(1R*,2S*,4S*,5R*)-Cyclo­hexane-1,2:4,5-tetra­carb­oxy­lic dianhydride

The title compound, C(10)H(8)O(6), a promising raw material to obtain colorless polyimides which are applied to microelectronic and optoelectronic devices, adopts a folded conformation in which the dihedral angle between the two anhydro rings is 55.15 (8)°. The central six-membered ring assumes a co...

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Autores principales: Uchida, Akira, Hasegawa, Masatoshi, Takezawa, Eiichiro, Yamaguchi, Shinya, Ishikawa, Atsushi, Kagayama, Takashi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297306/
https://www.ncbi.nlm.nih.gov/pubmed/22412496
http://dx.doi.org/10.1107/S1600536812003571
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author Uchida, Akira
Hasegawa, Masatoshi
Takezawa, Eiichiro
Yamaguchi, Shinya
Ishikawa, Atsushi
Kagayama, Takashi
author_facet Uchida, Akira
Hasegawa, Masatoshi
Takezawa, Eiichiro
Yamaguchi, Shinya
Ishikawa, Atsushi
Kagayama, Takashi
author_sort Uchida, Akira
collection PubMed
description The title compound, C(10)H(8)O(6), a promising raw material to obtain colorless polyimides which are applied to microelectronic and optoelectronic devices, adopts a folded conformation in which the dihedral angle between the two anhydro rings is 55.15 (8)°. The central six-membered ring assumes a conformation inter­mediate between boat and twist-boat. In the crystal, mol­ecules are linked by weak C—H⋯O inter­actions, forming a layer parallel to the bc plane.
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spelling pubmed-32973062012-03-12 (1R*,2S*,4S*,5R*)-Cyclo­hexane-1,2:4,5-tetra­carb­oxy­lic dianhydride Uchida, Akira Hasegawa, Masatoshi Takezawa, Eiichiro Yamaguchi, Shinya Ishikawa, Atsushi Kagayama, Takashi Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(8)O(6), a promising raw material to obtain colorless polyimides which are applied to microelectronic and optoelectronic devices, adopts a folded conformation in which the dihedral angle between the two anhydro rings is 55.15 (8)°. The central six-membered ring assumes a conformation inter­mediate between boat and twist-boat. In the crystal, mol­ecules are linked by weak C—H⋯O inter­actions, forming a layer parallel to the bc plane. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297306/ /pubmed/22412496 http://dx.doi.org/10.1107/S1600536812003571 Text en © Uchida et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Uchida, Akira
Hasegawa, Masatoshi
Takezawa, Eiichiro
Yamaguchi, Shinya
Ishikawa, Atsushi
Kagayama, Takashi
(1R*,2S*,4S*,5R*)-Cyclo­hexane-1,2:4,5-tetra­carb­oxy­lic dianhydride
title (1R*,2S*,4S*,5R*)-Cyclo­hexane-1,2:4,5-tetra­carb­oxy­lic dianhydride
title_full (1R*,2S*,4S*,5R*)-Cyclo­hexane-1,2:4,5-tetra­carb­oxy­lic dianhydride
title_fullStr (1R*,2S*,4S*,5R*)-Cyclo­hexane-1,2:4,5-tetra­carb­oxy­lic dianhydride
title_full_unstemmed (1R*,2S*,4S*,5R*)-Cyclo­hexane-1,2:4,5-tetra­carb­oxy­lic dianhydride
title_short (1R*,2S*,4S*,5R*)-Cyclo­hexane-1,2:4,5-tetra­carb­oxy­lic dianhydride
title_sort (1r*,2s*,4s*,5r*)-cyclo­hexane-1,2:4,5-tetra­carb­oxy­lic dianhydride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297306/
https://www.ncbi.nlm.nih.gov/pubmed/22412496
http://dx.doi.org/10.1107/S1600536812003571
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