings at 27.23 (7) and 67.96 (7)°; in the other molecule, the corresponding dihedr...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297294/ https://www.ncbi.nlm.nih.gov/pubmed/22412484 http://dx.doi.org/10.1107/S1600536812003649 |
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author | Tuncer, Hülya Görgülü, Ahmet Orhan Hökelek, Tuncer |
author_facet | Tuncer, Hülya Görgülü, Ahmet Orhan Hökelek, Tuncer |
author_sort | Tuncer, Hülya |
collection | PubMed |
description | The asymmetric unit of the title compound, C(21)H(13)N(3)O(2), contains two independent molecules with a similar structure. In one molecule, the central benzene ring is oriented with respect to the terminal benzene rings at 27.23 (7) and 67.96 (7)°; in the other molecule, the corresponding dihedral angles are 12.42 (7) and 64.55 (7)°. In both molecules, there is a short O—H⋯N interaction involving the OH group and the adjacent N atom. In the crystal, there are O—H⋯N hydrogen bonds, and C—H⋯O and N—H⋯O interactions linking the molecules to form a three-dimensional network. π–π stacking between the pyridine and benzene rings and between the benzene rings [centroid–centroid distances = 3.989 (2), 3.705 (2) and 3.607 (2) Å] may further stabilize the structure. A weak C—H⋯π interaction is present in the crystal. |
format | Online Article Text |
id | pubmed-3297294 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32972942012-03-12 4-{4-[(E)-(2-Hydroxyphenyl)iminomethyl]phenoxy}benzene-1,2-dicarbonitrile Tuncer, Hülya Görgülü, Ahmet Orhan Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(21)H(13)N(3)O(2), contains two independent molecules with a similar structure. In one molecule, the central benzene ring is oriented with respect to the terminal benzene rings at 27.23 (7) and 67.96 (7)°; in the other molecule, the corresponding dihedral angles are 12.42 (7) and 64.55 (7)°. In both molecules, there is a short O—H⋯N interaction involving the OH group and the adjacent N atom. In the crystal, there are O—H⋯N hydrogen bonds, and C—H⋯O and N—H⋯O interactions linking the molecules to form a three-dimensional network. π–π stacking between the pyridine and benzene rings and between the benzene rings [centroid–centroid distances = 3.989 (2), 3.705 (2) and 3.607 (2) Å] may further stabilize the structure. A weak C—H⋯π interaction is present in the crystal. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297294/ /pubmed/22412484 http://dx.doi.org/10.1107/S1600536812003649 Text en © Tuncer et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Tuncer, Hülya Görgülü, Ahmet Orhan Hökelek, Tuncer 4-{4-[(E)-(2-Hydroxyphenyl)iminomethyl]phenoxy}benzene-1,2-dicarbonitrile |
title | 4-{4-[(E)-(2-Hydroxyphenyl)iminomethyl]phenoxy}benzene-1,2-dicarbonitrile |
title_full | 4-{4-[(E)-(2-Hydroxyphenyl)iminomethyl]phenoxy}benzene-1,2-dicarbonitrile |
title_fullStr | 4-{4-[(E)-(2-Hydroxyphenyl)iminomethyl]phenoxy}benzene-1,2-dicarbonitrile |
title_full_unstemmed | 4-{4-[(E)-(2-Hydroxyphenyl)iminomethyl]phenoxy}benzene-1,2-dicarbonitrile |
title_short | 4-{4-[(E)-(2-Hydroxyphenyl)iminomethyl]phenoxy}benzene-1,2-dicarbonitrile |
title_sort | 4-{4-[(e)-(2-hydroxyphenyl)iminomethyl]phenoxy}benzene-1,2-dicarbonitrile |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297294/ https://www.ncbi.nlm.nih.gov/pubmed/22412484 http://dx.doi.org/10.1107/S1600536812003649 |
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