2-[(E)-Phen­yl(2-phenyl­hydrazin-1-yl­idene)meth­yl]phenol

In the title hydrazone derivative, C(19)H(16)N(2)O, a twist is found between the hy­droxy­phenyl and N-bound phenyl rings [dihedral angle = 24.37 (7)°]. The C-bound phenyl ring is almost perpendicular to each of these planes [dihedral angles = 75.30 (7) and 86.00 (7)°, respectively]. The conformatio...

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Detalles Bibliográficos
Autores principales: Howie, R. Alan, Wardell, James L., Wardell, Solange M. S. V., Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297864/
https://www.ncbi.nlm.nih.gov/pubmed/22412667
http://dx.doi.org/10.1107/S1600536812005387
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author Howie, R. Alan
Wardell, James L.
Wardell, Solange M. S. V.
Tiekink, Edward R. T.
author_facet Howie, R. Alan
Wardell, James L.
Wardell, Solange M. S. V.
Tiekink, Edward R. T.
author_sort Howie, R. Alan
collection PubMed
description In the title hydrazone derivative, C(19)H(16)N(2)O, a twist is found between the hy­droxy­phenyl and N-bound phenyl rings [dihedral angle = 24.37 (7)°]. The C-bound phenyl ring is almost perpendicular to each of these planes [dihedral angles = 75.30 (7) and 86.00 (7)°, respectively]. The conformation about the imine bond [1.2935 (17) Å] is E. The hy­droxy group forms an intra­molecular hydrogen bond with the imine N atom. Zigzag chains along [001] mediated by N—H⋯O hydrogen bonds feature in the crystal packing.
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spelling pubmed-32978642012-03-12 2-[(E)-Phen­yl(2-phenyl­hydrazin-1-yl­idene)meth­yl]phenol Howie, R. Alan Wardell, James L. Wardell, Solange M. S. V. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title hydrazone derivative, C(19)H(16)N(2)O, a twist is found between the hy­droxy­phenyl and N-bound phenyl rings [dihedral angle = 24.37 (7)°]. The C-bound phenyl ring is almost perpendicular to each of these planes [dihedral angles = 75.30 (7) and 86.00 (7)°, respectively]. The conformation about the imine bond [1.2935 (17) Å] is E. The hy­droxy group forms an intra­molecular hydrogen bond with the imine N atom. Zigzag chains along [001] mediated by N—H⋯O hydrogen bonds feature in the crystal packing. International Union of Crystallography 2012-02-24 /pmc/articles/PMC3297864/ /pubmed/22412667 http://dx.doi.org/10.1107/S1600536812005387 Text en © Howie et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Howie, R. Alan
Wardell, James L.
Wardell, Solange M. S. V.
Tiekink, Edward R. T.
2-[(E)-Phen­yl(2-phenyl­hydrazin-1-yl­idene)meth­yl]phenol
title 2-[(E)-Phen­yl(2-phenyl­hydrazin-1-yl­idene)meth­yl]phenol
title_full 2-[(E)-Phen­yl(2-phenyl­hydrazin-1-yl­idene)meth­yl]phenol
title_fullStr 2-[(E)-Phen­yl(2-phenyl­hydrazin-1-yl­idene)meth­yl]phenol
title_full_unstemmed 2-[(E)-Phen­yl(2-phenyl­hydrazin-1-yl­idene)meth­yl]phenol
title_short 2-[(E)-Phen­yl(2-phenyl­hydrazin-1-yl­idene)meth­yl]phenol
title_sort 2-[(e)-phen­yl(2-phenyl­hydrazin-1-yl­idene)meth­yl]phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297864/
https://www.ncbi.nlm.nih.gov/pubmed/22412667
http://dx.doi.org/10.1107/S1600536812005387
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AT tiekinkedwardrt 2ephenyl2phenylhydrazin1ylidenemethylphenol

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