Methyl (Z)-2-[(4-bromo-2-formyl­phen­oxy)meth­yl]-3-(4-methyl­phen­yl)acrylate

In the title compound, C(19)H(17)BrO(4), the dihedral angle between the two benzene rings is 82.9 (2)°. The mol­ecular structure is stabilized by an intra­molecular C—H⋯O hydrogen bond, which generates an S(7) ring motif. The crystal packing is stabilized by C—H⋯O hydrogen bonds, which generate two...

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Detalles Bibliográficos
Autores principales: Vijayakumar, S., Murugavel, S., Kannan, D., Bakthadoss, M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297846/
https://www.ncbi.nlm.nih.gov/pubmed/22412649
http://dx.doi.org/10.1107/S1600536812006630
Descripción
Sumario:In the title compound, C(19)H(17)BrO(4), the dihedral angle between the two benzene rings is 82.9 (2)°. The mol­ecular structure is stabilized by an intra­molecular C—H⋯O hydrogen bond, which generates an S(7) ring motif. The crystal packing is stabilized by C—H⋯O hydrogen bonds, which generate two centrosymmetic ring systems with R(2)(2)(18) and R(2)(2)(14) graph-set motifs. The crystal packing is further stabilized by inter­molecular π–π inter­actions [centroid–centroid distance = 3.984 (2) Å].

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