4-Bromo-N-(4-hy­droxy­benzyl­idene)­aniline

In the title compound, C(13)H(10)BrNO, the benzene ring planes are inclined at an angle of 48.85 (17)°, resulting in a nonplanar mol­ecule. A characteristic of aromatic Schiff bases with N-aryl substituents is that the terminal phenyl rings are twisted relative to the HC=N plane. In this case, the H...

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Autores principales: Jothi, L., Vasuki, G., Babu, R. Ramesh, Ramamurthi, K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297843/
https://www.ncbi.nlm.nih.gov/pubmed/22412646
http://dx.doi.org/10.1107/S1600536812006101
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author Jothi, L.
Vasuki, G.
Babu, R. Ramesh
Ramamurthi, K.
author_facet Jothi, L.
Vasuki, G.
Babu, R. Ramesh
Ramamurthi, K.
author_sort Jothi, L.
collection PubMed
description In the title compound, C(13)H(10)BrNO, the benzene ring planes are inclined at an angle of 48.85 (17)°, resulting in a nonplanar mol­ecule. A characteristic of aromatic Schiff bases with N-aryl substituents is that the terminal phenyl rings are twisted relative to the HC=N plane. In this case, the HC=N unit makes dihedral angles of 11.1 (4) and 38.5 (3)° with the hy­droxy­benzene and bromo­benzene rings, respectively. In the crystal, the molecules are linked by O—H⋯N hydrogen bonds to form infinite (C8) chains along the b axis.
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spelling pubmed-32978432012-03-12 4-Bromo-N-(4-hy­droxy­benzyl­idene)­aniline Jothi, L. Vasuki, G. Babu, R. Ramesh Ramamurthi, K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(10)BrNO, the benzene ring planes are inclined at an angle of 48.85 (17)°, resulting in a nonplanar mol­ecule. A characteristic of aromatic Schiff bases with N-aryl substituents is that the terminal phenyl rings are twisted relative to the HC=N plane. In this case, the HC=N unit makes dihedral angles of 11.1 (4) and 38.5 (3)° with the hy­droxy­benzene and bromo­benzene rings, respectively. In the crystal, the molecules are linked by O—H⋯N hydrogen bonds to form infinite (C8) chains along the b axis. International Union of Crystallography 2012-02-17 /pmc/articles/PMC3297843/ /pubmed/22412646 http://dx.doi.org/10.1107/S1600536812006101 Text en © Jothi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jothi, L.
Vasuki, G.
Babu, R. Ramesh
Ramamurthi, K.
4-Bromo-N-(4-hy­droxy­benzyl­idene)­aniline
title 4-Bromo-N-(4-hy­droxy­benzyl­idene)­aniline
title_full 4-Bromo-N-(4-hy­droxy­benzyl­idene)­aniline
title_fullStr 4-Bromo-N-(4-hy­droxy­benzyl­idene)­aniline
title_full_unstemmed 4-Bromo-N-(4-hy­droxy­benzyl­idene)­aniline
title_short 4-Bromo-N-(4-hy­droxy­benzyl­idene)­aniline
title_sort 4-bromo-n-(4-hy­droxy­benzyl­idene)­aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297843/
https://www.ncbi.nlm.nih.gov/pubmed/22412646
http://dx.doi.org/10.1107/S1600536812006101
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AT vasukig 4bromon4hydroxybenzylideneaniline
AT baburramesh 4bromon4hydroxybenzylideneaniline
AT ramamurthik 4bromon4hydroxybenzylideneaniline

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