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Dimethyl 4,5-dichlorobenzene-1,2-dicarboxyl­ate

In the title compound, C(10)H(8)Cl(2)O(4), the two Cl atoms and one of the meth­oxy­carbonyl groups are almost coplanar [maxi­mum derivation = 0.035 (2) Å] with the benzene plane, and the other meth­oxy­carbonyl group exhibits an almost orthogonal disposition relative to the benzene plane, with a di...

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Autor principal: Sun, Yongling
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297893/
https://www.ncbi.nlm.nih.gov/pubmed/22412696
http://dx.doi.org/10.1107/S1600536812007167
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author Sun, Yongling
author_facet Sun, Yongling
author_sort Sun, Yongling
collection PubMed
description In the title compound, C(10)H(8)Cl(2)O(4), the two Cl atoms and one of the meth­oxy­carbonyl groups are almost coplanar [maxi­mum derivation = 0.035 (2) Å] with the benzene plane, and the other meth­oxy­carbonyl group exhibits an almost orthogonal disposition relative to the benzene plane, with a dihedral angle of 84.82 (3)° between the planes. In the crystal, the molecules are connected into a chain propagating along the [011] direction through nonclassical C—H⋯O hydrogen bonds.
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spelling pubmed-32978932012-03-12 Dimethyl 4,5-dichlorobenzene-1,2-dicarboxyl­ate Sun, Yongling Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(10)H(8)Cl(2)O(4), the two Cl atoms and one of the meth­oxy­carbonyl groups are almost coplanar [maxi­mum derivation = 0.035 (2) Å] with the benzene plane, and the other meth­oxy­carbonyl group exhibits an almost orthogonal disposition relative to the benzene plane, with a dihedral angle of 84.82 (3)° between the planes. In the crystal, the molecules are connected into a chain propagating along the [011] direction through nonclassical C—H⋯O hydrogen bonds. International Union of Crystallography 2012-02-24 /pmc/articles/PMC3297893/ /pubmed/22412696 http://dx.doi.org/10.1107/S1600536812007167 Text en © Yongling Sun 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sun, Yongling
Dimethyl 4,5-dichlorobenzene-1,2-dicarboxyl­ate
title Dimethyl 4,5-dichlorobenzene-1,2-dicarboxyl­ate
title_full Dimethyl 4,5-dichlorobenzene-1,2-dicarboxyl­ate
title_fullStr Dimethyl 4,5-dichlorobenzene-1,2-dicarboxyl­ate
title_full_unstemmed Dimethyl 4,5-dichlorobenzene-1,2-dicarboxyl­ate
title_short Dimethyl 4,5-dichlorobenzene-1,2-dicarboxyl­ate
title_sort dimethyl 4,5-dichlorobenzene-1,2-dicarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297893/
https://www.ncbi.nlm.nih.gov/pubmed/22412696
http://dx.doi.org/10.1107/S1600536812007167
work_keys_str_mv AT sunyongling dimethyl45dichlorobenzene12dicarboxylate