(E)-3-Methyl-N′-(4-nitro­benzyl­idene)benzohydrazide methanol monosolvate

The title hydrazone compound, C(15)H(13)N(3)O(3)·CH(3)OH, crystallized as a methanol solvate. The hydrazone mol­ecule has an E configuration about the C=N bond and is almost planar, with a dihedral angle between the benzene rings of 5.3 (3)°. In the crystal, the hydrazone mol­ecules are linked via t...

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Autor principal: Tang, Chun-Bao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297325/
https://www.ncbi.nlm.nih.gov/pubmed/22412515
http://dx.doi.org/10.1107/S1600536812003868
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author Tang, Chun-Bao
author_facet Tang, Chun-Bao
author_sort Tang, Chun-Bao
collection PubMed
description The title hydrazone compound, C(15)H(13)N(3)O(3)·CH(3)OH, crystallized as a methanol solvate. The hydrazone mol­ecule has an E configuration about the C=N bond and is almost planar, with a dihedral angle between the benzene rings of 5.3 (3)°. In the crystal, the hydrazone mol­ecules are linked via the methanol solvent mol­ecule through N—H⋯O and O—H⋯O hydrogen bonds, so forming chains propagating along the a-axis direction.
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spelling pubmed-32973252012-03-12 (E)-3-Methyl-N′-(4-nitro­benzyl­idene)benzohydrazide methanol monosolvate Tang, Chun-Bao Acta Crystallogr Sect E Struct Rep Online Organic Papers The title hydrazone compound, C(15)H(13)N(3)O(3)·CH(3)OH, crystallized as a methanol solvate. The hydrazone mol­ecule has an E configuration about the C=N bond and is almost planar, with a dihedral angle between the benzene rings of 5.3 (3)°. In the crystal, the hydrazone mol­ecules are linked via the methanol solvent mol­ecule through N—H⋯O and O—H⋯O hydrogen bonds, so forming chains propagating along the a-axis direction. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3297325/ /pubmed/22412515 http://dx.doi.org/10.1107/S1600536812003868 Text en © Chun-Bao Tang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tang, Chun-Bao
(E)-3-Methyl-N′-(4-nitro­benzyl­idene)benzohydrazide methanol monosolvate
title (E)-3-Methyl-N′-(4-nitro­benzyl­idene)benzohydrazide methanol monosolvate
title_full (E)-3-Methyl-N′-(4-nitro­benzyl­idene)benzohydrazide methanol monosolvate
title_fullStr (E)-3-Methyl-N′-(4-nitro­benzyl­idene)benzohydrazide methanol monosolvate
title_full_unstemmed (E)-3-Methyl-N′-(4-nitro­benzyl­idene)benzohydrazide methanol monosolvate
title_short (E)-3-Methyl-N′-(4-nitro­benzyl­idene)benzohydrazide methanol monosolvate
title_sort (e)-3-methyl-n′-(4-nitro­benzyl­idene)benzohydrazide methanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297325/
https://www.ncbi.nlm.nih.gov/pubmed/22412515
http://dx.doi.org/10.1107/S1600536812003868
work_keys_str_mv AT tangchunbao e3methyln4nitrobenzylidenebenzohydrazidemethanolmonosolvate

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