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1-[(4-Bromophenyl)(morpholin-4-yl)methyl]naphthalen-2-ol
The title compound, C(21)H(20)BrNO(2), was obtained via a one-pot synthesis from the reaction of 4-bromobenzaldehyde, 2-naphthol and morpholine. In the asymmetric unit, there are four molecules with similar structures. The morpholine ring adopts a chair conformation, and the hydroxy group links w...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297874/ https://www.ncbi.nlm.nih.gov/pubmed/22412677 http://dx.doi.org/10.1107/S160053681200459X |
Sumario: | The title compound, C(21)H(20)BrNO(2), was obtained via a one-pot synthesis from the reaction of 4-bromobenzaldehyde, 2-naphthol and morpholine. In the asymmetric unit, there are four molecules with similar structures. The morpholine ring adopts a chair conformation, and the hydroxy group links with the morpholine via an intramolecular O—H⋯N hydrogen bond. The bromophenyl ring is approximately perpendicular to the mean pane of the naphthalene system at dihedral angles of 76.7 (3), 81.4 (3), 79.7 (3) and 84.5 (3)° in the four independent molecules. Weak C—H⋯O hydrogen bonds are observed in the crystal. |
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