10,16-Dichloro-6,20-dioxa-3,23-diaza­tetra­cyclo­[23.3.1.0(7,12).0(14,19)]nona­cosa-1(29),7,9,11,14(19),15,17,25,27-nona­ene-4,22-dione methanol monosolvate

In the title compound, C(25)H(22)Cl(2)N(2)O(4)·CH(3)OH, the macrocyclic mol­ecule adopts a slightly distorted C (2)-symmetric conformation. The macrocyclic mol­ecules are linked via N—H⋯O hydrogen bonds between the amide groups into chains extending along the [010] direction. The methanol mol­ecules...

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Autores principales: Pojarová, Michaela, Dušek, Michal, Sedláková, Zdeňka, Makrlík, Emanuel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297870/
https://www.ncbi.nlm.nih.gov/pubmed/22412673
http://dx.doi.org/10.1107/S1600536812007052
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author Pojarová, Michaela
Dušek, Michal
Sedláková, Zdeňka
Makrlík, Emanuel
author_facet Pojarová, Michaela
Dušek, Michal
Sedláková, Zdeňka
Makrlík, Emanuel
author_sort Pojarová, Michaela
collection PubMed
description In the title compound, C(25)H(22)Cl(2)N(2)O(4)·CH(3)OH, the macrocyclic mol­ecule adopts a slightly distorted C (2)-symmetric conformation. The macrocyclic mol­ecules are linked via N—H⋯O hydrogen bonds between the amide groups into chains extending along the [010] direction. The methanol mol­ecules bridge these chains via N—H⋯O and O—H⋯O hydrogen bonds with the formation of a two-dimensional polymeric structure parallel to (001). The methanol mol­ecule is disordered over two positions with the occupancy ratio of 9:1. The disorder of the solvent molecule is caused by weak intermolecular C—H⋯Cl hydrogen bonding.
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spelling pubmed-32978702012-03-12 10,16-Dichloro-6,20-dioxa-3,23-diaza­tetra­cyclo­[23.3.1.0(7,12).0(14,19)]nona­cosa-1(29),7,9,11,14(19),15,17,25,27-nona­ene-4,22-dione methanol monosolvate Pojarová, Michaela Dušek, Michal Sedláková, Zdeňka Makrlík, Emanuel Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(22)Cl(2)N(2)O(4)·CH(3)OH, the macrocyclic mol­ecule adopts a slightly distorted C (2)-symmetric conformation. The macrocyclic mol­ecules are linked via N—H⋯O hydrogen bonds between the amide groups into chains extending along the [010] direction. The methanol mol­ecules bridge these chains via N—H⋯O and O—H⋯O hydrogen bonds with the formation of a two-dimensional polymeric structure parallel to (001). The methanol mol­ecule is disordered over two positions with the occupancy ratio of 9:1. The disorder of the solvent molecule is caused by weak intermolecular C—H⋯Cl hydrogen bonding. International Union of Crystallography 2012-02-24 /pmc/articles/PMC3297870/ /pubmed/22412673 http://dx.doi.org/10.1107/S1600536812007052 Text en © Pojarová et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pojarová, Michaela
Dušek, Michal
Sedláková, Zdeňka
Makrlík, Emanuel
10,16-Dichloro-6,20-dioxa-3,23-diaza­tetra­cyclo­[23.3.1.0(7,12).0(14,19)]nona­cosa-1(29),7,9,11,14(19),15,17,25,27-nona­ene-4,22-dione methanol monosolvate
title 10,16-Dichloro-6,20-dioxa-3,23-diaza­tetra­cyclo­[23.3.1.0(7,12).0(14,19)]nona­cosa-1(29),7,9,11,14(19),15,17,25,27-nona­ene-4,22-dione methanol monosolvate
title_full 10,16-Dichloro-6,20-dioxa-3,23-diaza­tetra­cyclo­[23.3.1.0(7,12).0(14,19)]nona­cosa-1(29),7,9,11,14(19),15,17,25,27-nona­ene-4,22-dione methanol monosolvate
title_fullStr 10,16-Dichloro-6,20-dioxa-3,23-diaza­tetra­cyclo­[23.3.1.0(7,12).0(14,19)]nona­cosa-1(29),7,9,11,14(19),15,17,25,27-nona­ene-4,22-dione methanol monosolvate
title_full_unstemmed 10,16-Dichloro-6,20-dioxa-3,23-diaza­tetra­cyclo­[23.3.1.0(7,12).0(14,19)]nona­cosa-1(29),7,9,11,14(19),15,17,25,27-nona­ene-4,22-dione methanol monosolvate
title_short 10,16-Dichloro-6,20-dioxa-3,23-diaza­tetra­cyclo­[23.3.1.0(7,12).0(14,19)]nona­cosa-1(29),7,9,11,14(19),15,17,25,27-nona­ene-4,22-dione methanol monosolvate
title_sort 10,16-dichloro-6,20-dioxa-3,23-diaza­tetra­cyclo­[23.3.1.0(7,12).0(14,19)]nona­cosa-1(29),7,9,11,14(19),15,17,25,27-nona­ene-4,22-dione methanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297870/
https://www.ncbi.nlm.nih.gov/pubmed/22412673
http://dx.doi.org/10.1107/S1600536812007052
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