(1S,2S,6R,7aR)-2-Benzyl-1,6-dihy­droxy­hexa­hydro­pyrrolizin-3-one

In the title compound, C(14)H(17)NO(3), the dihedral angles show that the H atoms at two stereocenters are in a trans-diaxial configuration. In the crystal, the molecules are linked by O—H⋯O hydrogen bonds. The absolute configuration of the molecule has been established on the basis of refinement of...

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Detalles Bibliográficos
Autores principales: Oliveira, F. L., Freire, K. R. L., Aparicio, R., Coelho, F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297313/
https://www.ncbi.nlm.nih.gov/pubmed/22412503
http://dx.doi.org/10.1107/S1600536812002334
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author Oliveira, F. L.
Freire, K. R. L.
Aparicio, R.
Coelho, F.
author_facet Oliveira, F. L.
Freire, K. R. L.
Aparicio, R.
Coelho, F.
author_sort Oliveira, F. L.
collection PubMed
description In the title compound, C(14)H(17)NO(3), the dihedral angles show that the H atoms at two stereocenters are in a trans-diaxial configuration. In the crystal, the molecules are linked by O—H⋯O hydrogen bonds. The absolute configuration of the molecule has been established on the basis of refinement of the Hooft and Flack parameters.
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spelling pubmed-32973132012-03-12 (1S,2S,6R,7aR)-2-Benzyl-1,6-dihy­droxy­hexa­hydro­pyrrolizin-3-one Oliveira, F. L. Freire, K. R. L. Aparicio, R. Coelho, F. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(17)NO(3), the dihedral angles show that the H atoms at two stereocenters are in a trans-diaxial configuration. In the crystal, the molecules are linked by O—H⋯O hydrogen bonds. The absolute configuration of the molecule has been established on the basis of refinement of the Hooft and Flack parameters. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297313/ /pubmed/22412503 http://dx.doi.org/10.1107/S1600536812002334 Text en © Oliveira et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Oliveira, F. L.
Freire, K. R. L.
Aparicio, R.
Coelho, F.
(1S,2S,6R,7aR)-2-Benzyl-1,6-dihy­droxy­hexa­hydro­pyrrolizin-3-one
title (1S,2S,6R,7aR)-2-Benzyl-1,6-dihy­droxy­hexa­hydro­pyrrolizin-3-one
title_full (1S,2S,6R,7aR)-2-Benzyl-1,6-dihy­droxy­hexa­hydro­pyrrolizin-3-one
title_fullStr (1S,2S,6R,7aR)-2-Benzyl-1,6-dihy­droxy­hexa­hydro­pyrrolizin-3-one
title_full_unstemmed (1S,2S,6R,7aR)-2-Benzyl-1,6-dihy­droxy­hexa­hydro­pyrrolizin-3-one
title_short (1S,2S,6R,7aR)-2-Benzyl-1,6-dihy­droxy­hexa­hydro­pyrrolizin-3-one
title_sort (1s,2s,6r,7ar)-2-benzyl-1,6-dihy­droxy­hexa­hydro­pyrrolizin-3-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297313/
https://www.ncbi.nlm.nih.gov/pubmed/22412503
http://dx.doi.org/10.1107/S1600536812002334
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