3,3′-[1,2-Phenyl­enebis(methyl­ene)]bis­(1-ethyl­benzimidazolium) dibromide

In the title mol­ecular salt, C(26)H(28)N(4) (2+)·2Br(−), the central benzene ring makes dihedral angles of 76.75 (11) and 82.40 (10)° with the pendant benzimidazole rings. The corresponding angle between the benzimidazole rings is 57.03 (9)°. In the crystal, the cations and anions are linked via C—...

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Autores principales: Haque, Rosenani A., Iqbal, Muhammad Adnan, Budagumpi, Srinivasa, Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297300/
https://www.ncbi.nlm.nih.gov/pubmed/22412490
http://dx.doi.org/10.1107/S1600536812002802
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author Haque, Rosenani A.
Iqbal, Muhammad Adnan
Budagumpi, Srinivasa
Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Haque, Rosenani A.
Iqbal, Muhammad Adnan
Budagumpi, Srinivasa
Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Haque, Rosenani A.
collection PubMed
description In the title mol­ecular salt, C(26)H(28)N(4) (2+)·2Br(−), the central benzene ring makes dihedral angles of 76.75 (11) and 82.40 (10)° with the pendant benzimidazole rings. The corresponding angle between the benzimidazole rings is 57.03 (9)°. In the crystal, the cations and anions are linked via C—H⋯Br hydrogen bonds, forming sheets lying parallel to the bc plane. The crystal structure also features weak C—H⋯π inter­actions.
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spelling pubmed-32973002012-03-12 3,3′-[1,2-Phenyl­enebis(methyl­ene)]bis­(1-ethyl­benzimidazolium) dibromide Haque, Rosenani A. Iqbal, Muhammad Adnan Budagumpi, Srinivasa Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecular salt, C(26)H(28)N(4) (2+)·2Br(−), the central benzene ring makes dihedral angles of 76.75 (11) and 82.40 (10)° with the pendant benzimidazole rings. The corresponding angle between the benzimidazole rings is 57.03 (9)°. In the crystal, the cations and anions are linked via C—H⋯Br hydrogen bonds, forming sheets lying parallel to the bc plane. The crystal structure also features weak C—H⋯π inter­actions. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297300/ /pubmed/22412490 http://dx.doi.org/10.1107/S1600536812002802 Text en © Haque et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Haque, Rosenani A.
Iqbal, Muhammad Adnan
Budagumpi, Srinivasa
Hemamalini, Madhukar
Fun, Hoong-Kun
3,3′-[1,2-Phenyl­enebis(methyl­ene)]bis­(1-ethyl­benzimidazolium) dibromide
title 3,3′-[1,2-Phenyl­enebis(methyl­ene)]bis­(1-ethyl­benzimidazolium) dibromide
title_full 3,3′-[1,2-Phenyl­enebis(methyl­ene)]bis­(1-ethyl­benzimidazolium) dibromide
title_fullStr 3,3′-[1,2-Phenyl­enebis(methyl­ene)]bis­(1-ethyl­benzimidazolium) dibromide
title_full_unstemmed 3,3′-[1,2-Phenyl­enebis(methyl­ene)]bis­(1-ethyl­benzimidazolium) dibromide
title_short 3,3′-[1,2-Phenyl­enebis(methyl­ene)]bis­(1-ethyl­benzimidazolium) dibromide
title_sort 3,3′-[1,2-phenyl­enebis(methyl­ene)]bis­(1-ethyl­benzimidazolium) dibromide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297300/
https://www.ncbi.nlm.nih.gov/pubmed/22412490
http://dx.doi.org/10.1107/S1600536812002802
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