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1-(2-Hy­droxy­eth­yl)-1′-methyl-4′-(naph­thal­en-1-yl)-1′′,2′′,3′′,4′′-tetra­hydro­dispiro­[indoline-3,2′-pyrrolidine-3′,2′′-naphthalene]-2,1′′-dione

In the title compound, C(33)H(30)N(2)O(3), the pyrrolidine ring adopts an envelope conformation in which the H atom attached the an ortho-C atom deviates from the plane, whereas the cyclo­hexa­none ring in the tetra­hydro­naphthalene fused-ring system adopts a sofa conformation. The oxindoline ring...

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Autores principales: Selvanayagam, S., Sridhar, B., Saravanan, P., Raghunathan, R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297867/
https://www.ncbi.nlm.nih.gov/pubmed/22412670
http://dx.doi.org/10.1107/S1600536812006617
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author Selvanayagam, S.
Sridhar, B.
Saravanan, P.
Raghunathan, R.
author_facet Selvanayagam, S.
Sridhar, B.
Saravanan, P.
Raghunathan, R.
author_sort Selvanayagam, S.
collection PubMed
description In the title compound, C(33)H(30)N(2)O(3), the pyrrolidine ring adopts an envelope conformation in which the H atom attached the an ortho-C atom deviates from the plane, whereas the cyclo­hexa­none ring in the tetra­hydro­naphthalene fused-ring system adopts a sofa conformation. The oxindoline ring system is almost perpendicular with respect to the mean plane of the pyrrolidine ring, with a dihedral angle of 89.0 (1)°. Five intra­molecular C—H⋯O close contacts are observed. In the crystal, mol­ecules associate via O—H⋯O hydrogen bonds, forming R (2) (2)(14) dimers. In addition, there are weak C—H⋯π inter­actions.
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spelling pubmed-32978672012-03-12 1-(2-Hy­droxy­eth­yl)-1′-methyl-4′-(naph­thal­en-1-yl)-1′′,2′′,3′′,4′′-tetra­hydro­dispiro­[indoline-3,2′-pyrrolidine-3′,2′′-naphthalene]-2,1′′-dione Selvanayagam, S. Sridhar, B. Saravanan, P. Raghunathan, R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(33)H(30)N(2)O(3), the pyrrolidine ring adopts an envelope conformation in which the H atom attached the an ortho-C atom deviates from the plane, whereas the cyclo­hexa­none ring in the tetra­hydro­naphthalene fused-ring system adopts a sofa conformation. The oxindoline ring system is almost perpendicular with respect to the mean plane of the pyrrolidine ring, with a dihedral angle of 89.0 (1)°. Five intra­molecular C—H⋯O close contacts are observed. In the crystal, mol­ecules associate via O—H⋯O hydrogen bonds, forming R (2) (2)(14) dimers. In addition, there are weak C—H⋯π inter­actions. International Union of Crystallography 2012-02-24 /pmc/articles/PMC3297867/ /pubmed/22412670 http://dx.doi.org/10.1107/S1600536812006617 Text en © Selvanayagam et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Selvanayagam, S.
Sridhar, B.
Saravanan, P.
Raghunathan, R.
1-(2-Hy­droxy­eth­yl)-1′-methyl-4′-(naph­thal­en-1-yl)-1′′,2′′,3′′,4′′-tetra­hydro­dispiro­[indoline-3,2′-pyrrolidine-3′,2′′-naphthalene]-2,1′′-dione
title 1-(2-Hy­droxy­eth­yl)-1′-methyl-4′-(naph­thal­en-1-yl)-1′′,2′′,3′′,4′′-tetra­hydro­dispiro­[indoline-3,2′-pyrrolidine-3′,2′′-naphthalene]-2,1′′-dione
title_full 1-(2-Hy­droxy­eth­yl)-1′-methyl-4′-(naph­thal­en-1-yl)-1′′,2′′,3′′,4′′-tetra­hydro­dispiro­[indoline-3,2′-pyrrolidine-3′,2′′-naphthalene]-2,1′′-dione
title_fullStr 1-(2-Hy­droxy­eth­yl)-1′-methyl-4′-(naph­thal­en-1-yl)-1′′,2′′,3′′,4′′-tetra­hydro­dispiro­[indoline-3,2′-pyrrolidine-3′,2′′-naphthalene]-2,1′′-dione
title_full_unstemmed 1-(2-Hy­droxy­eth­yl)-1′-methyl-4′-(naph­thal­en-1-yl)-1′′,2′′,3′′,4′′-tetra­hydro­dispiro­[indoline-3,2′-pyrrolidine-3′,2′′-naphthalene]-2,1′′-dione
title_short 1-(2-Hy­droxy­eth­yl)-1′-methyl-4′-(naph­thal­en-1-yl)-1′′,2′′,3′′,4′′-tetra­hydro­dispiro­[indoline-3,2′-pyrrolidine-3′,2′′-naphthalene]-2,1′′-dione
title_sort 1-(2-hy­droxy­eth­yl)-1′-methyl-4′-(naph­thal­en-1-yl)-1′′,2′′,3′′,4′′-tetra­hydro­dispiro­[indoline-3,2′-pyrrolidine-3′,2′′-naphthalene]-2,1′′-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297867/
https://www.ncbi.nlm.nih.gov/pubmed/22412670
http://dx.doi.org/10.1107/S1600536812006617
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