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N-(3-Chlorobenzoyl)-2-nitrobenzenesulfonamide
In the title compound, C(13)H(9)ClN(2)O(5)S, the N—C bond in the C—SO(2)—NH—C segment has a gauche torsion with respect to the S=O bonds. The conformation between the N—H bond and the ortho-nitro group in the sulfonyl benzene ring is syn, and that between the C=O and the meta-Cl atom in the benzoyl...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297855/ https://www.ncbi.nlm.nih.gov/pubmed/22412658 http://dx.doi.org/10.1107/S160053681200640X |
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author | Suchetan, P. A. Foro, Sabine Gowda, B. Thimme Prakash, M. Shet |
author_facet | Suchetan, P. A. Foro, Sabine Gowda, B. Thimme Prakash, M. Shet |
author_sort | Suchetan, P. A. |
collection | PubMed |
description | In the title compound, C(13)H(9)ClN(2)O(5)S, the N—C bond in the C—SO(2)—NH—C segment has a gauche torsion with respect to the S=O bonds. The conformation between the N—H bond and the ortho-nitro group in the sulfonyl benzene ring is syn, and that between the C=O and the meta-Cl atom in the benzoyl ring is anti. The molecule is twisted at the S—N bond, with a torsion angle of 65.41 (38)°. The dihedral angle between the sulfonyl benzene ring and the –SO(2)—NH—C—O segment is 75.0 (1)°, and that between the sulfonyl and the benzoyl benzene ring is 89.1 (1)°. The crystal structure features inversion-related dimers linked by pairs of N—H⋯O(S) hydrogen bonds. |
format | Online Article Text |
id | pubmed-3297855 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32978552012-03-12 N-(3-Chlorobenzoyl)-2-nitrobenzenesulfonamide Suchetan, P. A. Foro, Sabine Gowda, B. Thimme Prakash, M. Shet Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(9)ClN(2)O(5)S, the N—C bond in the C—SO(2)—NH—C segment has a gauche torsion with respect to the S=O bonds. The conformation between the N—H bond and the ortho-nitro group in the sulfonyl benzene ring is syn, and that between the C=O and the meta-Cl atom in the benzoyl ring is anti. The molecule is twisted at the S—N bond, with a torsion angle of 65.41 (38)°. The dihedral angle between the sulfonyl benzene ring and the –SO(2)—NH—C—O segment is 75.0 (1)°, and that between the sulfonyl and the benzoyl benzene ring is 89.1 (1)°. The crystal structure features inversion-related dimers linked by pairs of N—H⋯O(S) hydrogen bonds. International Union of Crystallography 2012-02-17 /pmc/articles/PMC3297855/ /pubmed/22412658 http://dx.doi.org/10.1107/S160053681200640X Text en © Suchetan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Suchetan, P. A. Foro, Sabine Gowda, B. Thimme Prakash, M. Shet N-(3-Chlorobenzoyl)-2-nitrobenzenesulfonamide |
title |
N-(3-Chlorobenzoyl)-2-nitrobenzenesulfonamide |
title_full |
N-(3-Chlorobenzoyl)-2-nitrobenzenesulfonamide |
title_fullStr |
N-(3-Chlorobenzoyl)-2-nitrobenzenesulfonamide |
title_full_unstemmed |
N-(3-Chlorobenzoyl)-2-nitrobenzenesulfonamide |
title_short |
N-(3-Chlorobenzoyl)-2-nitrobenzenesulfonamide |
title_sort | n-(3-chlorobenzoyl)-2-nitrobenzenesulfonamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297855/ https://www.ncbi.nlm.nih.gov/pubmed/22412658 http://dx.doi.org/10.1107/S160053681200640X |
work_keys_str_mv | AT suchetanpa n3chlorobenzoyl2nitrobenzenesulfonamide AT forosabine n3chlorobenzoyl2nitrobenzenesulfonamide AT gowdabthimme n3chlorobenzoyl2nitrobenzenesulfonamide AT prakashmshet n3chlorobenzoyl2nitrobenzenesulfonamide |