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4-{4-[(E)-(2-Hy­droxy­phen­yl)imino­methyl]phen­oxy}benzene-1,2-di­carbo­nitrile

The asymmetric unit of the title compound, C(21)H(13)N(3)O(2), contains two independent mol­ecules with a similar structure. In one mol­ecule, the central benzene ring is oriented with respect to the terminal benzene rings at 27.23 (7) and 67.96 (7)°; in the other mol­ecule, the corresponding dihedr...

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Autores principales: Tuncer, Hülya, Görgülü, Ahmet Orhan, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297294/
https://www.ncbi.nlm.nih.gov/pubmed/22412484
http://dx.doi.org/10.1107/S1600536812003649
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author Tuncer, Hülya
Görgülü, Ahmet Orhan
Hökelek, Tuncer
author_facet Tuncer, Hülya
Görgülü, Ahmet Orhan
Hökelek, Tuncer
author_sort Tuncer, Hülya
collection PubMed
description The asymmetric unit of the title compound, C(21)H(13)N(3)O(2), contains two independent mol­ecules with a similar structure. In one mol­ecule, the central benzene ring is oriented with respect to the terminal benzene rings at 27.23 (7) and 67.96 (7)°; in the other mol­ecule, the corresponding dihedral angles are 12.42 (7) and 64.55 (7)°. In both molecules, there is a short O—H⋯N interaction involving the OH group and the adjacent N atom. In the crystal, there are O—H⋯N hydrogen bonds, and C—H⋯O and N—H⋯O interactions linking the molecules to form a three-dimensional network. π–π stacking between the pyridine and benzene rings and between the benzene rings [centroid–centroid distances = 3.989 (2), 3.705 (2) and 3.607 (2) Å] may further stabilize the structure. A weak C—H⋯π inter­action is present in the crystal.
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spelling pubmed-32972942012-03-12 4-{4-[(E)-(2-Hy­droxy­phen­yl)imino­methyl]phen­oxy}benzene-1,2-di­carbo­nitrile Tuncer, Hülya Görgülü, Ahmet Orhan Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(21)H(13)N(3)O(2), contains two independent mol­ecules with a similar structure. In one mol­ecule, the central benzene ring is oriented with respect to the terminal benzene rings at 27.23 (7) and 67.96 (7)°; in the other mol­ecule, the corresponding dihedral angles are 12.42 (7) and 64.55 (7)°. In both molecules, there is a short O—H⋯N interaction involving the OH group and the adjacent N atom. In the crystal, there are O—H⋯N hydrogen bonds, and C—H⋯O and N—H⋯O interactions linking the molecules to form a three-dimensional network. π–π stacking between the pyridine and benzene rings and between the benzene rings [centroid–centroid distances = 3.989 (2), 3.705 (2) and 3.607 (2) Å] may further stabilize the structure. A weak C—H⋯π inter­action is present in the crystal. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297294/ /pubmed/22412484 http://dx.doi.org/10.1107/S1600536812003649 Text en © Tuncer et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tuncer, Hülya
Görgülü, Ahmet Orhan
Hökelek, Tuncer
4-{4-[(E)-(2-Hy­droxy­phen­yl)imino­methyl]phen­oxy}benzene-1,2-di­carbo­nitrile
title 4-{4-[(E)-(2-Hy­droxy­phen­yl)imino­methyl]phen­oxy}benzene-1,2-di­carbo­nitrile
title_full 4-{4-[(E)-(2-Hy­droxy­phen­yl)imino­methyl]phen­oxy}benzene-1,2-di­carbo­nitrile
title_fullStr 4-{4-[(E)-(2-Hy­droxy­phen­yl)imino­methyl]phen­oxy}benzene-1,2-di­carbo­nitrile
title_full_unstemmed 4-{4-[(E)-(2-Hy­droxy­phen­yl)imino­methyl]phen­oxy}benzene-1,2-di­carbo­nitrile
title_short 4-{4-[(E)-(2-Hy­droxy­phen­yl)imino­methyl]phen­oxy}benzene-1,2-di­carbo­nitrile
title_sort 4-{4-[(e)-(2-hy­droxy­phen­yl)imino­methyl]phen­oxy}benzene-1,2-di­carbo­nitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297294/
https://www.ncbi.nlm.nih.gov/pubmed/22412484
http://dx.doi.org/10.1107/S1600536812003649
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