Methyl (Z)-2-[(4-bromo-2-formyl­phen­oxy)meth­yl]-3-(4-methyl­phen­yl)acrylate

In the title compound, C(19)H(17)BrO(4), the dihedral angle between the two benzene rings is 82.9 (2)°. The mol­ecular structure is stabilized by an intra­molecular C—H⋯O hydrogen bond, which generates an S(7) ring motif. The crystal packing is stabilized by C—H⋯O hydrogen bonds, which generate two...

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Detalles Bibliográficos
Autores principales: Vijayakumar, S., Murugavel, S., Kannan, D., Bakthadoss, M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297846/
https://www.ncbi.nlm.nih.gov/pubmed/22412649
http://dx.doi.org/10.1107/S1600536812006630
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author Vijayakumar, S.
Murugavel, S.
Kannan, D.
Bakthadoss, M.
author_facet Vijayakumar, S.
Murugavel, S.
Kannan, D.
Bakthadoss, M.
author_sort Vijayakumar, S.
collection PubMed
description In the title compound, C(19)H(17)BrO(4), the dihedral angle between the two benzene rings is 82.9 (2)°. The mol­ecular structure is stabilized by an intra­molecular C—H⋯O hydrogen bond, which generates an S(7) ring motif. The crystal packing is stabilized by C—H⋯O hydrogen bonds, which generate two centrosymmetic ring systems with R(2)(2)(18) and R(2)(2)(14) graph-set motifs. The crystal packing is further stabilized by inter­molecular π–π inter­actions [centroid–centroid distance = 3.984 (2) Å].
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spelling pubmed-32978462012-03-12 Methyl (Z)-2-[(4-bromo-2-formyl­phen­oxy)meth­yl]-3-(4-methyl­phen­yl)acrylate Vijayakumar, S. Murugavel, S. Kannan, D. Bakthadoss, M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(17)BrO(4), the dihedral angle between the two benzene rings is 82.9 (2)°. The mol­ecular structure is stabilized by an intra­molecular C—H⋯O hydrogen bond, which generates an S(7) ring motif. The crystal packing is stabilized by C—H⋯O hydrogen bonds, which generate two centrosymmetic ring systems with R(2)(2)(18) and R(2)(2)(14) graph-set motifs. The crystal packing is further stabilized by inter­molecular π–π inter­actions [centroid–centroid distance = 3.984 (2) Å]. International Union of Crystallography 2012-02-17 /pmc/articles/PMC3297846/ /pubmed/22412649 http://dx.doi.org/10.1107/S1600536812006630 Text en © Vijayakumar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Vijayakumar, S.
Murugavel, S.
Kannan, D.
Bakthadoss, M.
Methyl (Z)-2-[(4-bromo-2-formyl­phen­oxy)meth­yl]-3-(4-methyl­phen­yl)acrylate
title Methyl (Z)-2-[(4-bromo-2-formyl­phen­oxy)meth­yl]-3-(4-methyl­phen­yl)acrylate
title_full Methyl (Z)-2-[(4-bromo-2-formyl­phen­oxy)meth­yl]-3-(4-methyl­phen­yl)acrylate
title_fullStr Methyl (Z)-2-[(4-bromo-2-formyl­phen­oxy)meth­yl]-3-(4-methyl­phen­yl)acrylate
title_full_unstemmed Methyl (Z)-2-[(4-bromo-2-formyl­phen­oxy)meth­yl]-3-(4-methyl­phen­yl)acrylate
title_short Methyl (Z)-2-[(4-bromo-2-formyl­phen­oxy)meth­yl]-3-(4-methyl­phen­yl)acrylate
title_sort methyl (z)-2-[(4-bromo-2-formyl­phen­oxy)meth­yl]-3-(4-methyl­phen­yl)acrylate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297846/
https://www.ncbi.nlm.nih.gov/pubmed/22412649
http://dx.doi.org/10.1107/S1600536812006630
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