10,16-Dichloro-6,20-dioxa-3,23-diaza­tetra­cyclo­[23.3.1.0(7,12).0(14,19)]nona­cosa-1(29),7,9,11,14(19),15,17,25,27-nona­ene-4,22-dione methanol monosolvate

In the title compound, C(25)H(22)Cl(2)N(2)O(4)·CH(3)OH, the macrocyclic mol­ecule adopts a slightly distorted C (2)-symmetric conformation. The macrocyclic mol­ecules are linked via N—H⋯O hydrogen bonds between the amide groups into chains extending along the [010] direction. The methanol mol­ecules...

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Detalles Bibliográficos
Autores principales: Pojarová, Michaela, Dušek, Michal, Sedláková, Zdeňka, Makrlík, Emanuel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297870/
https://www.ncbi.nlm.nih.gov/pubmed/22412673
http://dx.doi.org/10.1107/S1600536812007052
Descripción
Sumario:In the title compound, C(25)H(22)Cl(2)N(2)O(4)·CH(3)OH, the macrocyclic mol­ecule adopts a slightly distorted C (2)-symmetric conformation. The macrocyclic mol­ecules are linked via N—H⋯O hydrogen bonds between the amide groups into chains extending along the [010] direction. The methanol mol­ecules bridge these chains via N—H⋯O and O—H⋯O hydrogen bonds with the formation of a two-dimensional polymeric structure parallel to (001). The methanol mol­ecule is disordered over two positions with the occupancy ratio of 9:1. The disorder of the solvent molecule is caused by weak intermolecular C—H⋯Cl hydrogen bonding.

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