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Dimethyl 4,5-dichlorobenzene-1,2-dicarboxylate
In the title compound, C(10)H(8)Cl(2)O(4), the two Cl atoms and one of the methoxycarbonyl groups are almost coplanar [maximum derivation = 0.035 (2) Å] with the benzene plane, and the other methoxycarbonyl group exhibits an almost orthogonal disposition relative to the benzene plane, with a di...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297893/ https://www.ncbi.nlm.nih.gov/pubmed/22412696 http://dx.doi.org/10.1107/S1600536812007167 |
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author | Sun, Yongling |
author_facet | Sun, Yongling |
author_sort | Sun, Yongling |
collection | PubMed |
description | In the title compound, C(10)H(8)Cl(2)O(4), the two Cl atoms and one of the methoxycarbonyl groups are almost coplanar [maximum derivation = 0.035 (2) Å] with the benzene plane, and the other methoxycarbonyl group exhibits an almost orthogonal disposition relative to the benzene plane, with a dihedral angle of 84.82 (3)° between the planes. In the crystal, the molecules are connected into a chain propagating along the [011] direction through nonclassical C—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-3297893 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32978932012-03-12 Dimethyl 4,5-dichlorobenzene-1,2-dicarboxylate Sun, Yongling Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(10)H(8)Cl(2)O(4), the two Cl atoms and one of the methoxycarbonyl groups are almost coplanar [maximum derivation = 0.035 (2) Å] with the benzene plane, and the other methoxycarbonyl group exhibits an almost orthogonal disposition relative to the benzene plane, with a dihedral angle of 84.82 (3)° between the planes. In the crystal, the molecules are connected into a chain propagating along the [011] direction through nonclassical C—H⋯O hydrogen bonds. International Union of Crystallography 2012-02-24 /pmc/articles/PMC3297893/ /pubmed/22412696 http://dx.doi.org/10.1107/S1600536812007167 Text en © Yongling Sun 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Sun, Yongling Dimethyl 4,5-dichlorobenzene-1,2-dicarboxylate |
title | Dimethyl 4,5-dichlorobenzene-1,2-dicarboxylate |
title_full | Dimethyl 4,5-dichlorobenzene-1,2-dicarboxylate |
title_fullStr | Dimethyl 4,5-dichlorobenzene-1,2-dicarboxylate |
title_full_unstemmed | Dimethyl 4,5-dichlorobenzene-1,2-dicarboxylate |
title_short | Dimethyl 4,5-dichlorobenzene-1,2-dicarboxylate |
title_sort | dimethyl 4,5-dichlorobenzene-1,2-dicarboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297893/ https://www.ncbi.nlm.nih.gov/pubmed/22412696 http://dx.doi.org/10.1107/S1600536812007167 |
work_keys_str_mv | AT sunyongling dimethyl45dichlorobenzene12dicarboxylate |