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N-(3-Chloro­benzo­yl)-2-nitro­benzene­sulfonamide

In the title compound, C(13)H(9)ClN(2)O(5)S, the N—C bond in the C—SO(2)—NH—C segment has a gauche torsion with respect to the S=O bonds. The conformation between the N—H bond and the ortho-nitro group in the sulfonyl benzene ring is syn, and that between the C=O and the meta-Cl atom in the benzoyl...

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Autores principales: Suchetan, P. A., Foro, Sabine, Gowda, B. Thimme, Prakash, M. Shet
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297855/
https://www.ncbi.nlm.nih.gov/pubmed/22412658
http://dx.doi.org/10.1107/S160053681200640X
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author Suchetan, P. A.
Foro, Sabine
Gowda, B. Thimme
Prakash, M. Shet
author_facet Suchetan, P. A.
Foro, Sabine
Gowda, B. Thimme
Prakash, M. Shet
author_sort Suchetan, P. A.
collection PubMed
description In the title compound, C(13)H(9)ClN(2)O(5)S, the N—C bond in the C—SO(2)—NH—C segment has a gauche torsion with respect to the S=O bonds. The conformation between the N—H bond and the ortho-nitro group in the sulfonyl benzene ring is syn, and that between the C=O and the meta-Cl atom in the benzoyl ring is anti. The mol­ecule is twisted at the S—N bond, with a torsion angle of 65.41 (38)°. The dihedral angle between the sulfonyl benzene ring and the –SO(2)—NH—C—O segment is 75.0 (1)°, and that between the sulfonyl and the benzoyl benzene ring is 89.1 (1)°. The crystal structure features inversion-related dimers linked by pairs of N—H⋯O(S) hydrogen bonds.
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spelling pubmed-32978552012-03-12 N-(3-Chloro­benzo­yl)-2-nitro­benzene­sulfonamide Suchetan, P. A. Foro, Sabine Gowda, B. Thimme Prakash, M. Shet Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(9)ClN(2)O(5)S, the N—C bond in the C—SO(2)—NH—C segment has a gauche torsion with respect to the S=O bonds. The conformation between the N—H bond and the ortho-nitro group in the sulfonyl benzene ring is syn, and that between the C=O and the meta-Cl atom in the benzoyl ring is anti. The mol­ecule is twisted at the S—N bond, with a torsion angle of 65.41 (38)°. The dihedral angle between the sulfonyl benzene ring and the –SO(2)—NH—C—O segment is 75.0 (1)°, and that between the sulfonyl and the benzoyl benzene ring is 89.1 (1)°. The crystal structure features inversion-related dimers linked by pairs of N—H⋯O(S) hydrogen bonds. International Union of Crystallography 2012-02-17 /pmc/articles/PMC3297855/ /pubmed/22412658 http://dx.doi.org/10.1107/S160053681200640X Text en © Suchetan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Suchetan, P. A.
Foro, Sabine
Gowda, B. Thimme
Prakash, M. Shet
N-(3-Chloro­benzo­yl)-2-nitro­benzene­sulfonamide
title N-(3-Chloro­benzo­yl)-2-nitro­benzene­sulfonamide
title_full N-(3-Chloro­benzo­yl)-2-nitro­benzene­sulfonamide
title_fullStr N-(3-Chloro­benzo­yl)-2-nitro­benzene­sulfonamide
title_full_unstemmed N-(3-Chloro­benzo­yl)-2-nitro­benzene­sulfonamide
title_short N-(3-Chloro­benzo­yl)-2-nitro­benzene­sulfonamide
title_sort n-(3-chloro­benzo­yl)-2-nitro­benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297855/
https://www.ncbi.nlm.nih.gov/pubmed/22412658
http://dx.doi.org/10.1107/S160053681200640X
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AT prakashmshet n3chlorobenzoyl2nitrobenzenesulfonamide