1-[(4-Bromo­phen­yl)(morpholin-4-yl)­meth­yl]naphthalen-2-ol

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The title compound, C(21)H(20)BrNO(2), was obtained via a one-pot synthesis from the reaction of 4-bromo­benzaldehyde, 2-naphthol and morpholine. In the asymmetric unit, there are four mol­ecules with similar structures. The morpholine ring adopts a chair conformation, and the hy­droxy group links w...

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Detalles Bibliográficos
Autor principal: Zhao, Qun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297874/
https://www.ncbi.nlm.nih.gov/pubmed/22412677
http://dx.doi.org/10.1107/S160053681200459X
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author Zhao, Qun
author_facet Zhao, Qun
author_sort Zhao, Qun
collection PubMed
description The title compound, C(21)H(20)BrNO(2), was obtained via a one-pot synthesis from the reaction of 4-bromo­benzaldehyde, 2-naphthol and morpholine. In the asymmetric unit, there are four mol­ecules with similar structures. The morpholine ring adopts a chair conformation, and the hy­droxy group links with the morpholine via an intra­molecular O—H⋯N hydrogen bond. The bromo­phenyl ring is approximately perpendicular to the mean pane of the naphthalene system at dihedral angles of 76.7 (3), 81.4 (3), 79.7 (3) and 84.5 (3)° in the four independent mol­ecules. Weak C—H⋯O hydrogen bonds are observed in the crystal.
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spelling pubmed-32978742012-03-12 1-[(4-Bromo­phen­yl)(morpholin-4-yl)­meth­yl]naphthalen-2-ol Zhao, Qun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(20)BrNO(2), was obtained via a one-pot synthesis from the reaction of 4-bromo­benzaldehyde, 2-naphthol and morpholine. In the asymmetric unit, there are four mol­ecules with similar structures. The morpholine ring adopts a chair conformation, and the hy­droxy group links with the morpholine via an intra­molecular O—H⋯N hydrogen bond. The bromo­phenyl ring is approximately perpendicular to the mean pane of the naphthalene system at dihedral angles of 76.7 (3), 81.4 (3), 79.7 (3) and 84.5 (3)° in the four independent mol­ecules. Weak C—H⋯O hydrogen bonds are observed in the crystal. International Union of Crystallography 2012-02-24 /pmc/articles/PMC3297874/ /pubmed/22412677 http://dx.doi.org/10.1107/S160053681200459X Text en © Qun Zhao 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhao, Qun
1-[(4-Bromo­phen­yl)(morpholin-4-yl)­meth­yl]naphthalen-2-ol
title 1-[(4-Bromo­phen­yl)(morpholin-4-yl)­meth­yl]naphthalen-2-ol
title_full 1-[(4-Bromo­phen­yl)(morpholin-4-yl)­meth­yl]naphthalen-2-ol
title_fullStr 1-[(4-Bromo­phen­yl)(morpholin-4-yl)­meth­yl]naphthalen-2-ol
title_full_unstemmed 1-[(4-Bromo­phen­yl)(morpholin-4-yl)­meth­yl]naphthalen-2-ol
title_short 1-[(4-Bromo­phen­yl)(morpholin-4-yl)­meth­yl]naphthalen-2-ol
title_sort 1-[(4-bromo­phen­yl)(morpholin-4-yl)­meth­yl]naphthalen-2-ol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297874/
https://www.ncbi.nlm.nih.gov/pubmed/22412677
http://dx.doi.org/10.1107/S160053681200459X
work_keys_str_mv AT zhaoqun 14bromophenylmorpholin4ylmethylnaphthalen2ol

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